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1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für Naturforschung B, 64, 2009, 11-12, S. 1401-1412 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
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| Schlagwörter: |
| author_facet |
Wrackmeyer, Bernd Klimkina, Elena V. Milius, Wolfgang Wrackmeyer, Bernd Klimkina, Elena V. Milius, Wolfgang |
|---|---|
| author |
Wrackmeyer, Bernd Klimkina, Elena V. Milius, Wolfgang |
| spellingShingle |
Wrackmeyer, Bernd Klimkina, Elena V. Milius, Wolfgang Zeitschrift für Naturforschung B 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies General Chemistry |
| author_sort |
wrackmeyer, bernd |
| spelling |
Wrackmeyer, Bernd Klimkina, Elena V. Milius, Wolfgang 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-2009-11-1222 <jats:p>2-Phenoxy-1,3,2-diazaphospha-[3]ferrocenophane and related derivatives (oxide, sulfide, selenide) were prepared, characterized in solution by multinuclear magnetic resonance methods (1D and 2D <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, <jats:sup>15</jats:sup>N and <jats:sup>31</jats:sup>P NMR) and in the solid state by X-ray structural analysis. The conformation of the 2-phenoxy derivative differs from that of the 2-tert-butyl compound. For further comparison, 2-R- 2,3-dihydro-1H-1,3,2-diazaphospha-phenalene derivatives R = 'Bu, PhO were prepared and studied by the same NMR techniques. The molecular structure of a selenide was determined, and together with the NMR evidence, it was concluded that the conformation of these heterocycles is independent of the respective substituent at the phosphorus atom</jats:p> 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies Zeitschrift für Naturforschung B |
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Walter de Gruyter GmbH, 2009 |
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| title |
1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_unstemmed |
1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_full |
1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
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1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
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1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_short |
1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_sort |
1,3,2-diazaphospha-[3]ferrocenophanes. molecular structures and multinuclear magnetic resonance studies |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-2009-11-1222 |
| publishDate |
2009 |
| physical |
1401-1412 |
| description |
<jats:p>2-Phenoxy-1,3,2-diazaphospha-[3]ferrocenophane and related derivatives (oxide, sulfide, selenide) were prepared, characterized in solution by multinuclear magnetic resonance methods (1D and 2D <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, <jats:sup>15</jats:sup>N and <jats:sup>31</jats:sup>P NMR) and in the solid state by X-ray structural analysis. The conformation of the 2-phenoxy derivative differs from that of the 2-tert-butyl compound. For further comparison, 2-R- 2,3-dihydro-1H-1,3,2-diazaphospha-phenalene derivatives R = 'Bu, PhO were prepared and studied by the same NMR techniques. The molecular structure of a selenide was determined, and together with the NMR evidence, it was concluded that the conformation of these heterocycles is independent of the respective substituent at the phosphorus atom</jats:p> |
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| author | Wrackmeyer, Bernd, Klimkina, Elena V., Milius, Wolfgang |
| author_facet | Wrackmeyer, Bernd, Klimkina, Elena V., Milius, Wolfgang, Wrackmeyer, Bernd, Klimkina, Elena V., Milius, Wolfgang |
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| description | <jats:p>2-Phenoxy-1,3,2-diazaphospha-[3]ferrocenophane and related derivatives (oxide, sulfide, selenide) were prepared, characterized in solution by multinuclear magnetic resonance methods (1D and 2D <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, <jats:sup>15</jats:sup>N and <jats:sup>31</jats:sup>P NMR) and in the solid state by X-ray structural analysis. The conformation of the 2-phenoxy derivative differs from that of the 2-tert-butyl compound. For further comparison, 2-R- 2,3-dihydro-1H-1,3,2-diazaphospha-phenalene derivatives R = 'Bu, PhO were prepared and studied by the same NMR techniques. The molecular structure of a selenide was determined, and together with the NMR evidence, it was concluded that the conformation of these heterocycles is independent of the respective substituent at the phosphorus atom</jats:p> |
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| spelling | Wrackmeyer, Bernd Klimkina, Elena V. Milius, Wolfgang 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-2009-11-1222 <jats:p>2-Phenoxy-1,3,2-diazaphospha-[3]ferrocenophane and related derivatives (oxide, sulfide, selenide) were prepared, characterized in solution by multinuclear magnetic resonance methods (1D and 2D <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, <jats:sup>15</jats:sup>N and <jats:sup>31</jats:sup>P NMR) and in the solid state by X-ray structural analysis. The conformation of the 2-phenoxy derivative differs from that of the 2-tert-butyl compound. For further comparison, 2-R- 2,3-dihydro-1H-1,3,2-diazaphospha-phenalene derivatives R = 'Bu, PhO were prepared and studied by the same NMR techniques. The molecular structure of a selenide was determined, and together with the NMR evidence, it was concluded that the conformation of these heterocycles is independent of the respective substituent at the phosphorus atom</jats:p> 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies Zeitschrift für Naturforschung B |
| spellingShingle | Wrackmeyer, Bernd, Klimkina, Elena V., Milius, Wolfgang, Zeitschrift für Naturforschung B, 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies, General Chemistry |
| title | 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_full | 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_fullStr | 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_full_unstemmed | 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_short | 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| title_sort | 1,3,2-diazaphospha-[3]ferrocenophanes. molecular structures and multinuclear magnetic resonance studies |
| title_unstemmed | 1,3,2-Diazaphospha-[3]ferrocenophanes. Molecular Structures and Multinuclear Magnetic Resonance Studies |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-2009-11-1222 |