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Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , |
| In: | Zeitschrift für Naturforschung B, 52, 1997, 1, S. 35-39 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Wedel, B. Müller-Buschbaum, Hk. Wedel, B. Müller-Buschbaum, Hk. |
|---|---|
| author |
Wedel, B. Müller-Buschbaum, Hk. |
| spellingShingle |
Wedel, B. Müller-Buschbaum, Hk. Zeitschrift für Naturforschung B Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 General Chemistry |
| author_sort |
wedel, b. |
| spelling |
Wedel, B. Müller-Buschbaum, Hk. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1997-0107 <jats:p>Pb<jats:sub>3</jats:sub>Fe<jats:sub>2</jats:sub>Te<jats:sub>2</jats:sub>O<jats:sub>12</jats:sub> (I) and Pb<jats:sub>2</jats:sub>CoTeO<jats:sub>6</jats:sub> (II) have been prepared by crystallization from melts. Single crystal X-ray investigations led to monoclinic (I) and tetragonal (II) symmetry, space groups C<jats:sup>4</jats:sup> <jats:sub>s</jats:sub>-Cc and D<jats:sup>17</jats:sup> <jats:sub>4h</jats:sub>-14/mmm. Lattice constants I: a = 9.866(3), b = 15.332(4), c = 7.172(2) Å, β = 111.34(3)°, Z = 4. II: a = 5.661(5), c = 8.004(7) Å, Z = 2. (I) represents a new crystal structure, characterized by a network of octahedra occupied by Fe<jats:sup>3+ </jats:sup>and Te<jats:sup>6+</jats:sup> in a disordered manner. The centres of negative charge of the lone pairs of Pb<jats:sup>2+</jats:sup> in I are estimated by Coulomb term calculations. II belongs to the elpasolithe type</jats:p> Über die Kristallstrukturen der Tellurate Pb<sub>3</sub>Fe<sub>2</sub>Te<sub>2</sub>O<sub>12</sub> und Pb<sub>2</sub>CoTeO<sub>6</sub> / On the Crystal Structures of the Tellurates Pb<sub>3</sub>Fe<sub>2</sub>Te<sub>2</sub>O<sub>12</sub> and Pb<sub>2</sub>CoTeO<sub>6</sub> Zeitschrift für Naturforschung B |
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Walter de Gruyter GmbH, 1997 |
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Walter de Gruyter GmbH, 1997 |
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1865-7117 0932-0776 |
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1997 |
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| title |
Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_unstemmed |
Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_full |
Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_fullStr |
Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_full_unstemmed |
Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_short |
Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_sort |
über die kristallstrukturen der tellurate pb<sub>3</sub>fe<sub>2</sub>te<sub>2</sub>o<sub>12</sub> und pb<sub>2</sub>coteo<sub>6</sub> / on the crystal structures of the tellurates pb<sub>3</sub>fe<sub>2</sub>te<sub>2</sub>o<sub>12</sub> and pb<sub>2</sub>coteo<sub>6</sub> |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-1997-0107 |
| publishDate |
1997 |
| physical |
35-39 |
| description |
<jats:p>Pb<jats:sub>3</jats:sub>Fe<jats:sub>2</jats:sub>Te<jats:sub>2</jats:sub>O<jats:sub>12</jats:sub> (I) and Pb<jats:sub>2</jats:sub>CoTeO<jats:sub>6</jats:sub> (II) have been prepared by crystallization from melts. Single crystal X-ray investigations led to monoclinic (I) and tetragonal (II) symmetry, space groups C<jats:sup>4</jats:sup>
<jats:sub>s</jats:sub>-Cc and D<jats:sup>17</jats:sup>
<jats:sub>4h</jats:sub>-14/mmm. Lattice constants I: a = 9.866(3), b = 15.332(4), c = 7.172(2) Å, β = 111.34(3)°, Z = 4. II: a = 5.661(5), c = 8.004(7) Å, Z = 2. (I) represents a new crystal structure, characterized by a network of octahedra occupied by Fe<jats:sup>3+ </jats:sup>and Te<jats:sup>6+</jats:sup> in a disordered manner. The centres of negative charge of the lone pairs of Pb<jats:sup>2+</jats:sup> in I are estimated by Coulomb term calculations. II belongs to the elpasolithe type</jats:p> |
