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Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5
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Zeitschriftentitel: | Zeitschrift für Naturforschung B |
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Personen und Körperschaften: | , , |
In: | Zeitschrift für Naturforschung B, 53, 1998, 3, S. 287-290 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Walter de Gruyter GmbH
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Schlagwörter: |
author_facet |
Wedel, B. Wulff, L. Müller-Buschbaum, Hk. Wedel, B. Wulff, L. Müller-Buschbaum, Hk. |
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author |
Wedel, B. Wulff, L. Müller-Buschbaum, Hk. |
spellingShingle |
Wedel, B. Wulff, L. Müller-Buschbaum, Hk. Zeitschrift für Naturforschung B Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 General Chemistry |
author_sort |
wedel, b. |
spelling |
Wedel, B. Wulff, L. Müller-Buschbaum, Hk. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1998-0306 <jats:title>Abstract</jats:title> <jats:p> Single crystals of Pb<jats:sub>2</jats:sub>TeO<jats:sub>5</jats:sub> have been prepared by flux techniques. X-ray investigations showed a new crystal structure with monoclinic symmetry, space group C<jats:sup>4</jats:sup> <jats:sub>S </jats:sub>-Cc, a = 13.099(3), b = 5.714(1), c = 7.520(2) Å, β = 123,80(3)°, Z = 4. Pb<jats:sub>2</jats:sub>TeO<jats:sub>5</jats:sub> is characterized by <jats:sup>1</jats:sup> <jats:sub>∞</jats:sub>[TeO<jats:sub>5</jats:sub>] chains of octahedra isolated from each other and incorporated into an edge, corner and face connected frame of PbO<jats:sub>7</jats:sub> polyhedra. Possible positions of the lone pair of electrons of Pb<jats:sup>2+</jats:sup> are estimated by calculations of Coulomb terms of lattice energy.</jats:p> Isolierte <sup>1</sup> <sub>∞</sub>[TeO<sub>5</sub>]-Oktaederketten im Bleitellurat Pb<sub>2</sub>TeO<sub>5</sub> / Isolated <sup>1</sup> <sub>∞</sub>[TeO<sub>5</sub>] Chains of Octahedra in the Lead Tellurate Pb<sub>2</sub>TeO<sub>5</sub> Zeitschrift für Naturforschung B |
doi_str_mv |
10.1515/znb-1998-0306 |
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Online Free |
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ElectronicArticle |
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DE-D275 DE-Bn3 DE-Brt1 DE-Zwi2 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 |
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Walter de Gruyter GmbH, 1998 |
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Walter de Gruyter GmbH, 1998 |
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1998 |
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Walter de Gruyter GmbH |
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Zeitschrift für Naturforschung B |
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title |
Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_unstemmed |
Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_full |
Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_fullStr |
Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_full_unstemmed |
Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_short |
Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_sort |
isolierte <sup>1</sup>
<sub>∞</sub>[teo<sub>5</sub>]-oktaederketten im bleitellurat pb<sub>2</sub>teo<sub>5</sub> / isolated <sup>1</sup>
<sub>∞</sub>[teo<sub>5</sub>] chains of octahedra in the lead tellurate pb<sub>2</sub>teo<sub>5</sub> |
topic |
General Chemistry |
url |
http://dx.doi.org/10.1515/znb-1998-0306 |
publishDate |
1998 |
physical |
287-290 |
description |
<jats:title>Abstract</jats:title>
<jats:p> Single crystals of Pb<jats:sub>2</jats:sub>TeO<jats:sub>5</jats:sub> have been prepared by flux techniques. X-ray investigations showed a new crystal structure with monoclinic symmetry, space group C<jats:sup>4</jats:sup>
<jats:sub>S </jats:sub>-Cc, a = 13.099(3), b = 5.714(1), c = 7.520(2) Å, β = 123,80(3)°, Z = 4. Pb<jats:sub>2</jats:sub>TeO<jats:sub>5</jats:sub> is characterized by <jats:sup>1</jats:sup>
<jats:sub>∞</jats:sub>[TeO<jats:sub>5</jats:sub>] chains of octahedra isolated from each other and incorporated into an edge, corner and face connected frame of PbO<jats:sub>7</jats:sub> polyhedra. Possible positions of the lone pair of electrons of Pb<jats:sup>2+</jats:sup> are estimated by calculations of Coulomb terms of lattice energy.</jats:p> |
