author_facet Schuh, Philipp
Steiner, Johannes
La Via, Francesco
Mauceri, Marco
Zielinski, Marcin
Wellmann, Peter J.
Schuh, Philipp
Steiner, Johannes
La Via, Francesco
Mauceri, Marco
Zielinski, Marcin
Wellmann, Peter J.
author Schuh, Philipp
Steiner, Johannes
La Via, Francesco
Mauceri, Marco
Zielinski, Marcin
Wellmann, Peter J.
spellingShingle Schuh, Philipp
Steiner, Johannes
La Via, Francesco
Mauceri, Marco
Zielinski, Marcin
Wellmann, Peter J.
Materials
Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
General Materials Science
author_sort schuh, philipp
spelling Schuh, Philipp Steiner, Johannes La Via, Francesco Mauceri, Marco Zielinski, Marcin Wellmann, Peter J. 1996-1944 MDPI AG General Materials Science http://dx.doi.org/10.3390/ma12152353 <jats:p>The growth of 3C-SiC shows technological challenges, such as high supersaturation, a silicon-rich gas phase and a high vertical temperature gradient. We have developed a transfer method creating high-quality 3C-SiC-on-SiC (100) seeding stacks, suitable for use in sublimation “sandwich” epitaxy (SE). This work presents simulation data on the change of supersaturation and the temperature gradient between source and seed for the bulk growth. A series of growth runs on increased source to seed distances was characterized by XRD and Raman spectroscopy. Results show a decrease in quality in terms of single-crystallinity with a decrease in supersaturation. Morphology analysis of as-grown material indicates an increasing protrusion dimension with increasing thickness. This effect limits the achievable maximal thickness. Additional polytype inclusions were observed, which began to occur with low supersaturation (S ≤ 0.06) and prolonged growth (increase of carbon gas-species).</jats:p> Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks Materials
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title Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_unstemmed Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_full Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_fullStr Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_full_unstemmed Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_short Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_sort limitations during vapor phase growth of bulk (100) 3c-sic using 3c-sic-on-sic seeding stacks
topic General Materials Science
url http://dx.doi.org/10.3390/ma12152353
publishDate 2019
physical 2353
description <jats:p>The growth of 3C-SiC shows technological challenges, such as high supersaturation, a silicon-rich gas phase and a high vertical temperature gradient. We have developed a transfer method creating high-quality 3C-SiC-on-SiC (100) seeding stacks, suitable for use in sublimation “sandwich” epitaxy (SE). This work presents simulation data on the change of supersaturation and the temperature gradient between source and seed for the bulk growth. A series of growth runs on increased source to seed distances was characterized by XRD and Raman spectroscopy. Results show a decrease in quality in terms of single-crystallinity with a decrease in supersaturation. Morphology analysis of as-grown material indicates an increasing protrusion dimension with increasing thickness. This effect limits the achievable maximal thickness. Additional polytype inclusions were observed, which began to occur with low supersaturation (S ≤ 0.06) and prolonged growth (increase of carbon gas-species).</jats:p>
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author Schuh, Philipp, Steiner, Johannes, La Via, Francesco, Mauceri, Marco, Zielinski, Marcin, Wellmann, Peter J.
author_facet Schuh, Philipp, Steiner, Johannes, La Via, Francesco, Mauceri, Marco, Zielinski, Marcin, Wellmann, Peter J., Schuh, Philipp, Steiner, Johannes, La Via, Francesco, Mauceri, Marco, Zielinski, Marcin, Wellmann, Peter J.
author_sort schuh, philipp
container_issue 15
container_start_page 0
container_title Materials
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description <jats:p>The growth of 3C-SiC shows technological challenges, such as high supersaturation, a silicon-rich gas phase and a high vertical temperature gradient. We have developed a transfer method creating high-quality 3C-SiC-on-SiC (100) seeding stacks, suitable for use in sublimation “sandwich” epitaxy (SE). This work presents simulation data on the change of supersaturation and the temperature gradient between source and seed for the bulk growth. A series of growth runs on increased source to seed distances was characterized by XRD and Raman spectroscopy. Results show a decrease in quality in terms of single-crystallinity with a decrease in supersaturation. Morphology analysis of as-grown material indicates an increasing protrusion dimension with increasing thickness. This effect limits the achievable maximal thickness. Additional polytype inclusions were observed, which began to occur with low supersaturation (S ≤ 0.06) and prolonged growth (increase of carbon gas-species).</jats:p>
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imprint_str_mv MDPI AG, 2019
institution DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3
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match_str schuh2019limitationsduringvaporphasegrowthofbulk1003csicusing3csiconsicseedingstacks
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physical 2353
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record_format ai
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source_id 49
spelling Schuh, Philipp Steiner, Johannes La Via, Francesco Mauceri, Marco Zielinski, Marcin Wellmann, Peter J. 1996-1944 MDPI AG General Materials Science http://dx.doi.org/10.3390/ma12152353 <jats:p>The growth of 3C-SiC shows technological challenges, such as high supersaturation, a silicon-rich gas phase and a high vertical temperature gradient. We have developed a transfer method creating high-quality 3C-SiC-on-SiC (100) seeding stacks, suitable for use in sublimation “sandwich” epitaxy (SE). This work presents simulation data on the change of supersaturation and the temperature gradient between source and seed for the bulk growth. A series of growth runs on increased source to seed distances was characterized by XRD and Raman spectroscopy. Results show a decrease in quality in terms of single-crystallinity with a decrease in supersaturation. Morphology analysis of as-grown material indicates an increasing protrusion dimension with increasing thickness. This effect limits the achievable maximal thickness. Additional polytype inclusions were observed, which began to occur with low supersaturation (S ≤ 0.06) and prolonged growth (increase of carbon gas-species).</jats:p> Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks Materials
spellingShingle Schuh, Philipp, Steiner, Johannes, La Via, Francesco, Mauceri, Marco, Zielinski, Marcin, Wellmann, Peter J., Materials, Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks, General Materials Science
title Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_full Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_fullStr Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_full_unstemmed Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_short Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
title_sort limitations during vapor phase growth of bulk (100) 3c-sic using 3c-sic-on-sic seeding stacks
title_unstemmed Limitations during Vapor Phase Growth of Bulk (100) 3C-SiC Using 3C-SiC-on-SiC Seeding Stacks
topic General Materials Science
url http://dx.doi.org/10.3390/ma12152353