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Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[...

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Zeitschriftentitel: Zeitschrift für Naturforschung B
Personen und Körperschaften: Werner, J.-P., Müller-Buschbaum, Hk.
In: Zeitschrift für Naturforschung B, 52, 1997, 4, S. 449-452
Format: E-Article
Sprache: Englisch
veröffentlicht:
Walter de Gruyter GmbH
Schlagwörter:
General Chemistry
author_facet Werner, J.-P.
Müller-Buschbaum, Hk.
Werner, J.-P.
Müller-Buschbaum, Hk.
author Werner, J.-P.
Müller-Buschbaum, Hk.
spellingShingle Werner, J.-P.
Müller-Buschbaum, Hk.
Zeitschrift für Naturforschung B
Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
General Chemistry
author_sort werner, j.-p.
spelling Werner, J.-P. Müller-Buschbaum, Hk. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1997-0403 <jats:title>Abstract</jats:title> <jats:p> Single crystals of Ln4[Al<jats:sub>12</jats:sub>O<jats:sub>24</jats:sub>](Pb<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub> (Ln = Nd, Sm) have been prepared by flux techniques. The compounds crystallize with cubic symmetry, space group Oh-Pn3̄m, a<jats:sub>Nd</jats:sub> = 9.514(1), a<jats:sub>Sm</jats:sub> = 9.481(1) Å, Z = 1. The crystal structure is characterized by a [Al<jats:sub>12</jats:sub>O<jats:sub>24</jats:sub>]<jats:sup>12-</jats:sup> framework. Four of the eight six-membered rings of AlO<jats:sub>4</jats:sub>-tetrahedra per sodalite cage are centered by Ln<jats:sup>3+</jats:sup> ions. The cages of the resulting electrically neutral network are filled with [Pb<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>]<jats:sup>±0</jats:sup> heterocubane units. Oxygen of the heterocubane units completes the coordination spheres of the rare earth ions to hexagonal bipyramids.</jats:p> Elektroneutrale Pb<sub>4</sub>O<sub>4</sub> -Heterokubaneinheiten in den Aluminatsodalithen Ln<sub>4</sub>[Al<sub>12</sub>O<sub>24</sub>](Pb<sub>4</sub>O<sub>4</sub>)<sub>2</sub> (Ln = Nd, Sm) / Electrically Neutral Pb<sub>4</sub>O<sub>4</sub> Heterocubane Units in Aluminate Sodalites Ln<sub>4</sub>[Al<sub>12</sub>O<sub>24</sub>](Pb<sub>4</sub>O<sub>4</sub>)<sub>2</sub> (Ln = Nd, Sm) Zeitschrift für Naturforschung B
doi_str_mv 10.1515/znb-1997-0403
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title Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_unstemmed Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_full Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_fullStr Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_full_unstemmed Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_short Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_sort elektroneutrale pb<sub>4</sub>o<sub>4</sub> -heterokubaneinheiten in den aluminatsodalithen ln<sub>4</sub>[al<sub>12</sub>o<sub>24</sub>](pb<sub>4</sub>o<sub>4</sub>)<sub>2</sub> (ln = nd, sm) / electrically neutral pb<sub>4</sub>o<sub>4</sub> heterocubane units in aluminate sodalites ln<sub>4</sub>[al<sub>12</sub>o<sub>24</sub>](pb<sub>4</sub>o<sub>4</sub>)<sub>2</sub> (ln = nd, sm)
topic General Chemistry
url http://dx.doi.org/10.1515/znb-1997-0403
publishDate 1997
physical 449-452
description <jats:title>Abstract</jats:title> <jats:p> Single crystals of Ln4[Al<jats:sub>12</jats:sub>O<jats:sub>24</jats:sub>](Pb<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub> (Ln = Nd, Sm) have been prepared by flux techniques. The compounds crystallize with cubic symmetry, space group Oh-Pn3̄m, a<jats:sub>Nd</jats:sub> = 9.514(1), a<jats:sub>Sm</jats:sub> = 9.481(1) Å, Z = 1. The crystal structure is characterized by a [Al<jats:sub>12</jats:sub>O<jats:sub>24</jats:sub>]<jats:sup>12-</jats:sup> framework. Four of the eight six-membered rings of AlO<jats:sub>4</jats:sub>-tetrahedra per sodalite cage are centered by Ln<jats:sup>3+</jats:sup> ions. The cages of the resulting electrically neutral network are filled with [Pb<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>]<jats:sup>±0</jats:sup> heterocubane units. Oxygen of the heterocubane units completes the coordination spheres of the rare earth ions to hexagonal bipyramids.</jats:p>
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author Werner, J.-P., Müller-Buschbaum, Hk.
author_facet Werner, J.-P., Müller-Buschbaum, Hk., Werner, J.-P., Müller-Buschbaum, Hk.
author_sort werner, j.-p.
