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Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+)
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für Naturforschung B, 41, 1986, 12, S. 1501-1505 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Weiss, Armin Riegler, Eugen Robl, Christian Weiss, Armin Riegler, Eugen Robl, Christian |
|---|---|
| author |
Weiss, Armin Riegler, Eugen Robl, Christian |
| spellingShingle |
Weiss, Armin Riegler, Eugen Robl, Christian Zeitschrift für Naturforschung B Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) General Chemistry |
| author_sort |
weiss, armin |
| spelling |
Weiss, Armin Riegler, Eugen Robl, Christian 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1986-1204 <jats:title>Abstract</jats:title> <jats:p>The isotypic compounds Na<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>24</jats:sub>[M<jats:sub>2</jats:sub>(C<jats:sub>6</jats:sub>H<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>] (M = Mn<jats:sup>2+</jats:sup>, Cd<jats:sup>2+</jats:sup>) form infinite net-like layers. The transition metal ion is coordinated octahedrally. The dianion of 2,5-dihydroxy-1.4- benzoquinone, consisting of two allyl systems interlinked by two long C-C distances (152-153 pm), acts as a chelating ligand. Adjacent layers are connected by hydrogen bonds. The stacking sequence of these layers, ···AAA···, leads to channels, which are filled by hydrated Na<jats:sup>+ </jats:sup>ions. The Na<jats:sup>+</jats:sup> ions are coordinated in a distorted octahedral fashion, with neighbouring octahedra sharing common faces. </jats:p> Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na<sub>2</sub>(H<sub>2</sub>O)<sub>24</sub>[M<sub>2</sub>(C<sub>6</sub>H<sub>2</sub>O<sub>4</sub>)<sub>3</sub>] (M = Mn<sup>2+</sup>, Cd<sup>2+</sup>) Zeitschrift für Naturforschung B |
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10.1515/znb-1986-1204 |
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Online Free |
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ElectronicArticle |
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ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTUxNS96bmItMTk4Ni0xMjA0 |
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DE-Bn3 DE-Brt1 DE-Zwi2 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 DE-D275 |
| imprint |
Walter de Gruyter GmbH, 1986 |
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Walter de Gruyter GmbH, 1986 |
| issn |
0932-0776 1865-7117 |
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English |
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1986 |
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Zeitschrift für Naturforschung B |
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| title |
Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_unstemmed |
Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_full |
Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_fullStr |
Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_full_unstemmed |
Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_short |
Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_sort |
polymerie 2,5-dihydroxy-1,4-benzoquinone transition metal complexes na<sub>2</sub>(h<sub>2</sub>o)<sub>24</sub>[m<sub>2</sub>(c<sub>6</sub>h<sub>2</sub>o<sub>4</sub>)<sub>3</sub>] (m = mn<sup>2+</sup>, cd<sup>2+</sup>) |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-1986-1204 |
| publishDate |
1986 |
| physical |
1501-1505 |
| description |
<jats:title>Abstract</jats:title>
<jats:p>The isotypic compounds Na<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>24</jats:sub>[M<jats:sub>2</jats:sub>(C<jats:sub>6</jats:sub>H<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>] (M = Mn<jats:sup>2+</jats:sup>, Cd<jats:sup>2+</jats:sup>) form infinite net-like layers. The transition metal ion is coordinated octahedrally. The dianion of 2,5-dihydroxy-1.4- benzoquinone, consisting of two allyl systems interlinked by two long C-C distances (152-153 pm), acts as a chelating ligand. Adjacent layers are connected by hydrogen bonds. The stacking sequence of these layers, ···AAA···, leads to channels, which are filled by hydrated Na<jats:sup>+ </jats:sup>ions. The Na<jats:sup>+</jats:sup> ions are coordinated in a distorted octahedral fashion, with neighbouring octahedra sharing common faces. </jats:p> |
