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Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and mole...
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Zeitschriftentitel: | Journal of the Serbian Chemical Society |
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Personen und Körperschaften: | , , , |
In: | Journal of the Serbian Chemical Society, 71, 2006, 6, S. 593-604 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
National Library of Serbia
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author_facet |
Leovac, Vukadin Divjakovic, Vladimir Cesljevic, Valerija Rakocevic, Milena Leovac, Vukadin Divjakovic, Vladimir Cesljevic, Valerija Rakocevic, Milena |
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author |
Leovac, Vukadin Divjakovic, Vladimir Cesljevic, Valerija Rakocevic, Milena |
spellingShingle |
Leovac, Vukadin Divjakovic, Vladimir Cesljevic, Valerija Rakocevic, Milena Journal of the Serbian Chemical Society Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ General Chemistry |
author_sort |
leovac, vukadin |
spelling |
Leovac, Vukadin Divjakovic, Vladimir Cesljevic, Valerija Rakocevic, Milena 0352-5139 1820-7421 National Library of Serbia General Chemistry http://dx.doi.org/10.2298/jsc0606593l <jats:p>The template reaction of a warm methanolic solution of Ni(OAc)2?4H2O S-n-propylisothiosemicarbazide hydroiodide and acetylacetone yielded the needle- like, brown, diamagnetic complex [Ni(L-H)]I?MeOH, and in the presence of an excess of NH 4NCS, brown, prismatic crystals of the complex [Ni(L-H)]NCS (1), both compounds involving the monoanionic form of the ligand, acetylacetone bis(S-n-propylisothiosemicarbazone), L. Slow recrystallization fromMeOH, EtOH, iPrOH and Me2CO gave the corresponding monosolvent complexes [Ni(L-H)]I?solvent, of which only those involving EtOH and iPrOH were suitable for structural analysis. The crystallographic parameters of [Ni(L-H)]I?EtOH (2) and [Ni(L-H)]I?iPrOH (3) are very similar to each other, showing their structures are isomorphic. The crystal structures of the title compounds consist of the independent ions: NCS-, or I-, and the chemically identical cation [Ni(L-H)]+, where L-H is the monoanion resulting from deprotonation of the acetylacetone moiety, a tetradentate N4 ligand forming a square-planar coordination around a Ni(II) ion. It was found that the isothiosemicarbazide fragment of the ligand has an imido form. The complex cations of the compounds [Ni(L-H)]NCS and [Ni(L-H)]I?EtOH exhibit significant difference only in the conformation of their propyl groups.</jats:p> Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ Journal of the Serbian Chemical Society |
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10.2298/jsc0606593l |
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Online Free |
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ElectronicArticle |
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National Library of Serbia, 2006 |
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National Library of Serbia, 2006 |
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0352-5139 1820-7421 |
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0352-5139 1820-7421 |
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National Library of Serbia |
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Journal of the Serbian Chemical Society |
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49 |
title |
Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_unstemmed |
Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_full |
Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_fullStr |
Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_full_unstemmed |
Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_short |
Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_sort |
transition metal complexes with thiosemicarbazide-based ligands. part 51. square-planer nickel(ii)complex with acetylacetone bis(s-n-propylisothiosemicarbazone)(l).crystal and molecular structure of [ |
topic |
General Chemistry |
url |
http://dx.doi.org/10.2298/jsc0606593l |
publishDate |
2006 |
physical |
593-604 |
description |
<jats:p>The template reaction of a warm methanolic solution of Ni(OAc)2?4H2O S-n-propylisothiosemicarbazide hydroiodide and acetylacetone yielded the needle- like, brown, diamagnetic complex [Ni(L-H)]I?MeOH, and in the presence of an excess of NH 4NCS, brown, prismatic crystals of the complex [Ni(L-H)]NCS (1), both compounds involving the monoanionic form of the ligand, acetylacetone bis(S-n-propylisothiosemicarbazone), L. Slow recrystallization fromMeOH, EtOH, iPrOH and Me2CO gave the corresponding monosolvent complexes [Ni(L-H)]I?solvent, of which only those involving EtOH and iPrOH were suitable for structural analysis. The crystallographic parameters of [Ni(L-H)]I?EtOH (2) and [Ni(L-H)]I?iPrOH (3) are very similar to each other, showing their structures are isomorphic. The crystal structures of the title compounds consist of the independent ions: NCS-, or I-, and the chemically identical cation [Ni(L-H)]+, where L-H is the monoanion resulting from deprotonation of the acetylacetone moiety, a tetradentate N4 ligand forming a square-planar coordination around a Ni(II) ion. It was found that the isothiosemicarbazide fragment of the ligand has an imido form. The complex cations of the compounds [Ni(L-H)]NCS and [Ni(L-H)]I?EtOH exhibit significant difference only in the conformation of their propyl groups.</jats:p> |
