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69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C)
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , |
| In: | Zeitschrift für Naturforschung B, 64, 2009, 1, S. 41-46 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Wrackmeyer, Bernd Klimkina, Elena V. Wrackmeyer, Bernd Klimkina, Elena V. |
|---|---|
| author |
Wrackmeyer, Bernd Klimkina, Elena V. |
| spellingShingle |
Wrackmeyer, Bernd Klimkina, Elena V. Zeitschrift für Naturforschung B 69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) General Chemistry |
| author_sort |
wrackmeyer, bernd |
| spelling |
Wrackmeyer, Bernd Klimkina, Elena V. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-2009-0106 <jats:p>The <jats:sup>13</jats:sup>C, <jats:sup>69/71</jats:sup>Ga and <jats:sup>115</jats:sup>In NMR spectra of lithium tetra(tert-butyl)gallate and -indate were measured under various conditions. It proved possible to determine for the first time the coupling constants <jats:sup>1</jats:sup>J(<jats:sup>69/71</jats:sup>Ga,<jats:sup>13</jats:sup>C) = 182 Hz/232 Hz and <jats:sup>1</jats:sup>J(<jats:sup>115</jats:sup>In,<jats:sup>13</jats:sup>C) = 310±10 Hz for these metallates under conditions for solvent-separated ions. DFT calculations [B3LYP/6-311+G(d,p)] were carried out for organogallium compounds such as tri(tert-butyl)gallium, trimethylgallium and tetramethylgallate in order to predict and confirm coupling constants <jats:sup>1</jats:sup>J(Ga,<jats:sup>13</jats:sup>C).</jats:p> <sup>69/71</sup>Ga and <sup>115</sup>In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants <sup>1</sup>J(<sup>69/71</sup>Ga,<sup>13</sup>C) and <sup>1</sup>J(<sup>115</sup>In,<sup>13</sup>C) Zeitschrift für Naturforschung B |
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| title |
69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_unstemmed |
69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_full |
69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_fullStr |
69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_full_unstemmed |
69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_short |
69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_sort |
<sup>69/71</sup>ga and <sup>115</sup>in nmr spectroscopy of lithium tetra(tert-butyl)gallate and -indate: spin-spin coupling constants <sup>1</sup>j(<sup>69/71</sup>ga,<sup>13</sup>c) and <sup>1</sup>j(<sup>115</sup>in,<sup>13</sup>c) |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-2009-0106 |
| publishDate |
2009 |
| physical |
41-46 |
| description |
<jats:p>The <jats:sup>13</jats:sup>C, <jats:sup>69/71</jats:sup>Ga and <jats:sup>115</jats:sup>In NMR spectra of lithium tetra(tert-butyl)gallate and -indate were measured under various conditions. It proved possible to determine for the first time the coupling constants <jats:sup>1</jats:sup>J(<jats:sup>69/71</jats:sup>Ga,<jats:sup>13</jats:sup>C) = 182 Hz/232 Hz and <jats:sup>1</jats:sup>J(<jats:sup>115</jats:sup>In,<jats:sup>13</jats:sup>C) = 310±10 Hz for these metallates under conditions for solvent-separated ions. DFT calculations [B3LYP/6-311+G(d,p)] were carried out for organogallium compounds such as tri(tert-butyl)gallium, trimethylgallium and tetramethylgallate in order to predict and confirm coupling constants <jats:sup>1</jats:sup>J(Ga,<jats:sup>13</jats:sup>C).</jats:p> |
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| description | <jats:p>The <jats:sup>13</jats:sup>C, <jats:sup>69/71</jats:sup>Ga and <jats:sup>115</jats:sup>In NMR spectra of lithium tetra(tert-butyl)gallate and -indate were measured under various conditions. It proved possible to determine for the first time the coupling constants <jats:sup>1</jats:sup>J(<jats:sup>69/71</jats:sup>Ga,<jats:sup>13</jats:sup>C) = 182 Hz/232 Hz and <jats:sup>1</jats:sup>J(<jats:sup>115</jats:sup>In,<jats:sup>13</jats:sup>C) = 310±10 Hz for these metallates under conditions for solvent-separated ions. DFT calculations [B3LYP/6-311+G(d,p)] were carried out for organogallium compounds such as tri(tert-butyl)gallium, trimethylgallium and tetramethylgallate in order to predict and confirm coupling constants <jats:sup>1</jats:sup>J(Ga,<jats:sup>13</jats:sup>C).</jats:p> |
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| institution | DE-Gla1, DE-Zi4, DE-15, DE-Rs1, DE-Pl11, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161 |
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| spelling | Wrackmeyer, Bernd Klimkina, Elena V. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-2009-0106 <jats:p>The <jats:sup>13</jats:sup>C, <jats:sup>69/71</jats:sup>Ga and <jats:sup>115</jats:sup>In NMR spectra of lithium tetra(tert-butyl)gallate and -indate were measured under various conditions. It proved possible to determine for the first time the coupling constants <jats:sup>1</jats:sup>J(<jats:sup>69/71</jats:sup>Ga,<jats:sup>13</jats:sup>C) = 182 Hz/232 Hz and <jats:sup>1</jats:sup>J(<jats:sup>115</jats:sup>In,<jats:sup>13</jats:sup>C) = 310±10 Hz for these metallates under conditions for solvent-separated ions. DFT calculations [B3LYP/6-311+G(d,p)] were carried out for organogallium compounds such as tri(tert-butyl)gallium, trimethylgallium and tetramethylgallate in order to predict and confirm coupling constants <jats:sup>1</jats:sup>J(Ga,<jats:sup>13</jats:sup>C).</jats:p> <sup>69/71</sup>Ga and <sup>115</sup>In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants <sup>1</sup>J(<sup>69/71</sup>Ga,<sup>13</sup>C) and <sup>1</sup>J(<sup>115</sup>In,<sup>13</sup>C) Zeitschrift für Naturforschung B |
| spellingShingle | Wrackmeyer, Bernd, Klimkina, Elena V., Zeitschrift für Naturforschung B, 69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C), General Chemistry |
| title | 69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_full | 69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_fullStr | 69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_full_unstemmed | 69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_short | 69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| title_sort | <sup>69/71</sup>ga and <sup>115</sup>in nmr spectroscopy of lithium tetra(tert-butyl)gallate and -indate: spin-spin coupling constants <sup>1</sup>j(<sup>69/71</sup>ga,<sup>13</sup>c) and <sup>1</sup>j(<sup>115</sup>in,<sup>13</sup>c) |
| title_unstemmed | 69/71Ga and 115In NMR Spectroscopy of Lithium Tetra(tert-butyl)gallate and -indate: Spin-Spin Coupling Constants 1J(69/71Ga,13C) and 1J(115In,13C) |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-2009-0106 |