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Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of...

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Zeitschriftentitel: Zeitschrift für Naturforschung B
Personen und Körperschaften: Schlecht, Sabine, Chitsaz, Soheila, Neumüller, Bernhard, Dehnicke, Kurt
In: Zeitschrift für Naturforschung B, 53, 1998, 1, S. 17-22
Format: E-Article
Sprache: Englisch
veröffentlicht:
Walter de Gruyter GmbH
Schlagwörter:
General Chemistry
author_facet Schlecht, Sabine
Chitsaz, Soheila
Neumüller, Bernhard
Dehnicke, Kurt
Schlecht, Sabine
Chitsaz, Soheila
Neumüller, Bernhard
Dehnicke, Kurt
author Schlecht, Sabine
Chitsaz, Soheila
Neumüller, Bernhard
Dehnicke, Kurt
spellingShingle Schlecht, Sabine
Chitsaz, Soheila
Neumüller, Bernhard
Dehnicke, Kurt
Zeitschrift für Naturforschung B
Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
General Chemistry
author_sort schlecht, sabine
spelling Schlecht, Sabine Chitsaz, Soheila Neumüller, Bernhard Dehnicke, Kurt 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1998-0106 <jats:p>The crystal structures of the monoclinic form of Ph<jats:sub>2</jats:sub>P(O)NH<jats:sub>2</jats:sub> and of its cesium salt, [Cs{Ph<jats:sub>2</jats:sub>P(O)NH}] have been determined by X-ray methods.</jats:p> <jats:p>Ph<jats:sub>2</jats:sub>P(O)NH<jats:sub>2</jats:sub>: Space group P2<jats:sub>1</jats:sub>/c, Z = 16, lattice dimensions (-80°C): a = 2530.2(3), b = 858.9(2), c = 2135.5(3) pm, β = 110.78(1)°, R , = 0.055. Diphenylphosphinic acid amide forms dimeric molecules via N-H ··· O hydrogen bonds, the dimeric units again are associated via hydrogen bonds to form infinite double chains along the crystallographic c axis.</jats:p> <jats:p>[Cs{Ph<jats:sub>2</jats:sub>P(O)NH}]: Space group Pccn, Z = 8 , lattice dimensions (-83°C): a = 1262.8(1), b = 2632.3(2), c = 769.1(1) pm , R1 = 0.024. The compound is associated via Cs-O and Cs-N contacts along the crystallographic [001] axis forming a tubular arrangement. There are no hydrogen bonds.</jats:p> Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph<sub>2</sub>P(O)NH<sub>2</sub>, und seines Cäsiumsalzes [Cs{Ph<sub>2</sub>P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph<sub>2</sub>P(O)NH<sub>2</sub>, and of its Cesium Salt [Cs{Ph<sub>2</sub>P(O)NH}] Zeitschrift für Naturforschung B
doi_str_mv 10.1515/znb-1998-0106
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imprint Walter de Gruyter GmbH, 1998
imprint_str_mv Walter de Gruyter GmbH, 1998
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title Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_unstemmed Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_full Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_fullStr Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_full_unstemmed Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_short Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_sort die kristallstrukturen des diphenylphosphinsäureamids, ph<sub>2</sub>p(o)nh<sub>2</sub>, und seines cäsiumsalzes [cs{ph<sub>2</sub>p(o)nh}] / crystal structures of diphenylphosphinic acid amide, ph<sub>2</sub>p(o)nh<sub>2</sub>, and of its cesium salt [cs{ph<sub>2</sub>p(o)nh}]
topic General Chemistry
url http://dx.doi.org/10.1515/znb-1998-0106
publishDate 1998
physical 17-22
description <jats:p>The crystal structures of the monoclinic form of Ph<jats:sub>2</jats:sub>P(O)NH<jats:sub>2</jats:sub> and of its cesium salt, [Cs{Ph<jats:sub>2</jats:sub>P(O)NH}] have been determined by X-ray methods.</jats:p> <jats:p>Ph<jats:sub>2</jats:sub>P(O)NH<jats:sub>2</jats:sub>: Space group P2<jats:sub>1</jats:sub>/c, Z = 16, lattice dimensions (-80°C): a = 2530.2(3), b = 858.9(2), c = 2135.5(3) pm, β = 110.78(1)°, R , = 0.055. Diphenylphosphinic acid amide forms dimeric molecules via N-H ··· O hydrogen bonds, the dimeric units again are associated via hydrogen bonds to form infinite double chains along the crystallographic c axis.</jats:p> <jats:p>[Cs{Ph<jats:sub>2</jats:sub>P(O)NH}]: Space group Pccn, Z = 8 , lattice dimensions (-83°C): a = 1262.8(1), b = 2632.3(2), c = 769.1(1) pm , R1 = 0.024. The compound is associated via Cs-O and Cs-N contacts along the crystallographic [001] axis forming a tubular arrangement. There are no hydrogen bonds.</jats:p>
