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Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 -
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für Naturforschung B, 52, 1997, 4, S. 543-545 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Lau, Carsten Neumüller, Bernhard Dehnicke, Kurt Lau, Carsten Neumüller, Bernhard Dehnicke, Kurt |
|---|---|
| author |
Lau, Carsten Neumüller, Bernhard Dehnicke, Kurt |
| spellingShingle |
Lau, Carsten Neumüller, Bernhard Dehnicke, Kurt Zeitschrift für Naturforschung B Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - General Chemistry |
| author_sort |
lau, carsten |
| spelling |
Lau, Carsten Neumüller, Bernhard Dehnicke, Kurt 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1997-0416 <jats:title>Abstract</jats:title> <jats:p> Chloro-Cycloselenazenium Hexachloroanti-monate(V), Synthesis, Crystal Structure [Se<jats:sub>3</jats:sub>N<jats:sub>2</jats:sub>Cl]<jats:sup>+</jats:sup>SbCl<jats:sub>6</jats:sub> <jats:sup>-</jats:sup> has been prepared as red crystals by the reaction of the nitride chloride Se<jats:sub>2</jats:sub>NCl<jats:sub>5</jats:sub> with antimony(III) chloride in dichloromethane. It was characterized by a crystal structure determination. Space group PI, Z = 2, 4396 observed unique reflections, R = 0.030. Lattice dimensions at -80 °C: a = 698.2, b = 699.7, c = 1510.5 pm, α = 89.45°, β = 86.18°, γ = 68.22°. The structure consists of two symmetry-independent cations and two symmetry independent anions, which differ only slightly from each other. The cations contain Se3N2 five-membered rings, which deviate very little from planarity as shown by fol ding angles of 14° and 18°. The Se-N bond distances are between 171.4 and 176.4 pm suggesting double-bond constituents.</jats:p> Synthese und Kristallstruktur von [Se<sub>3</sub>N<sub>2</sub>Cl]<sup>+</sup>SbCl<sub>6</sub> <sup>-</sup> / Synthesis and Crystal Structure of [Se<sub>3</sub>N<sub>2</sub>Cl]<sup>+</sup>SbCl<sub>6</sub> <sup>-</sup> Zeitschrift für Naturforschung B |
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| title |
Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_unstemmed |
Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_full |
Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_fullStr |
Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_full_unstemmed |
Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_short |
Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_sort |
synthese und kristallstruktur von [se<sub>3</sub>n<sub>2</sub>cl]<sup>+</sup>sbcl<sub>6</sub>
<sup>-</sup> / synthesis and crystal structure of [se<sub>3</sub>n<sub>2</sub>cl]<sup>+</sup>sbcl<sub>6</sub>
<sup>-</sup> |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-1997-0416 |
| publishDate |
1997 |
| physical |
543-545 |
| description |
<jats:title>Abstract</jats:title>
<jats:p> Chloro-Cycloselenazenium Hexachloroanti-monate(V), Synthesis, Crystal Structure [Se<jats:sub>3</jats:sub>N<jats:sub>2</jats:sub>Cl]<jats:sup>+</jats:sup>SbCl<jats:sub>6</jats:sub>
<jats:sup>-</jats:sup> has been prepared as red crystals by the reaction of the nitride chloride Se<jats:sub>2</jats:sub>NCl<jats:sub>5</jats:sub> with antimony(III) chloride in dichloromethane. It was characterized by a crystal structure determination. Space group PI, Z = 2, 4396 observed unique reflections, R = 0.030. Lattice dimensions at -80 °C: a = 698.2, b = 699.7, c = 1510.5 pm, α = 89.45°, β = 86.18°, γ = 68.22°. The structure consists of two symmetry-independent cations and two symmetry independent anions, which differ only slightly from each other. The cations contain Se3N2 five-membered rings, which deviate very little from planarity as shown by fol ding angles of 14° and 18°. The Se-N bond distances are between 171.4 and 176.4 pm suggesting double-bond constituents.</jats:p> |
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| author | Lau, Carsten, Neumüller, Bernhard, Dehnicke, Kurt |
