author_facet Du, T. Z.
Liu, C.-H.
Zhao, Y. B.
Du, T. Z.
Liu, C.-H.
Zhao, Y. B.
author Du, T. Z.
Liu, C.-H.
Zhao, Y. B.
spellingShingle Du, T. Z.
Liu, C.-H.
Zhao, Y. B.
Advances in Science and Research
Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
Atmospheric Science
Pollution
Geophysics
Ecological Modeling
author_sort du, t. z.
spelling Du, T. Z. Liu, C.-H. Zhao, Y. B. 1992-0636 Copernicus GmbH Atmospheric Science Pollution Geophysics Ecological Modeling http://dx.doi.org/10.5194/asr-11-89-2014 <jats:p>Abstract. In this study, the dispersion of chemically reactive pollutants is calculated by large-eddy simulation (LES) in a neutrally stratified urban canopy layer (UCL) over urban areas. As a pilot attempt, idealized street canyons of unity building-height-to-street-width (aspect) ratio are used. Nitric oxide (NO) is emitted from the ground surface of the first street canyon into the domain doped with ozone (O3). In the absence of ultraviolet radiation, this irreversible chemistry produces nitrogen dioxide (NO2), developing a reactive plume over the rough urban surface. A range of timescales of turbulence and chemistry are utilized to examine the mechanism of turbulent mixing and chemical reactions in the UCL. The Damköhler number (Da) and the reaction rate (r) are analyzed along the vertical direction on the plane normal to the prevailing flow at 10 m after the source. The maximum reaction rate peaks at an elevation where Damköhler number Da is equal or close to unity. Hence, comparable timescales of turbulence and reaction could enhance the chemical reactions in the plume. </jats:p> Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions Advances in Science and Research
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title Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_unstemmed Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_full Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_fullStr Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_full_unstemmed Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_short Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_sort large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
topic Atmospheric Science
Pollution
Geophysics
Ecological Modeling
url http://dx.doi.org/10.5194/asr-11-89-2014
publishDate 2014
physical 89-91
description <jats:p>Abstract. In this study, the dispersion of chemically reactive pollutants is calculated by large-eddy simulation (LES) in a neutrally stratified urban canopy layer (UCL) over urban areas. As a pilot attempt, idealized street canyons of unity building-height-to-street-width (aspect) ratio are used. Nitric oxide (NO) is emitted from the ground surface of the first street canyon into the domain doped with ozone (O3). In the absence of ultraviolet radiation, this irreversible chemistry produces nitrogen dioxide (NO2), developing a reactive plume over the rough urban surface. A range of timescales of turbulence and chemistry are utilized to examine the mechanism of turbulent mixing and chemical reactions in the UCL. The Damköhler number (Da) and the reaction rate (r) are analyzed along the vertical direction on the plane normal to the prevailing flow at 10 m after the source. The maximum reaction rate peaks at an elevation where Damköhler number Da is equal or close to unity. Hence, comparable timescales of turbulence and reaction could enhance the chemical reactions in the plume. </jats:p>
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author Du, T. Z., Liu, C.-H., Zhao, Y. B.
author_facet Du, T. Z., Liu, C.-H., Zhao, Y. B., Du, T. Z., Liu, C.-H., Zhao, Y. B.
author_sort du, t. z.
container_issue 1
container_start_page 89
container_title Advances in Science and Research
container_volume 11
description <jats:p>Abstract. In this study, the dispersion of chemically reactive pollutants is calculated by large-eddy simulation (LES) in a neutrally stratified urban canopy layer (UCL) over urban areas. As a pilot attempt, idealized street canyons of unity building-height-to-street-width (aspect) ratio are used. Nitric oxide (NO) is emitted from the ground surface of the first street canyon into the domain doped with ozone (O3). In the absence of ultraviolet radiation, this irreversible chemistry produces nitrogen dioxide (NO2), developing a reactive plume over the rough urban surface. A range of timescales of turbulence and chemistry are utilized to examine the mechanism of turbulent mixing and chemical reactions in the UCL. The Damköhler number (Da) and the reaction rate (r) are analyzed along the vertical direction on the plane normal to the prevailing flow at 10 m after the source. The maximum reaction rate peaks at an elevation where Damköhler number Da is equal or close to unity. Hence, comparable timescales of turbulence and reaction could enhance the chemical reactions in the plume. </jats:p>
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spelling Du, T. Z. Liu, C.-H. Zhao, Y. B. 1992-0636 Copernicus GmbH Atmospheric Science Pollution Geophysics Ecological Modeling http://dx.doi.org/10.5194/asr-11-89-2014 <jats:p>Abstract. In this study, the dispersion of chemically reactive pollutants is calculated by large-eddy simulation (LES) in a neutrally stratified urban canopy layer (UCL) over urban areas. As a pilot attempt, idealized street canyons of unity building-height-to-street-width (aspect) ratio are used. Nitric oxide (NO) is emitted from the ground surface of the first street canyon into the domain doped with ozone (O3). In the absence of ultraviolet radiation, this irreversible chemistry produces nitrogen dioxide (NO2), developing a reactive plume over the rough urban surface. A range of timescales of turbulence and chemistry are utilized to examine the mechanism of turbulent mixing and chemical reactions in the UCL. The Damköhler number (Da) and the reaction rate (r) are analyzed along the vertical direction on the plane normal to the prevailing flow at 10 m after the source. The maximum reaction rate peaks at an elevation where Damköhler number Da is equal or close to unity. Hence, comparable timescales of turbulence and reaction could enhance the chemical reactions in the plume. </jats:p> Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions Advances in Science and Research
spellingShingle Du, T. Z., Liu, C.-H., Zhao, Y. B., Advances in Science and Research, Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions, Atmospheric Science, Pollution, Geophysics, Ecological Modeling
title Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_full Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_fullStr Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_full_unstemmed Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_short Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_sort large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
title_unstemmed Large-eddy simulation of pollutant dispersion from a ground-level area source over urban street canyons with irreversible chemical reactions
topic Atmospheric Science, Pollution, Geophysics, Ecological Modeling
url http://dx.doi.org/10.5194/asr-11-89-2014