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| description | <jats:p>Pb<jats:sub>3</jats:sub>Fe<jats:sub>2</jats:sub>Te<jats:sub>2</jats:sub>O<jats:sub>12</jats:sub> (I) and Pb<jats:sub>2</jats:sub>CoTeO<jats:sub>6</jats:sub> (II) have been prepared by crystallization from melts. Single crystal X-ray investigations led to monoclinic (I) and tetragonal (II) symmetry, space groups C<jats:sup>4</jats:sup> <jats:sub>s</jats:sub>-Cc and D<jats:sup>17</jats:sup> <jats:sub>4h</jats:sub>-14/mmm. Lattice constants I: a = 9.866(3), b = 15.332(4), c = 7.172(2) Å, β = 111.34(3)°, Z = 4. II: a = 5.661(5), c = 8.004(7) Å, Z = 2. (I) represents a new crystal structure, characterized by a network of octahedra occupied by Fe<jats:sup>3+ </jats:sup>and Te<jats:sup>6+</jats:sup> in a disordered manner. The centres of negative charge of the lone pairs of Pb<jats:sup>2+</jats:sup> in I are estimated by Coulomb term calculations. II belongs to the elpasolithe type</jats:p> |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTUxNS96bmItMTk5Ny0wMTA3 |
| imprint | Walter de Gruyter GmbH, 1997 |
| imprint_str_mv | Walter de Gruyter GmbH, 1997 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Zi4, DE-Gla1, DE-15, DE-Pl11, DE-Rs1, DE-14, DE-105, DE-Ch1, DE-L229 |
| issn | 1865-7117, 0932-0776 |
| issn_str_mv | 1865-7117, 0932-0776 |
| language | English |
| last_indexed | 2024-03-01T15:44:56.857Z |
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| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 35-39 |
| publishDate | 1997 |
| publishDateSort | 1997 |
| publisher | Walter de Gruyter GmbH |
| record_format | ai |
| recordtype | ai |
| series | Zeitschrift für Naturforschung B |
| source_id | 49 |
| spelling | Wedel, B. Müller-Buschbaum, Hk. 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1997-0107 <jats:p>Pb<jats:sub>3</jats:sub>Fe<jats:sub>2</jats:sub>Te<jats:sub>2</jats:sub>O<jats:sub>12</jats:sub> (I) and Pb<jats:sub>2</jats:sub>CoTeO<jats:sub>6</jats:sub> (II) have been prepared by crystallization from melts. Single crystal X-ray investigations led to monoclinic (I) and tetragonal (II) symmetry, space groups C<jats:sup>4</jats:sup> <jats:sub>s</jats:sub>-Cc and D<jats:sup>17</jats:sup> <jats:sub>4h</jats:sub>-14/mmm. Lattice constants I: a = 9.866(3), b = 15.332(4), c = 7.172(2) Å, β = 111.34(3)°, Z = 4. II: a = 5.661(5), c = 8.004(7) Å, Z = 2. (I) represents a new crystal structure, characterized by a network of octahedra occupied by Fe<jats:sup>3+ </jats:sup>and Te<jats:sup>6+</jats:sup> in a disordered manner. The centres of negative charge of the lone pairs of Pb<jats:sup>2+</jats:sup> in I are estimated by Coulomb term calculations. II belongs to the elpasolithe type</jats:p> Über die Kristallstrukturen der Tellurate Pb<sub>3</sub>Fe<sub>2</sub>Te<sub>2</sub>O<sub>12</sub> und Pb<sub>2</sub>CoTeO<sub>6</sub> / On the Crystal Structures of the Tellurates Pb<sub>3</sub>Fe<sub>2</sub>Te<sub>2</sub>O<sub>12</sub> and Pb<sub>2</sub>CoTeO<sub>6</sub> Zeitschrift für Naturforschung B |
| spellingShingle | Wedel, B., Müller-Buschbaum, Hk., Zeitschrift für Naturforschung B, Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6, General Chemistry |
| title | Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_full | Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_fullStr | Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_full_unstemmed | Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_short | Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| title_sort | über die kristallstrukturen der tellurate pb<sub>3</sub>fe<sub>2</sub>te<sub>2</sub>o<sub>12</sub> und pb<sub>2</sub>coteo<sub>6</sub> / on the crystal structures of the tellurates pb<sub>3</sub>fe<sub>2</sub>te<sub>2</sub>o<sub>12</sub> and pb<sub>2</sub>coteo<sub>6</sub> |
| title_unstemmed | Über die Kristallstrukturen der Tellurate Pb3Fe2Te2O12 und Pb2CoTeO6 / On the Crystal Structures of the Tellurates Pb3Fe2Te2O12 and Pb2CoTeO6 |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-1997-0107 |