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author | Leovac, Vukadin, Divjakovic, Vladimir, Cesljevic, Valerija, Rakocevic, Milena |
author_facet | Leovac, Vukadin, Divjakovic, Vladimir, Cesljevic, Valerija, Rakocevic, Milena, Leovac, Vukadin, Divjakovic, Vladimir, Cesljevic, Valerija, Rakocevic, Milena |
author_sort | leovac, vukadin |
container_issue | 6 |
container_start_page | 593 |
container_title | Journal of the Serbian Chemical Society |
container_volume | 71 |
description | <jats:p>The template reaction of a warm methanolic solution of Ni(OAc)2?4H2O S-n-propylisothiosemicarbazide hydroiodide and acetylacetone yielded the needle- like, brown, diamagnetic complex [Ni(L-H)]I?MeOH, and in the presence of an excess of NH 4NCS, brown, prismatic crystals of the complex [Ni(L-H)]NCS (1), both compounds involving the monoanionic form of the ligand, acetylacetone bis(S-n-propylisothiosemicarbazone), L. Slow recrystallization fromMeOH, EtOH, iPrOH and Me2CO gave the corresponding monosolvent complexes [Ni(L-H)]I?solvent, of which only those involving EtOH and iPrOH were suitable for structural analysis. The crystallographic parameters of [Ni(L-H)]I?EtOH (2) and [Ni(L-H)]I?iPrOH (3) are very similar to each other, showing their structures are isomorphic. The crystal structures of the title compounds consist of the independent ions: NCS-, or I-, and the chemically identical cation [Ni(L-H)]+, where L-H is the monoanion resulting from deprotonation of the acetylacetone moiety, a tetradentate N4 ligand forming a square-planar coordination around a Ni(II) ion. It was found that the isothiosemicarbazide fragment of the ligand has an imido form. The complex cations of the compounds [Ni(L-H)]NCS and [Ni(L-H)]I?EtOH exhibit significant difference only in the conformation of their propyl groups.</jats:p> |
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imprint | National Library of Serbia, 2006 |
imprint_str_mv | National Library of Serbia, 2006 |
institution | DE-14, DE-105, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Zi4, DE-Gla1, DE-15, DE-Pl11, DE-Rs1 |
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mega_collection | National Library of Serbia (CrossRef) |
physical | 593-604 |
publishDate | 2006 |
publishDateSort | 2006 |
publisher | National Library of Serbia |
record_format | ai |
recordtype | ai |
series | Journal of the Serbian Chemical Society |
source_id | 49 |
spelling | Leovac, Vukadin Divjakovic, Vladimir Cesljevic, Valerija Rakocevic, Milena 0352-5139 1820-7421 National Library of Serbia General Chemistry http://dx.doi.org/10.2298/jsc0606593l <jats:p>The template reaction of a warm methanolic solution of Ni(OAc)2?4H2O S-n-propylisothiosemicarbazide hydroiodide and acetylacetone yielded the needle- like, brown, diamagnetic complex [Ni(L-H)]I?MeOH, and in the presence of an excess of NH 4NCS, brown, prismatic crystals of the complex [Ni(L-H)]NCS (1), both compounds involving the monoanionic form of the ligand, acetylacetone bis(S-n-propylisothiosemicarbazone), L. Slow recrystallization fromMeOH, EtOH, iPrOH and Me2CO gave the corresponding monosolvent complexes [Ni(L-H)]I?solvent, of which only those involving EtOH and iPrOH were suitable for structural analysis. The crystallographic parameters of [Ni(L-H)]I?EtOH (2) and [Ni(L-H)]I?iPrOH (3) are very similar to each other, showing their structures are isomorphic. The crystal structures of the title compounds consist of the independent ions: NCS-, or I-, and the chemically identical cation [Ni(L-H)]+, where L-H is the monoanion resulting from deprotonation of the acetylacetone moiety, a tetradentate N4 ligand forming a square-planar coordination around a Ni(II) ion. It was found that the isothiosemicarbazide fragment of the ligand has an imido form. The complex cations of the compounds [Ni(L-H)]NCS and [Ni(L-H)]I?EtOH exhibit significant difference only in the conformation of their propyl groups.</jats:p> Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ Journal of the Serbian Chemical Society |
spellingShingle | Leovac, Vukadin, Divjakovic, Vladimir, Cesljevic, Valerija, Rakocevic, Milena, Journal of the Serbian Chemical Society, Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [, General Chemistry |
title | Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_full | Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_fullStr | Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_full_unstemmed | Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_short | Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
title_sort | transition metal complexes with thiosemicarbazide-based ligands. part 51. square-planer nickel(ii)complex with acetylacetone bis(s-n-propylisothiosemicarbazone)(l).crystal and molecular structure of [ |
title_unstemmed | Transition metal complexes with thiosemicarbazide-based ligands. Part 51. Square-planer nickel(II)complex with acetylacetone bis(S-n-propylisothiosemicarbazone)(L).Crystal and molecular structure of [ |
topic | General Chemistry |
url | http://dx.doi.org/10.2298/jsc0606593l |