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A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor
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| Zeitschriftentitel: | International Journal of Chemical Reactor Engineering |
|---|---|
| Personen und Körperschaften: | , , , , , , , |
| In: | International Journal of Chemical Reactor Engineering, 11, 2013, 1, S. 265-269 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Wang, Lina Wang, Yaquan Wu, Guoqiang Feng, Wenping Zhang, Teng Yang, Rumin Jin, Xing Shi, Hainan Wang, Lina Wang, Yaquan Wu, Guoqiang Feng, Wenping Zhang, Teng Yang, Rumin Jin, Xing Shi, Hainan |
|---|---|
| author |
Wang, Lina Wang, Yaquan Wu, Guoqiang Feng, Wenping Zhang, Teng Yang, Rumin Jin, Xing Shi, Hainan |
| spellingShingle |
Wang, Lina Wang, Yaquan Wu, Guoqiang Feng, Wenping Zhang, Teng Yang, Rumin Jin, Xing Shi, Hainan International Journal of Chemical Reactor Engineering A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor General Chemical Engineering |
| author_sort |
wang, lina |
| spelling |
Wang, Lina Wang, Yaquan Wu, Guoqiang Feng, Wenping Zhang, Teng Yang, Rumin Jin, Xing Shi, Hainan 2194-5748 1542-6580 Walter de Gruyter GmbH General Chemical Engineering http://dx.doi.org/10.1515/ijcre-2013-0044 <jats:title>Abstract</jats:title> <jats:p>H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> decomposition in the propylene epoxidation system in a fixed-bed reactor was studied herein for the first time. The decomposition rate of H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> increased with increasing reaction temperature. The decomposition reaction followed the first-order kinetics equation at 30–50°C, whereas it did not follow the equation any longer at higher than 50°C. A kinetics equation for the H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> decomposition catalyzed by TS-1/SiO<jats:sub>2</jats:sub> at 30–50°C was obtained, and the reaction activation energy Ea was calculated as 69.26 kJ/mol.</jats:p> A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor International Journal of Chemical Reactor Engineering |
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Walter de Gruyter GmbH, 2013 |
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International Journal of Chemical Reactor Engineering |
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| title |
A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_unstemmed |
A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_full |
A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_fullStr |
A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_full_unstemmed |
A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_short |
A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_sort |
a novel kinetics study on h2o2 decomposition inthe propylene epoxidation system in a fixed-bed reactor |
| topic |
General Chemical Engineering |
| url |
http://dx.doi.org/10.1515/ijcre-2013-0044 |
| publishDate |
2013 |
| physical |
265-269 |
| description |
<jats:title>Abstract</jats:title>
<jats:p>H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> decomposition in the propylene epoxidation system in a fixed-bed reactor was studied herein for the first time. The decomposition rate of H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> increased with increasing reaction temperature. The decomposition reaction followed the first-order kinetics equation at 30–50°C, whereas it did not follow the equation any longer at higher than 50°C. A kinetics equation for the H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> decomposition catalyzed by TS-1/SiO<jats:sub>2</jats:sub> at 30–50°C was obtained, and the reaction activation energy Ea was calculated as 69.26 kJ/mol.</jats:p> |
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| author | Wang, Lina, Wang, Yaquan, Wu, Guoqiang, Feng, Wenping, Zhang, Teng, Yang, Rumin, Jin, Xing, Shi, Hainan |
| author_facet | Wang, Lina, Wang, Yaquan, Wu, Guoqiang, Feng, Wenping, Zhang, Teng, Yang, Rumin, Jin, Xing, Shi, Hainan, Wang, Lina, Wang, Yaquan, Wu, Guoqiang, Feng, Wenping, Zhang, Teng, Yang, Rumin, Jin, Xing, Shi, Hainan |
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| description | <jats:title>Abstract</jats:title> <jats:p>H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> decomposition in the propylene epoxidation system in a fixed-bed reactor was studied herein for the first time. The decomposition rate of H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> increased with increasing reaction temperature. The decomposition reaction followed the first-order kinetics equation at 30–50°C, whereas it did not follow the equation any longer at higher than 50°C. A kinetics equation for the H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> decomposition catalyzed by TS-1/SiO<jats:sub>2</jats:sub> at 30–50°C was obtained, and the reaction activation energy Ea was calculated as 69.26 kJ/mol.</jats:p> |
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| physical | 265-269 |
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| series | International Journal of Chemical Reactor Engineering |
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| spelling | Wang, Lina Wang, Yaquan Wu, Guoqiang Feng, Wenping Zhang, Teng Yang, Rumin Jin, Xing Shi, Hainan 2194-5748 1542-6580 Walter de Gruyter GmbH General Chemical Engineering http://dx.doi.org/10.1515/ijcre-2013-0044 <jats:title>Abstract</jats:title> <jats:p>H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> decomposition in the propylene epoxidation system in a fixed-bed reactor was studied herein for the first time. The decomposition rate of H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> increased with increasing reaction temperature. The decomposition reaction followed the first-order kinetics equation at 30–50°C, whereas it did not follow the equation any longer at higher than 50°C. A kinetics equation for the H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> decomposition catalyzed by TS-1/SiO<jats:sub>2</jats:sub> at 30–50°C was obtained, and the reaction activation energy Ea was calculated as 69.26 kJ/mol.</jats:p> A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor International Journal of Chemical Reactor Engineering |
| spellingShingle | Wang, Lina, Wang, Yaquan, Wu, Guoqiang, Feng, Wenping, Zhang, Teng, Yang, Rumin, Jin, Xing, Shi, Hainan, International Journal of Chemical Reactor Engineering, A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor, General Chemical Engineering |
| title | A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_full | A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_fullStr | A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_full_unstemmed | A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_short | A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| title_sort | a novel kinetics study on h2o2 decomposition inthe propylene epoxidation system in a fixed-bed reactor |
| title_unstemmed | A Novel Kinetics Study on H2O2 Decomposition inthe Propylene Epoxidation System in a Fixed-Bed Reactor |
| topic | General Chemical Engineering |
| url | http://dx.doi.org/10.1515/ijcre-2013-0044 |