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| description | <jats:title>Abstract</jats:title> <jats:p> Chloro-Cycloselenazenium Hexachloroanti-monate(V), Synthesis, Crystal Structure [Se<jats:sub>3</jats:sub>N<jats:sub>2</jats:sub>Cl]<jats:sup>+</jats:sup>SbCl<jats:sub>6</jats:sub> <jats:sup>-</jats:sup> has been prepared as red crystals by the reaction of the nitride chloride Se<jats:sub>2</jats:sub>NCl<jats:sub>5</jats:sub> with antimony(III) chloride in dichloromethane. It was characterized by a crystal structure determination. Space group PI, Z = 2, 4396 observed unique reflections, R = 0.030. Lattice dimensions at -80 °C: a = 698.2, b = 699.7, c = 1510.5 pm, α = 89.45°, β = 86.18°, γ = 68.22°. The structure consists of two symmetry-independent cations and two symmetry independent anions, which differ only slightly from each other. The cations contain Se3N2 five-membered rings, which deviate very little from planarity as shown by fol ding angles of 14° and 18°. The Se-N bond distances are between 171.4 and 176.4 pm suggesting double-bond constituents.</jats:p> |
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| imprint | Walter de Gruyter GmbH, 1997 |
| imprint_str_mv | Walter de Gruyter GmbH, 1997 |
| institution | DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zwi2, DE-Gla1, DE-Zi4, DE-15 |
| issn | 1865-7117, 0932-0776 |
| issn_str_mv | 1865-7117, 0932-0776 |
| language | English |
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| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 543-545 |
| publishDate | 1997 |
| publishDateSort | 1997 |
| publisher | Walter de Gruyter GmbH |
| record_format | ai |
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| series | Zeitschrift für Naturforschung B |
| source_id | 49 |
| spelling | Lau, Carsten Neumüller, Bernhard Dehnicke, Kurt 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1997-0416 <jats:title>Abstract</jats:title> <jats:p> Chloro-Cycloselenazenium Hexachloroanti-monate(V), Synthesis, Crystal Structure [Se<jats:sub>3</jats:sub>N<jats:sub>2</jats:sub>Cl]<jats:sup>+</jats:sup>SbCl<jats:sub>6</jats:sub> <jats:sup>-</jats:sup> has been prepared as red crystals by the reaction of the nitride chloride Se<jats:sub>2</jats:sub>NCl<jats:sub>5</jats:sub> with antimony(III) chloride in dichloromethane. It was characterized by a crystal structure determination. Space group PI, Z = 2, 4396 observed unique reflections, R = 0.030. Lattice dimensions at -80 °C: a = 698.2, b = 699.7, c = 1510.5 pm, α = 89.45°, β = 86.18°, γ = 68.22°. The structure consists of two symmetry-independent cations and two symmetry independent anions, which differ only slightly from each other. The cations contain Se3N2 five-membered rings, which deviate very little from planarity as shown by fol ding angles of 14° and 18°. The Se-N bond distances are between 171.4 and 176.4 pm suggesting double-bond constituents.</jats:p> Synthese und Kristallstruktur von [Se<sub>3</sub>N<sub>2</sub>Cl]<sup>+</sup>SbCl<sub>6</sub> <sup>-</sup> / Synthesis and Crystal Structure of [Se<sub>3</sub>N<sub>2</sub>Cl]<sup>+</sup>SbCl<sub>6</sub> <sup>-</sup> Zeitschrift für Naturforschung B |
| spellingShingle | Lau, Carsten, Neumüller, Bernhard, Dehnicke, Kurt, Zeitschrift für Naturforschung B, Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 -, General Chemistry |
| title | Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_full | Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_fullStr | Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_full_unstemmed | Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_short | Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| title_sort | synthese und kristallstruktur von [se<sub>3</sub>n<sub>2</sub>cl]<sup>+</sup>sbcl<sub>6</sub> <sup>-</sup> / synthesis and crystal structure of [se<sub>3</sub>n<sub>2</sub>cl]<sup>+</sup>sbcl<sub>6</sub> <sup>-</sup> |
| title_unstemmed | Synthese und Kristallstruktur von [Se3N2Cl]+SbCl6 - / Synthesis and Crystal Structure of [Se3N2Cl]+SbCl6 - |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-1997-0416 |