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author Schlecht, Sabine, Chitsaz, Soheila, Neumüller, Bernhard, Dehnicke, Kurt
author_facet Schlecht, Sabine, Chitsaz, Soheila, Neumüller, Bernhard, Dehnicke, Kurt, Schlecht, Sabine, Chitsaz, Soheila, Neumüller, Bernhard, Dehnicke, Kurt
author_sort schlecht, sabine
container_issue 1
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container_title Zeitschrift für Naturforschung B
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description <jats:p>The crystal structures of the monoclinic form of Ph<jats:sub>2</jats:sub>P(O)NH<jats:sub>2</jats:sub> and of its cesium salt, [Cs{Ph<jats:sub>2</jats:sub>P(O)NH}] have been determined by X-ray methods.</jats:p> <jats:p>Ph<jats:sub>2</jats:sub>P(O)NH<jats:sub>2</jats:sub>: Space group P2<jats:sub>1</jats:sub>/c, Z = 16, lattice dimensions (-80°C): a = 2530.2(3), b = 858.9(2), c = 2135.5(3) pm, β = 110.78(1)°, R , = 0.055. Diphenylphosphinic acid amide forms dimeric molecules via N-H ··· O hydrogen bonds, the dimeric units again are associated via hydrogen bonds to form infinite double chains along the crystallographic c axis.</jats:p> <jats:p>[Cs{Ph<jats:sub>2</jats:sub>P(O)NH}]: Space group Pccn, Z = 8 , lattice dimensions (-83°C): a = 1262.8(1), b = 2632.3(2), c = 769.1(1) pm , R1 = 0.024. The compound is associated via Cs-O and Cs-N contacts along the crystallographic [001] axis forming a tubular arrangement. There are no hydrogen bonds.</jats:p>
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spelling Schlecht, Sabine Chitsaz, Soheila Neumüller, Bernhard Dehnicke, Kurt 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1998-0106 <jats:p>The crystal structures of the monoclinic form of Ph<jats:sub>2</jats:sub>P(O)NH<jats:sub>2</jats:sub> and of its cesium salt, [Cs{Ph<jats:sub>2</jats:sub>P(O)NH}] have been determined by X-ray methods.</jats:p> <jats:p>Ph<jats:sub>2</jats:sub>P(O)NH<jats:sub>2</jats:sub>: Space group P2<jats:sub>1</jats:sub>/c, Z = 16, lattice dimensions (-80°C): a = 2530.2(3), b = 858.9(2), c = 2135.5(3) pm, β = 110.78(1)°, R , = 0.055. Diphenylphosphinic acid amide forms dimeric molecules via N-H ··· O hydrogen bonds, the dimeric units again are associated via hydrogen bonds to form infinite double chains along the crystallographic c axis.</jats:p> <jats:p>[Cs{Ph<jats:sub>2</jats:sub>P(O)NH}]: Space group Pccn, Z = 8 , lattice dimensions (-83°C): a = 1262.8(1), b = 2632.3(2), c = 769.1(1) pm , R1 = 0.024. The compound is associated via Cs-O and Cs-N contacts along the crystallographic [001] axis forming a tubular arrangement. There are no hydrogen bonds.</jats:p> Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph<sub>2</sub>P(O)NH<sub>2</sub>, und seines Cäsiumsalzes [Cs{Ph<sub>2</sub>P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph<sub>2</sub>P(O)NH<sub>2</sub>, and of its Cesium Salt [Cs{Ph<sub>2</sub>P(O)NH}] Zeitschrift für Naturforschung B
spellingShingle Schlecht, Sabine, Chitsaz, Soheila, Neumüller, Bernhard, Dehnicke, Kurt, Zeitschrift für Naturforschung B, Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}], General Chemistry
title Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_full Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_fullStr Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_full_unstemmed Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_short Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
title_sort die kristallstrukturen des diphenylphosphinsäureamids, ph<sub>2</sub>p(o)nh<sub>2</sub>, und seines cäsiumsalzes [cs{ph<sub>2</sub>p(o)nh}] / crystal structures of diphenylphosphinic acid amide, ph<sub>2</sub>p(o)nh<sub>2</sub>, and of its cesium salt [cs{ph<sub>2</sub>p(o)nh}]
title_unstemmed Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(O)NH2, und seines Cäsiumsalzes [Cs{Ph2P(O)NH}] / Crystal Structures of Diphenylphosphinic Acid Amide, Ph2P(O)NH2, and of its Cesium Salt [Cs{Ph2P(O)NH}]
topic General Chemistry
url http://dx.doi.org/10.1515/znb-1998-0106