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Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic P...

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Zeitschriftentitel: Zeitschrift für Naturforschung B
Personen und Körperschaften: Robl, Christian, Weiss, Armin
In: Zeitschrift für Naturforschung B, 41, 1986, 12, S. 1495-1500
Format: E-Article
Sprache: Englisch
veröffentlicht:
Walter de Gruyter GmbH
Schlagwörter:
General Chemistry
author_facet Robl, Christian
Weiss, Armin
Robl, Christian
Weiss, Armin
author Robl, Christian
Weiss, Armin
spellingShingle Robl, Christian
Weiss, Armin
Zeitschrift für Naturforschung B
Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
General Chemistry
author_sort robl, christian
spelling Robl, Christian Weiss, Armin 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1986-1203 <jats:title>Abstract</jats:title> <jats:p>BaC<jats:sub>6</jats:sub>X<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub> · 3H<jats:sub>2</jats:sub>O (X = Cl, Br) crystallizes in the orthorhombic space group Cmca. 4 of the 8 oxygen atoms around Ba<jats:sup>2+</jats:sup> belong to two different dianions, chelating Ba<jats:sup>2+</jats:sup>. In this way 1-dimensional corrugated chains are formed, interlinked by two oxygen atoms of neighbouring chains, thus forming layers. This interconnection is of polar character within a layer. The in­terlinking oxygen atoms have one carbon- and two Ba<jats:sup>2+</jats:sup> neighbours. CN 8 is completed by two water molecules. The latter and a further water molecule situated between the layers may be removed reversibly in a topochemical reaction without destruction of the structure. </jats:p> Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC<sub>6</sub>X<sub>2</sub>O<sub>4</sub> · 3 H<sub>2</sub>O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC<sub>6</sub>X<sub>2</sub>O<sub>4</sub> · 3 H<sub>2</sub>O (X = Cl, Br) Zeitschrift für Naturforschung B
doi_str_mv 10.1515/znb-1986-1203
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imprint Walter de Gruyter GmbH, 1986
imprint_str_mv Walter de Gruyter GmbH, 1986
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publishDateSort 1986
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title Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_unstemmed Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_full Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_fullStr Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_full_unstemmed Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_short Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_sort komplexe mit substituierten 2,5-dihydroxy-p-benzochinonen: das isotype paar bac<sub>6</sub>x<sub>2</sub>o<sub>4</sub> · 3 h<sub>2</sub>o (x = cl, br) / complexes with substituted 2,5-dihydroxy-p-benzochinones: the isotypic pair bac<sub>6</sub>x<sub>2</sub>o<sub>4</sub> · 3 h<sub>2</sub>o (x = cl, br)
topic General Chemistry
url http://dx.doi.org/10.1515/znb-1986-1203
publishDate 1986
physical 1495-1500
description <jats:title>Abstract</jats:title> <jats:p>BaC<jats:sub>6</jats:sub>X<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub> · 3H<jats:sub>2</jats:sub>O (X = Cl, Br) crystallizes in the orthorhombic space group Cmca. 4 of the 8 oxygen atoms around Ba<jats:sup>2+</jats:sup> belong to two different dianions, chelating Ba<jats:sup>2+</jats:sup>. In this way 1-dimensional corrugated chains are formed, interlinked by two oxygen atoms of neighbouring chains, thus forming layers. This interconnection is of polar character within a layer. The in­terlinking oxygen atoms have one carbon- and two Ba<jats:sup>2+</jats:sup> neighbours. CN 8 is completed by two water molecules. The latter and a further water molecule situated between the layers may be removed reversibly in a topochemical reaction without destruction of the structure. </jats:p>
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author Robl, Christian, Weiss, Armin
author_facet Robl, Christian, Weiss, Armin, Robl, Christian, Weiss, Armin
author_sort robl, christian
container_issue 12
container_start_page 1495
container_title Zeitschrift für Naturforschung B
container_volume 41
description <jats:title>Abstract</jats:title> <jats:p>BaC<jats:sub>6</jats:sub>X<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub> · 3H<jats:sub>2</jats:sub>O (X = Cl, Br) crystallizes in the orthorhombic space group Cmca. 4 of the 8 oxygen atoms around Ba<jats:sup>2+</jats:sup> belong to two different dianions, chelating Ba<jats:sup>2+</jats:sup>. In this way 1-dimensional corrugated chains are formed, interlinked by two oxygen atoms of neighbouring chains, thus forming layers. This interconnection is of polar character within a layer. The in­terlinking oxygen atoms have one carbon- and two Ba<jats:sup>2+</jats:sup> neighbours. CN 8 is completed by two water molecules. The latter and a further water molecule situated between the layers may be removed reversibly in a topochemical reaction without destruction of the structure. </jats:p>
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institution DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275
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spelling Robl, Christian Weiss, Armin 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1986-1203 <jats:title>Abstract</jats:title> <jats:p>BaC<jats:sub>6</jats:sub>X<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub> · 3H<jats:sub>2</jats:sub>O (X = Cl, Br) crystallizes in the orthorhombic space group Cmca. 4 of the 8 oxygen atoms around Ba<jats:sup>2+</jats:sup> belong to two different dianions, chelating Ba<jats:sup>2+</jats:sup>. In this way 1-dimensional corrugated chains are formed, interlinked by two oxygen atoms of neighbouring chains, thus forming layers. This interconnection is of polar character within a layer. The in­terlinking oxygen atoms have one carbon- and two Ba<jats:sup>2+</jats:sup> neighbours. CN 8 is completed by two water molecules. The latter and a further water molecule situated between the layers may be removed reversibly in a topochemical reaction without destruction of the structure. </jats:p> Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC<sub>6</sub>X<sub>2</sub>O<sub>4</sub> · 3 H<sub>2</sub>O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC<sub>6</sub>X<sub>2</sub>O<sub>4</sub> · 3 H<sub>2</sub>O (X = Cl, Br) Zeitschrift für Naturforschung B
spellingShingle Robl, Christian, Weiss, Armin, Zeitschrift für Naturforschung B, Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br), General Chemistry
title Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_full Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_fullStr Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_full_unstemmed Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_short Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
title_sort komplexe mit substituierten 2,5-dihydroxy-p-benzochinonen: das isotype paar bac<sub>6</sub>x<sub>2</sub>o<sub>4</sub> · 3 h<sub>2</sub>o (x = cl, br) / complexes with substituted 2,5-dihydroxy-p-benzochinones: the isotypic pair bac<sub>6</sub>x<sub>2</sub>o<sub>4</sub> · 3 h<sub>2</sub>o (x = cl, br)
title_unstemmed Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: Das isotype Paar BaC6X2O4 · 3 H2O (X = Cl, Br) / Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: The Isotypic Pair BaC6X2O4 · 3 H2O (X = Cl, Br)
topic General Chemistry
url http://dx.doi.org/10.1515/znb-1986-1203