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Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC...
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für Naturforschung B, 41, 1986, 11, S. 1333-1336 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Weiss, Armin Riegler, Eugen Robl, Christian Weiss, Armin Riegler, Eugen Robl, Christian |
|---|---|
| author |
Weiss, Armin Riegler, Eugen Robl, Christian |
| spellingShingle |
Weiss, Armin Riegler, Eugen Robl, Christian Zeitschrift für Naturforschung B Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) General Chemistry |
| author_sort |
weiss, armin |
| spelling |
Weiss, Armin Riegler, Eugen Robl, Christian 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1986-1102 <jats:title>Abstract</jats:title> <jats:p> The isostructural compounds (MC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O)<jats:sub>3</jats:sub>·CH<jats:sub>3</jats:sub>COOH·H<jats:sub>2</jats:sub>O (M=Zn<jats:sup>2+</jats:sup>,Mn<jats:sup>2+</jats:sup>) crystallize in the triclinic space group P1̄, if grown in solution of high ionic strength. The structural features are similar to those in the cubic phase. Correspondingly CH<jats:sub>3</jats:sub>COOH·H<jats:sub>2</jats:sub>O can be trapped in cage like cavities, formed by the 3-dimensional framework o f M<jats:sup>2+</jats:sup> and C<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub> <jats:sup>2-</jats:sup> . The metal ions are coordinated in a distorted octahedral fashion. The squarate dianions act as four-fold monodentate ligands.</jats:p> Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC<sub>4</sub>O<sub>4</sub>·2 H<sub>2</sub>O)<sub>3</sub>·CH<sub>3</sub>COOH·H<sub>2</sub>O(M = Zn<sup>2+</sup>, Mn<sup>2+</sup>)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC<sub>4</sub>O<sub>4</sub>·2 H<sub>2</sub>O)<sub>3</sub>-CH<sub>3</sub>COOH·H<sub>2</sub>O(M = Zn<sup>2+</sup>, Mn<sup>2+</sup>) Zeitschrift für Naturforschung B |
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10.1515/znb-1986-1102 |
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Online Free |
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Walter de Gruyter GmbH, 1986 |
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Walter de Gruyter GmbH, 1986 |
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1865-7117 0932-0776 |
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1865-7117 0932-0776 |
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Walter de Gruyter GmbH (CrossRef) |
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Zeitschrift für Naturforschung B |
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49 |
| title |
Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_unstemmed |
Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_full |
Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_fullStr |
Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_full_unstemmed |
Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_short |
Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_sort |
übergangsmetallquadratate, iii über die trikline käfigstruktur des (mc<sub>4</sub>o<sub>4</sub>·2 h<sub>2</sub>o)<sub>3</sub>·ch<sub>3</sub>cooh·h<sub>2</sub>o(m = zn<sup>2+</sup>, mn<sup>2+</sup>)/transition metal squarates, iii on the triclinic cage structure of (mc<sub>4</sub>o<sub>4</sub>·2 h<sub>2</sub>o)<sub>3</sub>-ch<sub>3</sub>cooh·h<sub>2</sub>o(m = zn<sup>2+</sup>, mn<sup>2+</sup>) |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-1986-1102 |
| publishDate |
1986 |
| physical |
1333-1336 |
| description |
<jats:title>Abstract</jats:title>
<jats:p> The isostructural compounds (MC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O)<jats:sub>3</jats:sub>·CH<jats:sub>3</jats:sub>COOH·H<jats:sub>2</jats:sub>O (M=Zn<jats:sup>2+</jats:sup>,Mn<jats:sup>2+</jats:sup>) crystallize in the triclinic space group P1̄, if grown in solution of high ionic strength. The structural features are similar to those in the cubic phase. Correspondingly CH<jats:sub>3</jats:sub>COOH·H<jats:sub>2</jats:sub>O can be trapped in cage like cavities, formed by the 3-dimensional framework o f M<jats:sup>2+</jats:sup> and C<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>
<jats:sup>2-</jats:sup> . The metal ions are coordinated in a distorted octahedral fashion. The squarate dianions act as four-fold monodentate ligands.</jats:p> |
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| description | <jats:title>Abstract</jats:title> <jats:p> The isostructural compounds (MC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O)<jats:sub>3</jats:sub>·CH<jats:sub>3</jats:sub>COOH·H<jats:sub>2</jats:sub>O (M=Zn<jats:sup>2+</jats:sup>,Mn<jats:sup>2+</jats:sup>) crystallize in the triclinic space group P1̄, if grown in solution of high ionic strength. The structural features are similar to those in the cubic phase. Correspondingly CH<jats:sub>3</jats:sub>COOH·H<jats:sub>2</jats:sub>O can be trapped in cage like cavities, formed by the 3-dimensional framework o f M<jats:sup>2+</jats:sup> and C<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub> <jats:sup>2-</jats:sup> . The metal ions are coordinated in a distorted octahedral fashion. The squarate dianions act as four-fold monodentate ligands.</jats:p> |
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| imprint | Walter de Gruyter GmbH, 1986 |
| imprint_str_mv | Walter de Gruyter GmbH, 1986 |
| institution | DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14 |
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| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 1333-1336 |
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| spelling | Weiss, Armin Riegler, Eugen Robl, Christian 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1986-1102 <jats:title>Abstract</jats:title> <jats:p> The isostructural compounds (MC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O)<jats:sub>3</jats:sub>·CH<jats:sub>3</jats:sub>COOH·H<jats:sub>2</jats:sub>O (M=Zn<jats:sup>2+</jats:sup>,Mn<jats:sup>2+</jats:sup>) crystallize in the triclinic space group P1̄, if grown in solution of high ionic strength. The structural features are similar to those in the cubic phase. Correspondingly CH<jats:sub>3</jats:sub>COOH·H<jats:sub>2</jats:sub>O can be trapped in cage like cavities, formed by the 3-dimensional framework o f M<jats:sup>2+</jats:sup> and C<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub> <jats:sup>2-</jats:sup> . The metal ions are coordinated in a distorted octahedral fashion. The squarate dianions act as four-fold monodentate ligands.</jats:p> Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC<sub>4</sub>O<sub>4</sub>·2 H<sub>2</sub>O)<sub>3</sub>·CH<sub>3</sub>COOH·H<sub>2</sub>O(M = Zn<sup>2+</sup>, Mn<sup>2+</sup>)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC<sub>4</sub>O<sub>4</sub>·2 H<sub>2</sub>O)<sub>3</sub>-CH<sub>3</sub>COOH·H<sub>2</sub>O(M = Zn<sup>2+</sup>, Mn<sup>2+</sup>) Zeitschrift für Naturforschung B |
| spellingShingle | Weiss, Armin, Riegler, Eugen, Robl, Christian, Zeitschrift für Naturforschung B, Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+), General Chemistry |
| title | Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_full | Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_fullStr | Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_full_unstemmed | Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_short | Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| title_sort | übergangsmetallquadratate, iii über die trikline käfigstruktur des (mc<sub>4</sub>o<sub>4</sub>·2 h<sub>2</sub>o)<sub>3</sub>·ch<sub>3</sub>cooh·h<sub>2</sub>o(m = zn<sup>2+</sup>, mn<sup>2+</sup>)/transition metal squarates, iii on the triclinic cage structure of (mc<sub>4</sub>o<sub>4</sub>·2 h<sub>2</sub>o)<sub>3</sub>-ch<sub>3</sub>cooh·h<sub>2</sub>o(m = zn<sup>2+</sup>, mn<sup>2+</sup>) |
| title_unstemmed | Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+) |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-1986-1102 |