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Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane...
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , |
| In: | Zeitschrift für Naturforschung B, 68, 2013, 8, S. 860-870 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
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| Schlagwörter: |
| author_facet |
Taouss, Christina Jones, Peter G. Taouss, Christina Jones, Peter G. |
|---|---|
| author |
Taouss, Christina Jones, Peter G. |
| spellingShingle |
Taouss, Christina Jones, Peter G. Zeitschrift für Naturforschung B Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides General Chemistry |
| author_sort |
taouss, christina |
| spelling |
Taouss, Christina Jones, Peter G. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.5560/znb.2013-3157 <jats:p>We report the crystal structures of six diphosphane monochalcogenides [1: 1,2-bis(diphenylphosphano) methane sulfide (dppmS), 2: 1,2-bis(diphenylphosphano)ethane oxide (dppeO), 3: 1,2- bis(diphenylphosphano)ethane sulfide (dppeS), 4: 1,2-bis(diphenylphosphano)benzene sulfide (dppbzS), 5: 1,2-bis(diphenylphosphano)benzene selenide (dppbzSe), 6: 1,8-bis(diphenylphosphano)- naphthalene sulfide (dppnS) as its dichloromethane sesquisolvate and monosolvate 6a/6b]. No isotypy is observed for analogous compounds with the same phosphine but different chalcogens. The two independent molecules of 3 are superimposable to a good approximation up to and including the ipso carbons, but the ring orientations are different; 3 differs from 2 mainly by a rotation around the P1- C1 bond. The molecules of 4 and 5 are similar except for the disposition of the rings at P<jats:sup>III</jats:sup>. The two molecules of 6 show the distortions typical of 1,8-disubstituted naphthalenes and are closely similar. In the packing of structures 1-3 non-classical hydrogen bonds of the form C-H···E (E=chalcogen) are observed. In a supplement two supposedly new polymorphs of dppmSe<jats:sub>2</jats:sub> are shown to be probably identical to previously known forms. </jats:p> Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides Zeitschrift für Naturforschung B |
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| title |
Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_unstemmed |
Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_full |
Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_fullStr |
Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_full_unstemmed |
Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_short |
Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_sort |
phosphanchalkogenide und ihre metallkomplexe. i. strukturen einiger diphosphanmonochalkogenide/ phosphane chalcogenides and their metal complexes. i. structures of some diphosphane monochalcogenides |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.5560/znb.2013-3157 |
| publishDate |
2013 |
| physical |
860-870 |
| description |
<jats:p>We report the crystal structures of six diphosphane monochalcogenides [1: 1,2-bis(diphenylphosphano) methane sulfide (dppmS), 2: 1,2-bis(diphenylphosphano)ethane oxide (dppeO), 3: 1,2- bis(diphenylphosphano)ethane sulfide (dppeS), 4: 1,2-bis(diphenylphosphano)benzene sulfide (dppbzS), 5: 1,2-bis(diphenylphosphano)benzene selenide (dppbzSe), 6: 1,8-bis(diphenylphosphano)- naphthalene sulfide (dppnS) as its dichloromethane sesquisolvate and monosolvate 6a/6b]. No isotypy is observed for analogous compounds with the same phosphine but different chalcogens. The two independent molecules of 3 are superimposable to a good approximation up to and including the ipso carbons, but the ring orientations are different; 3 differs from 2 mainly by a rotation around the P1- C1 bond. The molecules of 4 and 5 are similar except for the disposition of the rings at P<jats:sup>III</jats:sup>. The two molecules of 6 show the distortions typical of 1,8-disubstituted naphthalenes and are closely similar. In the packing of structures 1-3 non-classical hydrogen bonds of the form C-H···E (E=chalcogen) are observed. In a supplement two supposedly new polymorphs of dppmSe<jats:sub>2</jats:sub> are shown to be probably identical to previously known forms. </jats:p> |