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url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Polymerie+2%2C5-Dihydroxy-1%2C4-benzoquinone+Transition+Metal+Complexes+Na2%28H2O%2924%5BM2%28C6H2O4%293%5D+%28M+%3D+Mn2%2B%2C+Cd2%2B%29&rft.date=1986-12-01&genre=article&issn=0932-0776&volume=41&issue=12&spage=1501&epage=1505&pages=1501-1505&jtitle=Zeitschrift+f%C3%BCr+Naturforschung+B&atitle=Polymerie+2%2C5-Dihydroxy-1%2C4-benzoquinone+Transition+Metal+Complexes+Na%3Csub%3E2%3C%2Fsub%3E%28H%3Csub%3E2%3C%2Fsub%3EO%29%3Csub%3E24%3C%2Fsub%3E%5BM%3Csub%3E2%3C%2Fsub%3E%28C%3Csub%3E6%3C%2Fsub%3EH%3Csub%3E2%3C%2Fsub%3EO%3Csub%3E4%3C%2Fsub%3E%29%3Csub%3E3%3C%2Fsub%3E%5D+%28M+%3D+Mn%3Csup%3E2%2B%3C%2Fsup%3E%2C+Cd%3Csup%3E2%2B%3C%2Fsup%3E%29&aulast=Robl&aufirst=Christian&rft_id=info%3Adoi%2F10.1515%2Fznb-1986-1204&rft.language%5B0%5D=eng |
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| author | Weiss, Armin, Riegler, Eugen, Robl, Christian |
| author_facet | Weiss, Armin, Riegler, Eugen, Robl, Christian, Weiss, Armin, Riegler, Eugen, Robl, Christian |
| author_sort | weiss, armin |
| container_issue | 12 |
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| container_title | Zeitschrift für Naturforschung B |
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| description | <jats:title>Abstract</jats:title> <jats:p>The isotypic compounds Na<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>24</jats:sub>[M<jats:sub>2</jats:sub>(C<jats:sub>6</jats:sub>H<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>] (M = Mn<jats:sup>2+</jats:sup>, Cd<jats:sup>2+</jats:sup>) form infinite net-like layers. The transition metal ion is coordinated octahedrally. The dianion of 2,5-dihydroxy-1.4- benzoquinone, consisting of two allyl systems interlinked by two long C-C distances (152-153 pm), acts as a chelating ligand. Adjacent layers are connected by hydrogen bonds. The stacking sequence of these layers, ···AAA···, leads to channels, which are filled by hydrated Na<jats:sup>+ </jats:sup>ions. The Na<jats:sup>+</jats:sup> ions are coordinated in a distorted octahedral fashion, with neighbouring octahedra sharing common faces. </jats:p> |
| doi_str_mv | 10.1515/znb-1986-1204 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTUxNS96bmItMTk4Ni0xMjA0 |
| imprint | Walter de Gruyter GmbH, 1986 |
| imprint_str_mv | Walter de Gruyter GmbH, 1986 |
| institution | DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275 |
| issn | 0932-0776, 1865-7117 |
| issn_str_mv | 0932-0776, 1865-7117 |
| language | English |
| last_indexed | 2024-03-01T17:01:03.28Z |
| match_str | weiss1986polymerie25dihydroxy14benzoquinonetransitionmetalcomplexesna2h2o24m2c6h2o43mmn2cd2 |
| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 1501-1505 |
| publishDate | 1986 |
| publishDateSort | 1986 |
| publisher | Walter de Gruyter GmbH |
| record_format | ai |
| recordtype | ai |
| series | Zeitschrift für Naturforschung B |
| source_id | 49 |
| spelling | Weiss, Armin Riegler, Eugen Robl, Christian 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1986-1204 <jats:title>Abstract</jats:title> <jats:p>The isotypic compounds Na<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>24</jats:sub>[M<jats:sub>2</jats:sub>(C<jats:sub>6</jats:sub>H<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>] (M = Mn<jats:sup>2+</jats:sup>, Cd<jats:sup>2+</jats:sup>) form infinite net-like layers. The transition metal ion is coordinated octahedrally. The dianion of 2,5-dihydroxy-1.4- benzoquinone, consisting of two allyl systems interlinked by two long C-C distances (152-153 pm), acts as a chelating ligand. Adjacent layers are connected by hydrogen bonds. The stacking sequence of these layers, ···AAA···, leads to channels, which are filled by hydrated Na<jats:sup>+ </jats:sup>ions. The Na<jats:sup>+</jats:sup> ions are coordinated in a distorted octahedral fashion, with neighbouring octahedra sharing common faces. </jats:p> Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na<sub>2</sub>(H<sub>2</sub>O)<sub>24</sub>[M<sub>2</sub>(C<sub>6</sub>H<sub>2</sub>O<sub>4</sub>)<sub>3</sub>] (M = Mn<sup>2+</sup>, Cd<sup>2+</sup>) Zeitschrift für Naturforschung B |
| spellingShingle | Weiss, Armin, Riegler, Eugen, Robl, Christian, Zeitschrift für Naturforschung B, Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+), General Chemistry |
| title | Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_full | Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_fullStr | Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_full_unstemmed | Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_short | Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| title_sort | polymerie 2,5-dihydroxy-1,4-benzoquinone transition metal complexes na<sub>2</sub>(h<sub>2</sub>o)<sub>24</sub>[m<sub>2</sub>(c<sub>6</sub>h<sub>2</sub>o<sub>4</sub>)<sub>3</sub>] (m = mn<sup>2+</sup>, cd<sup>2+</sup>) |
| title_unstemmed | Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-1986-1204 |