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author | Wedel, B., Wulff, L., Müller-Buschbaum, Hk. |
author_facet | Wedel, B., Wulff, L., Müller-Buschbaum, Hk., Wedel, B., Wulff, L., Müller-Buschbaum, Hk. |
author_sort | wedel, b. |
container_issue | 3 |
container_start_page | 287 |
container_title | Zeitschrift für Naturforschung B |
container_volume | 53 |
description | <jats:title>Abstract</jats:title> <jats:p> Single crystals of Pb<jats:sub>2</jats:sub>TeO<jats:sub>5</jats:sub> have been prepared by flux techniques. X-ray investigations showed a new crystal structure with monoclinic symmetry, space group C<jats:sup>4</jats:sup> <jats:sub>S </jats:sub>-Cc, a = 13.099(3), b = 5.714(1), c = 7.520(2) Å, β = 123,80(3)°, Z = 4. Pb<jats:sub>2</jats:sub>TeO<jats:sub>5</jats:sub> is characterized by <jats:sup>1</jats:sup> <jats:sub>∞</jats:sub>[TeO<jats:sub>5</jats:sub>] chains of octahedra isolated from each other and incorporated into an edge, corner and face connected frame of PbO<jats:sub>7</jats:sub> polyhedra. Possible positions of the lone pair of electrons of Pb<jats:sup>2+</jats:sup> are estimated by calculations of Coulomb terms of lattice energy.</jats:p> |
doi_str_mv | 10.1515/znb-1998-0306 |
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imprint | Walter de Gruyter GmbH, 1998 |
imprint_str_mv | Walter de Gruyter GmbH, 1998 |
institution | DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
issn | 1865-7117, 0932-0776 |
issn_str_mv | 1865-7117, 0932-0776 |
language | English |
last_indexed | 2024-03-01T15:04:32.733Z |
match_str | wedel1998isolierte1teo5oktaederkettenimbleitelluratpb2teo5isolated1teo5chainsofoctahedraintheleadtelluratepb2teo5 |
mega_collection | Walter de Gruyter GmbH (CrossRef) |
physical | 287-290 |
publishDate | 1998 |
publishDateSort | 1998 |
publisher | Walter de Gruyter GmbH |
record_format | ai |
recordtype | ai |
series | Zeitschrift für Naturforschung B |
source_id | 49 |
spelling | Wedel, B. Wulff, L. Müller-Buschbaum, Hk. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1998-0306 <jats:title>Abstract</jats:title> <jats:p> Single crystals of Pb<jats:sub>2</jats:sub>TeO<jats:sub>5</jats:sub> have been prepared by flux techniques. X-ray investigations showed a new crystal structure with monoclinic symmetry, space group C<jats:sup>4</jats:sup> <jats:sub>S </jats:sub>-Cc, a = 13.099(3), b = 5.714(1), c = 7.520(2) Å, β = 123,80(3)°, Z = 4. Pb<jats:sub>2</jats:sub>TeO<jats:sub>5</jats:sub> is characterized by <jats:sup>1</jats:sup> <jats:sub>∞</jats:sub>[TeO<jats:sub>5</jats:sub>] chains of octahedra isolated from each other and incorporated into an edge, corner and face connected frame of PbO<jats:sub>7</jats:sub> polyhedra. Possible positions of the lone pair of electrons of Pb<jats:sup>2+</jats:sup> are estimated by calculations of Coulomb terms of lattice energy.</jats:p> Isolierte <sup>1</sup> <sub>∞</sub>[TeO<sub>5</sub>]-Oktaederketten im Bleitellurat Pb<sub>2</sub>TeO<sub>5</sub> / Isolated <sup>1</sup> <sub>∞</sub>[TeO<sub>5</sub>] Chains of Octahedra in the Lead Tellurate Pb<sub>2</sub>TeO<sub>5</sub> Zeitschrift für Naturforschung B |
spellingShingle | Wedel, B., Wulff, L., Müller-Buschbaum, Hk., Zeitschrift für Naturforschung B, Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5, General Chemistry |
title | Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_full | Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_fullStr | Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_full_unstemmed | Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_short | Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
title_sort | isolierte <sup>1</sup> <sub>∞</sub>[teo<sub>5</sub>]-oktaederketten im bleitellurat pb<sub>2</sub>teo<sub>5</sub> / isolated <sup>1</sup> <sub>∞</sub>[teo<sub>5</sub>] chains of octahedra in the lead tellurate pb<sub>2</sub>teo<sub>5</sub> |
title_unstemmed | Isolierte 1 ∞[TeO5]-Oktaederketten im Bleitellurat Pb2TeO5 / Isolated 1 ∞[TeO5] Chains of Octahedra in the Lead Tellurate Pb2TeO5 |
topic | General Chemistry |
url | http://dx.doi.org/10.1515/znb-1998-0306 |