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| description | <jats:p>We report the crystal structures of six diphosphane monochalcogenides [1: 1,2-bis(diphenylphosphano) methane sulfide (dppmS), 2: 1,2-bis(diphenylphosphano)ethane oxide (dppeO), 3: 1,2- bis(diphenylphosphano)ethane sulfide (dppeS), 4: 1,2-bis(diphenylphosphano)benzene sulfide (dppbzS), 5: 1,2-bis(diphenylphosphano)benzene selenide (dppbzSe), 6: 1,8-bis(diphenylphosphano)- naphthalene sulfide (dppnS) as its dichloromethane sesquisolvate and monosolvate 6a/6b]. No isotypy is observed for analogous compounds with the same phosphine but different chalcogens. The two independent molecules of 3 are superimposable to a good approximation up to and including the ipso carbons, but the ring orientations are different; 3 differs from 2 mainly by a rotation around the P1- C1 bond. The molecules of 4 and 5 are similar except for the disposition of the rings at P<jats:sup>III</jats:sup>. The two molecules of 6 show the distortions typical of 1,8-disubstituted naphthalenes and are closely similar. In the packing of structures 1-3 non-classical hydrogen bonds of the form C-H···E (E=chalcogen) are observed. In a supplement two supposedly new polymorphs of dppmSe<jats:sub>2</jats:sub> are shown to be probably identical to previously known forms. </jats:p> |
| doi_str_mv | 10.5560/znb.2013-3157 |
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| imprint | Walter de Gruyter GmbH, 2013 |
| imprint_str_mv | Walter de Gruyter GmbH, 2013 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zwi2 |
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| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 860-870 |
| publishDate | 2013 |
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| publisher | Walter de Gruyter GmbH |
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| series | Zeitschrift für Naturforschung B |
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| spelling | Taouss, Christina Jones, Peter G. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.5560/znb.2013-3157 <jats:p>We report the crystal structures of six diphosphane monochalcogenides [1: 1,2-bis(diphenylphosphano) methane sulfide (dppmS), 2: 1,2-bis(diphenylphosphano)ethane oxide (dppeO), 3: 1,2- bis(diphenylphosphano)ethane sulfide (dppeS), 4: 1,2-bis(diphenylphosphano)benzene sulfide (dppbzS), 5: 1,2-bis(diphenylphosphano)benzene selenide (dppbzSe), 6: 1,8-bis(diphenylphosphano)- naphthalene sulfide (dppnS) as its dichloromethane sesquisolvate and monosolvate 6a/6b]. No isotypy is observed for analogous compounds with the same phosphine but different chalcogens. The two independent molecules of 3 are superimposable to a good approximation up to and including the ipso carbons, but the ring orientations are different; 3 differs from 2 mainly by a rotation around the P1- C1 bond. The molecules of 4 and 5 are similar except for the disposition of the rings at P<jats:sup>III</jats:sup>. The two molecules of 6 show the distortions typical of 1,8-disubstituted naphthalenes and are closely similar. In the packing of structures 1-3 non-classical hydrogen bonds of the form C-H···E (E=chalcogen) are observed. In a supplement two supposedly new polymorphs of dppmSe<jats:sub>2</jats:sub> are shown to be probably identical to previously known forms. </jats:p> Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides Zeitschrift für Naturforschung B |
| spellingShingle | Taouss, Christina, Jones, Peter G., Zeitschrift für Naturforschung B, Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides, General Chemistry |
| title | Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_full | Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_fullStr | Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_full_unstemmed | Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_short | Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| title_sort | phosphanchalkogenide und ihre metallkomplexe. i. strukturen einiger diphosphanmonochalkogenide/ phosphane chalcogenides and their metal complexes. i. structures of some diphosphane monochalcogenides |
| title_unstemmed | Phosphanchalkogenide und ihre Metallkomplexe. I. Strukturen einiger Diphosphanmonochalkogenide/ Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides |
| topic | General Chemistry |
| url | http://dx.doi.org/10.5560/znb.2013-3157 |