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Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1C...
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für Naturforschung B, 59, 2004, 2, S. 190-195 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
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| Schlagwörter: |
| author_facet |
Lang, Markus A Mayer, Peter Beck, Wolfgang Lang, Markus A Mayer, Peter Beck, Wolfgang |
|---|---|
| author |
Lang, Markus A Mayer, Peter Beck, Wolfgang |
| spellingShingle |
Lang, Markus A Mayer, Peter Beck, Wolfgang Zeitschrift für Naturforschung B Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) General Chemistry |
| author_sort |
lang, markus a |
| spelling |
Lang, Markus A Mayer, Peter Beck, Wolfgang 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-2004-0211 <jats:p>By reaction of chloro bridged halfsandwich complexes with silver salts and subsequent addition of isocyanocarboxylic acid esters the isocyanide complexes [(arene)M(CNCHR<jats:sup>1</jats:sup>CO<jats:sub>2</jats:sub>R<jats:sup>2</jats:sup>)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>(X<jats:sup>−</jats:sup>)<jats:sub>2</jats:sub> (arene = C<jats:sub>6</jats:sub>Me<jats:sub>6</jats:sub>, p-cymene, M = Ru; arene = C<jats:sub>5</jats:sub>Me<jats:sub>5</jats:sub>, M = Rh, Ir), (R<jats:sup>1</jats:sup> = H, Me, CHMe<jats:sub>2</jats:sub>, CH<jats:sub>2</jats:sub>Ph, X = BF<jats:sub>4</jats:sub>, CF<jats:sub>3</jats:sub> SO<jats:sub>3</jats:sub>) were prepared and characterized. The structure of [(C<jats:sub>5</jats:sub>Me<jats:sub>5</jats:sub>) Ir(CNCH<jats:sub>2</jats:sub>CO<jats:sub>2</jats:sub>Et)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>(CF<jats:sub>3</jats:sub>SO<jats:sub>3</jats:sub> <jats:sup>−</jats:sup>)<jats:sub>2</jats:sub> was determined by X-ray structure analysis.</jats:p> Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR<sup>1</sup>CO<sub>2</sub>R<sup>2</sup>)<sub>3</sub>]<sup>2+</sup> (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR<sup>1</sup>CO<sub>2</sub>R<sup>2</sup>)<sub>3</sub>]<sup>2+</sup> (M = Ru, Rh, Ir) Zeitschrift für Naturforschung B |
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Walter de Gruyter GmbH, 2004 |
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Walter de Gruyter GmbH, 2004 |
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1865-7117 0932-0776 |
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1865-7117 0932-0776 |
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| title |
Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_unstemmed |
Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_full |
Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_fullStr |
Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_full_unstemmed |
Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_short |
Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_sort |
tris(2-isocyanocarbonsäureester)-halbsandwich-komplexe [(aren)m(cnchr<sup>1</sup>co<sub>2</sub>r<sup>2</sup>)<sub>3</sub>]<sup>2+</sup> (m = ru, rh, ir) / tris(2-isocyanocarboxylic acid ester) – halfsandwich complexes [(arene)m(cnchr<sup>1</sup>co<sub>2</sub>r<sup>2</sup>)<sub>3</sub>]<sup>2+</sup> (m = ru, rh, ir) |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-2004-0211 |
| publishDate |
2004 |
| physical |
190-195 |
| description |
<jats:p>By reaction of chloro bridged halfsandwich complexes with silver salts and subsequent addition of isocyanocarboxylic acid esters the isocyanide complexes [(arene)M(CNCHR<jats:sup>1</jats:sup>CO<jats:sub>2</jats:sub>R<jats:sup>2</jats:sup>)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>(X<jats:sup>−</jats:sup>)<jats:sub>2</jats:sub> (arene = C<jats:sub>6</jats:sub>Me<jats:sub>6</jats:sub>, p-cymene, M = Ru; arene = C<jats:sub>5</jats:sub>Me<jats:sub>5</jats:sub>, M = Rh, Ir), (R<jats:sup>1</jats:sup> = H, Me, CHMe<jats:sub>2</jats:sub>, CH<jats:sub>2</jats:sub>Ph, X = BF<jats:sub>4</jats:sub>, CF<jats:sub>3</jats:sub> SO<jats:sub>3</jats:sub>) were prepared and characterized. The structure of [(C<jats:sub>5</jats:sub>Me<jats:sub>5</jats:sub>) Ir(CNCH<jats:sub>2</jats:sub>CO<jats:sub>2</jats:sub>Et)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>(CF<jats:sub>3</jats:sub>SO<jats:sub>3</jats:sub>
<jats:sup>−</jats:sup>)<jats:sub>2</jats:sub> was determined by X-ray structure analysis.</jats:p> |