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container_title Zeitschrift für Naturforschung B
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description <jats:title>Abstract</jats:title> <jats:p> Single crystals of Ln4[Al<jats:sub>12</jats:sub>O<jats:sub>24</jats:sub>](Pb<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub> (Ln = Nd, Sm) have been prepared by flux techniques. The compounds crystallize with cubic symmetry, space group Oh-Pn3̄m, a<jats:sub>Nd</jats:sub> = 9.514(1), a<jats:sub>Sm</jats:sub> = 9.481(1) Å, Z = 1. The crystal structure is characterized by a [Al<jats:sub>12</jats:sub>O<jats:sub>24</jats:sub>]<jats:sup>12-</jats:sup> framework. Four of the eight six-membered rings of AlO<jats:sub>4</jats:sub>-tetrahedra per sodalite cage are centered by Ln<jats:sup>3+</jats:sup> ions. The cages of the resulting electrically neutral network are filled with [Pb<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>]<jats:sup>±0</jats:sup> heterocubane units. Oxygen of the heterocubane units completes the coordination spheres of the rare earth ions to hexagonal bipyramids.</jats:p>
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imprint Walter de Gruyter GmbH, 1997
imprint_str_mv Walter de Gruyter GmbH, 1997
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spelling Werner, J.-P. Müller-Buschbaum, Hk. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1997-0403 <jats:title>Abstract</jats:title> <jats:p> Single crystals of Ln4[Al<jats:sub>12</jats:sub>O<jats:sub>24</jats:sub>](Pb<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub> (Ln = Nd, Sm) have been prepared by flux techniques. The compounds crystallize with cubic symmetry, space group Oh-Pn3̄m, a<jats:sub>Nd</jats:sub> = 9.514(1), a<jats:sub>Sm</jats:sub> = 9.481(1) Å, Z = 1. The crystal structure is characterized by a [Al<jats:sub>12</jats:sub>O<jats:sub>24</jats:sub>]<jats:sup>12-</jats:sup> framework. Four of the eight six-membered rings of AlO<jats:sub>4</jats:sub>-tetrahedra per sodalite cage are centered by Ln<jats:sup>3+</jats:sup> ions. The cages of the resulting electrically neutral network are filled with [Pb<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>]<jats:sup>±0</jats:sup> heterocubane units. Oxygen of the heterocubane units completes the coordination spheres of the rare earth ions to hexagonal bipyramids.</jats:p> Elektroneutrale Pb<sub>4</sub>O<sub>4</sub> -Heterokubaneinheiten in den Aluminatsodalithen Ln<sub>4</sub>[Al<sub>12</sub>O<sub>24</sub>](Pb<sub>4</sub>O<sub>4</sub>)<sub>2</sub> (Ln = Nd, Sm) / Electrically Neutral Pb<sub>4</sub>O<sub>4</sub> Heterocubane Units in Aluminate Sodalites Ln<sub>4</sub>[Al<sub>12</sub>O<sub>24</sub>](Pb<sub>4</sub>O<sub>4</sub>)<sub>2</sub> (Ln = Nd, Sm) Zeitschrift für Naturforschung B
spellingShingle Werner, J.-P., Müller-Buschbaum, Hk., Zeitschrift für Naturforschung B, Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm), General Chemistry
title Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_full Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_fullStr Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_full_unstemmed Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_short Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
title_sort elektroneutrale pb<sub>4</sub>o<sub>4</sub> -heterokubaneinheiten in den aluminatsodalithen ln<sub>4</sub>[al<sub>12</sub>o<sub>24</sub>](pb<sub>4</sub>o<sub>4</sub>)<sub>2</sub> (ln = nd, sm) / electrically neutral pb<sub>4</sub>o<sub>4</sub> heterocubane units in aluminate sodalites ln<sub>4</sub>[al<sub>12</sub>o<sub>24</sub>](pb<sub>4</sub>o<sub>4</sub>)<sub>2</sub> (ln = nd, sm)
title_unstemmed Elektroneutrale Pb4O4 -Heterokubaneinheiten in den Aluminatsodalithen Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm) / Electrically Neutral Pb4O4 Heterocubane Units in Aluminate Sodalites Ln4[Al12O24](Pb4O4)2 (Ln = Nd, Sm)
topic General Chemistry
url http://dx.doi.org/10.1515/znb-1997-0403