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Ring-opening polymerization
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| Zeitschriftentitel: | Chemistry Teacher International |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Chemistry Teacher International, 3, 2021, 2, S. 33-57 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
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Penczek, Stanislaw Pretula, Julia Slomkowski, Stanislaw Penczek, Stanislaw Pretula, Julia Slomkowski, Stanislaw |
|---|---|
| author |
Penczek, Stanislaw Pretula, Julia Slomkowski, Stanislaw |
| spellingShingle |
Penczek, Stanislaw Pretula, Julia Slomkowski, Stanislaw Chemistry Teacher International Ring-opening polymerization Education Chemistry (miscellaneous) |
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penczek, stanislaw |
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Penczek, Stanislaw Pretula, Julia Slomkowski, Stanislaw 2569-3263 Walter de Gruyter GmbH Education Chemistry (miscellaneous) http://dx.doi.org/10.1515/cti-2020-0028 <jats:title>Abstract</jats:title> <jats:p>Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization. (IUPAC Recommendations 2008), <jats:italic>Pure and Applied Chemistry</jats:italic>, 80(10), 2163–2193) as (cit.) “Ring-opening polymerization (ROP): Polymerization in which a cyclic monomer yields a monomeric unit that is either acyclic or contains fewer rings than the cyclic monomer”. The large part of the resulting polymerizations is living/controlled; practically all belong to chain polymerizations. After the introduction, providing basic information on chain polymerizations, the paper presents the concise overview of major classes of monomers used in ROP, including cyclic ethers, esters, carbonates, and siloxanes as well as cyclic nitrogen, phosphorus, and sulfur containing monomers. There are discussed also thermodynamics, kinetic polymerizability, and major mechanisms of ROP. Special attention is concentrated on polymers prepared by ROP on industrial scale.</jats:p> Ring-opening polymerization Chemistry Teacher International |
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Ring-opening polymerization |
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Ring-opening polymerization |
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Ring-opening polymerization |
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Ring-opening polymerization |
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Ring-opening polymerization |
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Ring-opening polymerization |
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ring-opening polymerization |
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Education Chemistry (miscellaneous) |
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http://dx.doi.org/10.1515/cti-2020-0028 |
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2021 |
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33-57 |
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<jats:title>Abstract</jats:title>
<jats:p>Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization. (IUPAC Recommendations 2008), <jats:italic>Pure and Applied Chemistry</jats:italic>, 80(10), 2163–2193) as (cit.) “Ring-opening polymerization (ROP): Polymerization in which a cyclic monomer yields a monomeric unit that is either acyclic or contains fewer rings than the cyclic monomer”. The large part of the resulting polymerizations is living/controlled; practically all belong to chain polymerizations. After the introduction, providing basic information on chain polymerizations, the paper presents the concise overview of major classes of monomers used in ROP, including cyclic ethers, esters, carbonates, and siloxanes as well as cyclic nitrogen, phosphorus, and sulfur containing monomers. There are discussed also thermodynamics, kinetic polymerizability, and major mechanisms of ROP. Special attention is concentrated on polymers prepared by ROP on industrial scale.</jats:p> |
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| author | Penczek, Stanislaw, Pretula, Julia, Slomkowski, Stanislaw |
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| description | <jats:title>Abstract</jats:title> <jats:p>Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization. (IUPAC Recommendations 2008), <jats:italic>Pure and Applied Chemistry</jats:italic>, 80(10), 2163–2193) as (cit.) “Ring-opening polymerization (ROP): Polymerization in which a cyclic monomer yields a monomeric unit that is either acyclic or contains fewer rings than the cyclic monomer”. The large part of the resulting polymerizations is living/controlled; practically all belong to chain polymerizations. After the introduction, providing basic information on chain polymerizations, the paper presents the concise overview of major classes of monomers used in ROP, including cyclic ethers, esters, carbonates, and siloxanes as well as cyclic nitrogen, phosphorus, and sulfur containing monomers. There are discussed also thermodynamics, kinetic polymerizability, and major mechanisms of ROP. Special attention is concentrated on polymers prepared by ROP on industrial scale.</jats:p> |
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| series | Chemistry Teacher International |
| source_id | 49 |
| spelling | Penczek, Stanislaw Pretula, Julia Slomkowski, Stanislaw 2569-3263 Walter de Gruyter GmbH Education Chemistry (miscellaneous) http://dx.doi.org/10.1515/cti-2020-0028 <jats:title>Abstract</jats:title> <jats:p>Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization. (IUPAC Recommendations 2008), <jats:italic>Pure and Applied Chemistry</jats:italic>, 80(10), 2163–2193) as (cit.) “Ring-opening polymerization (ROP): Polymerization in which a cyclic monomer yields a monomeric unit that is either acyclic or contains fewer rings than the cyclic monomer”. The large part of the resulting polymerizations is living/controlled; practically all belong to chain polymerizations. After the introduction, providing basic information on chain polymerizations, the paper presents the concise overview of major classes of monomers used in ROP, including cyclic ethers, esters, carbonates, and siloxanes as well as cyclic nitrogen, phosphorus, and sulfur containing monomers. There are discussed also thermodynamics, kinetic polymerizability, and major mechanisms of ROP. Special attention is concentrated on polymers prepared by ROP on industrial scale.</jats:p> Ring-opening polymerization Chemistry Teacher International |
| spellingShingle | Penczek, Stanislaw, Pretula, Julia, Slomkowski, Stanislaw, Chemistry Teacher International, Ring-opening polymerization, Education, Chemistry (miscellaneous) |
| title | Ring-opening polymerization |
| title_full | Ring-opening polymerization |
| title_fullStr | Ring-opening polymerization |
| title_full_unstemmed | Ring-opening polymerization |
| title_short | Ring-opening polymerization |
| title_sort | ring-opening polymerization |
| title_unstemmed | Ring-opening polymerization |
| topic | Education, Chemistry (miscellaneous) |
| url | http://dx.doi.org/10.1515/cti-2020-0028 |