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| author | Lang, Markus A, Mayer, Peter, Beck, Wolfgang |
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| description | <jats:p>By reaction of chloro bridged halfsandwich complexes with silver salts and subsequent addition of isocyanocarboxylic acid esters the isocyanide complexes [(arene)M(CNCHR<jats:sup>1</jats:sup>CO<jats:sub>2</jats:sub>R<jats:sup>2</jats:sup>)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>(X<jats:sup>−</jats:sup>)<jats:sub>2</jats:sub> (arene = C<jats:sub>6</jats:sub>Me<jats:sub>6</jats:sub>, p-cymene, M = Ru; arene = C<jats:sub>5</jats:sub>Me<jats:sub>5</jats:sub>, M = Rh, Ir), (R<jats:sup>1</jats:sup> = H, Me, CHMe<jats:sub>2</jats:sub>, CH<jats:sub>2</jats:sub>Ph, X = BF<jats:sub>4</jats:sub>, CF<jats:sub>3</jats:sub> SO<jats:sub>3</jats:sub>) were prepared and characterized. The structure of [(C<jats:sub>5</jats:sub>Me<jats:sub>5</jats:sub>) Ir(CNCH<jats:sub>2</jats:sub>CO<jats:sub>2</jats:sub>Et)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>(CF<jats:sub>3</jats:sub>SO<jats:sub>3</jats:sub> <jats:sup>−</jats:sup>)<jats:sub>2</jats:sub> was determined by X-ray structure analysis.</jats:p> |
| doi_str_mv | 10.1515/znb-2004-0211 |
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| imprint | Walter de Gruyter GmbH, 2004 |
| imprint_str_mv | Walter de Gruyter GmbH, 2004 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161 |
| issn | 1865-7117, 0932-0776 |
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| language | English |
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| match_str | lang2004tris2isocyanocarbonsaureesterhalbsandwichkomplexearenmcnchr1co2r232mrurhirtris2isocyanocarboxylicacidesterhalfsandwichcomplexesarenemcnchr1co2r232mrurhir |
| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 190-195 |
| publishDate | 2004 |
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| series | Zeitschrift für Naturforschung B |
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| spelling | Lang, Markus A Mayer, Peter Beck, Wolfgang 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-2004-0211 <jats:p>By reaction of chloro bridged halfsandwich complexes with silver salts and subsequent addition of isocyanocarboxylic acid esters the isocyanide complexes [(arene)M(CNCHR<jats:sup>1</jats:sup>CO<jats:sub>2</jats:sub>R<jats:sup>2</jats:sup>)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>(X<jats:sup>−</jats:sup>)<jats:sub>2</jats:sub> (arene = C<jats:sub>6</jats:sub>Me<jats:sub>6</jats:sub>, p-cymene, M = Ru; arene = C<jats:sub>5</jats:sub>Me<jats:sub>5</jats:sub>, M = Rh, Ir), (R<jats:sup>1</jats:sup> = H, Me, CHMe<jats:sub>2</jats:sub>, CH<jats:sub>2</jats:sub>Ph, X = BF<jats:sub>4</jats:sub>, CF<jats:sub>3</jats:sub> SO<jats:sub>3</jats:sub>) were prepared and characterized. The structure of [(C<jats:sub>5</jats:sub>Me<jats:sub>5</jats:sub>) Ir(CNCH<jats:sub>2</jats:sub>CO<jats:sub>2</jats:sub>Et)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>(CF<jats:sub>3</jats:sub>SO<jats:sub>3</jats:sub> <jats:sup>−</jats:sup>)<jats:sub>2</jats:sub> was determined by X-ray structure analysis.</jats:p> Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR<sup>1</sup>CO<sub>2</sub>R<sup>2</sup>)<sub>3</sub>]<sup>2+</sup> (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR<sup>1</sup>CO<sub>2</sub>R<sup>2</sup>)<sub>3</sub>]<sup>2+</sup> (M = Ru, Rh, Ir) Zeitschrift für Naturforschung B |
| spellingShingle | Lang, Markus A, Mayer, Peter, Beck, Wolfgang, Zeitschrift für Naturforschung B, Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir), General Chemistry |
| title | Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_full | Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_fullStr | Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_full_unstemmed | Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_short | Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| title_sort | tris(2-isocyanocarbonsäureester)-halbsandwich-komplexe [(aren)m(cnchr<sup>1</sup>co<sub>2</sub>r<sup>2</sup>)<sub>3</sub>]<sup>2+</sup> (m = ru, rh, ir) / tris(2-isocyanocarboxylic acid ester) – halfsandwich complexes [(arene)m(cnchr<sup>1</sup>co<sub>2</sub>r<sup>2</sup>)<sub>3</sub>]<sup>2+</sup> (m = ru, rh, ir) |
| title_unstemmed | Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-2004-0211 |