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Synthesis and Crystal Structure of CuC4O4·2 H2O
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , |
| In: | Zeitschrift für Naturforschung B, 41, 1986, 11, S. 1341-1345 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Robl, Christian Weiss, Armin Robl, Christian Weiss, Armin |
|---|---|
| author |
Robl, Christian Weiss, Armin |
| spellingShingle |
Robl, Christian Weiss, Armin Zeitschrift für Naturforschung B Synthesis and Crystal Structure of CuC4O4·2 H2O General Chemistry |
| author_sort |
robl, christian |
| spelling |
Robl, Christian Weiss, Armin 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1986-1104 <jats:title>Abstract</jats:title> <jats:p> The monoclinic compound CuC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O (space group P 2<jats:sub>1</jats:sub>/c) was prepared from aqueous acetate buffered solution. The structure was solved from a twinned crystal. Chains consisting of squarate dianions and Cu<jats:sup>2+</jats:sup> , which is coordinated octahedrally in a strongly distorted manner, are the main feature. Only two squarate oxygen atoms contribute considerably to the coordination of Cu<jats:sup>2+</jats:sup>. Neighbouring chains share common oxygen atoms (H<jats:sub>2</jats:sub>O . O<jats:sub>squarate</jats:sub>) of the coordination polyhedra. Furthermore the chains are very probably interlinked by strong hydrogen bonds. Thermal decomposition of CuC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O leads to CuO.</jats:p> Synthesis and Crystal Structure of CuC<sub>4</sub>O<sub>4</sub>·2 H<sub>2</sub>O Zeitschrift für Naturforschung B |
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Walter de Gruyter GmbH, 1986 |
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Walter de Gruyter GmbH |
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Zeitschrift für Naturforschung B |
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| title |
Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_unstemmed |
Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_full |
Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_fullStr |
Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_full_unstemmed |
Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_short |
Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_sort |
synthesis and crystal structure of cuc<sub>4</sub>o<sub>4</sub>·2 h<sub>2</sub>o |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-1986-1104 |
| publishDate |
1986 |
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1341-1345 |
| description |
<jats:title>Abstract</jats:title>
<jats:p> The monoclinic compound CuC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O (space group P 2<jats:sub>1</jats:sub>/c) was prepared from aqueous acetate buffered solution. The structure was solved from a twinned crystal. Chains consisting of squarate dianions and Cu<jats:sup>2+</jats:sup> , which is coordinated octahedrally in a strongly distorted manner, are the main feature. Only two squarate oxygen atoms contribute considerably to the coordination of Cu<jats:sup>2+</jats:sup>. Neighbouring chains share common oxygen atoms (H<jats:sub>2</jats:sub>O . O<jats:sub>squarate</jats:sub>) of the coordination polyhedra. Furthermore the chains are very probably interlinked by strong hydrogen bonds. Thermal decomposition of CuC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O leads to CuO.</jats:p> |
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| description | <jats:title>Abstract</jats:title> <jats:p> The monoclinic compound CuC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O (space group P 2<jats:sub>1</jats:sub>/c) was prepared from aqueous acetate buffered solution. The structure was solved from a twinned crystal. Chains consisting of squarate dianions and Cu<jats:sup>2+</jats:sup> , which is coordinated octahedrally in a strongly distorted manner, are the main feature. Only two squarate oxygen atoms contribute considerably to the coordination of Cu<jats:sup>2+</jats:sup>. Neighbouring chains share common oxygen atoms (H<jats:sub>2</jats:sub>O . O<jats:sub>squarate</jats:sub>) of the coordination polyhedra. Furthermore the chains are very probably interlinked by strong hydrogen bonds. Thermal decomposition of CuC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O leads to CuO.</jats:p> |
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| imprint | Walter de Gruyter GmbH, 1986 |
| imprint_str_mv | Walter de Gruyter GmbH, 1986 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161 |
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| physical | 1341-1345 |
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| series | Zeitschrift für Naturforschung B |
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| spelling | Robl, Christian Weiss, Armin 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1986-1104 <jats:title>Abstract</jats:title> <jats:p> The monoclinic compound CuC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O (space group P 2<jats:sub>1</jats:sub>/c) was prepared from aqueous acetate buffered solution. The structure was solved from a twinned crystal. Chains consisting of squarate dianions and Cu<jats:sup>2+</jats:sup> , which is coordinated octahedrally in a strongly distorted manner, are the main feature. Only two squarate oxygen atoms contribute considerably to the coordination of Cu<jats:sup>2+</jats:sup>. Neighbouring chains share common oxygen atoms (H<jats:sub>2</jats:sub>O . O<jats:sub>squarate</jats:sub>) of the coordination polyhedra. Furthermore the chains are very probably interlinked by strong hydrogen bonds. Thermal decomposition of CuC<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>·2 H<jats:sub>2</jats:sub>O leads to CuO.</jats:p> Synthesis and Crystal Structure of CuC<sub>4</sub>O<sub>4</sub>·2 H<sub>2</sub>O Zeitschrift für Naturforschung B |
| spellingShingle | Robl, Christian, Weiss, Armin, Zeitschrift für Naturforschung B, Synthesis and Crystal Structure of CuC4O4·2 H2O, General Chemistry |
| title | Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_full | Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_fullStr | Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_full_unstemmed | Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_short | Synthesis and Crystal Structure of CuC4O4·2 H2O |
| title_sort | synthesis and crystal structure of cuc<sub>4</sub>o<sub>4</sub>·2 h<sub>2</sub>o |
| title_unstemmed | Synthesis and Crystal Structure of CuC4O4·2 H2O |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-1986-1104 |