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Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1]
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , |
| In: | Zeitschrift für Naturforschung B, 40, 1985, 11, S. 1481-1484 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Sebald, Angelika Wrackmeyer, Bernd Sebald, Angelika Wrackmeyer, Bernd |
|---|---|
| author |
Sebald, Angelika Wrackmeyer, Bernd |
| spellingShingle |
Sebald, Angelika Wrackmeyer, Bernd Zeitschrift für Naturforschung B Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] General Chemistry |
| author_sort |
sebald, angelika |
| spelling |
Sebald, Angelika Wrackmeyer, Bernd 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1985-1110 <jats:p>The reaction of [dppmPtCl<jats:sub>2</jats:sub>] (dppm = bis(diphenylphosphino)methane) with bis(alkynyl)-dimethylstannanes leads to monomeric complexes [dppmPt(C≡C−R)<jats:sub>2</jats:sub>], 2 (R = H, CH<jats:sub>3</jats:sub>, C<jats:sub>4</jats:sub>H<jats:sub>9</jats:sub> <jats:sup>t</jats:sup>, C<jats:sub>6</jats:sub>H<jats:sub>5</jats:sub>) in >90% yield. Rearrangement of 2 into the dimeric complexes 3, trans,trans- [Pt<jats:sub>2</jats:sub>(C≡C−R)<jats:sub>4</jats:sub>(dppm)<jats:sub>2</jats:sub>] is catalyzed by traces of various phosphanes. All products are characterized by <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, <jats:sup>31</jats:sup>P and <jats:sup>195</jats:sup>Pt NMR spectroscopy. </jats:p> Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] Zeitschrift für Naturforschung B |
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10.1515/znb-1985-1110 |
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Online Free |
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ElectronicArticle |
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DE-D275 DE-Bn3 DE-Brt1 DE-Zwi2 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 |
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Walter de Gruyter GmbH, 1985 |
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Walter de Gruyter GmbH, 1985 |
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0932-0776 1865-7117 |
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0932-0776 1865-7117 |
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Walter de Gruyter GmbH (CrossRef) |
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sebald1985monomerebisdiphenylphosphinomethanplatinacetylidkomplexe1monomericbisdiphenylphosphinomethanplatinumacetylidecomplexes1 |
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1985 |
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Walter de Gruyter GmbH |
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ai |
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Zeitschrift für Naturforschung B |
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49 |
| title |
Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_unstemmed |
Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_full |
Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_fullStr |
Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_full_unstemmed |
Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_short |
Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_sort |
monomere [bis(diphenylphosphino)methan]platin-acetylid-komplexe [1] / monomeric [bis(diphenylphosphino)methan]platinum acetylide complexes [1] |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-1985-1110 |
| publishDate |
1985 |
| physical |
1481-1484 |
| description |
<jats:p>The reaction of [dppmPtCl<jats:sub>2</jats:sub>] (dppm = bis(diphenylphosphino)methane) with bis(alkynyl)-dimethylstannanes leads to monomeric complexes [dppmPt(C≡C−R)<jats:sub>2</jats:sub>], 2 (R = H, CH<jats:sub>3</jats:sub>, C<jats:sub>4</jats:sub>H<jats:sub>9</jats:sub>
<jats:sup>t</jats:sup>, C<jats:sub>6</jats:sub>H<jats:sub>5</jats:sub>) in >90% yield. Rearrangement of 2 into the dimeric complexes 3, trans,trans- [Pt<jats:sub>2</jats:sub>(C≡C−R)<jats:sub>4</jats:sub>(dppm)<jats:sub>2</jats:sub>] is catalyzed by traces of various phosphanes. All products are characterized by <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, <jats:sup>31</jats:sup>P and <jats:sup>195</jats:sup>Pt NMR spectroscopy. </jats:p> |
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| author | Sebald, Angelika, Wrackmeyer, Bernd |
| author_facet | Sebald, Angelika, Wrackmeyer, Bernd, Sebald, Angelika, Wrackmeyer, Bernd |
| author_sort | sebald, angelika |
| container_issue | 11 |
| container_start_page | 1481 |
| container_title | Zeitschrift für Naturforschung B |
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| description | <jats:p>The reaction of [dppmPtCl<jats:sub>2</jats:sub>] (dppm = bis(diphenylphosphino)methane) with bis(alkynyl)-dimethylstannanes leads to monomeric complexes [dppmPt(C≡C−R)<jats:sub>2</jats:sub>], 2 (R = H, CH<jats:sub>3</jats:sub>, C<jats:sub>4</jats:sub>H<jats:sub>9</jats:sub> <jats:sup>t</jats:sup>, C<jats:sub>6</jats:sub>H<jats:sub>5</jats:sub>) in >90% yield. Rearrangement of 2 into the dimeric complexes 3, trans,trans- [Pt<jats:sub>2</jats:sub>(C≡C−R)<jats:sub>4</jats:sub>(dppm)<jats:sub>2</jats:sub>] is catalyzed by traces of various phosphanes. All products are characterized by <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, <jats:sup>31</jats:sup>P and <jats:sup>195</jats:sup>Pt NMR spectroscopy. </jats:p> |
| doi_str_mv | 10.1515/znb-1985-1110 |
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| format_dezwi2 | Article, E-Article |
| format_finc | Article, E-Article |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTUxNS96bmItMTk4NS0xMTEw |
| imprint | Walter de Gruyter GmbH, 1985 |
| imprint_str_mv | Walter de Gruyter GmbH, 1985 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
| issn | 0932-0776, 1865-7117 |
| issn_str_mv | 0932-0776, 1865-7117 |
| language | English |
| last_indexed | 2024-03-01T15:05:18.904Z |
| match_str | sebald1985monomerebisdiphenylphosphinomethanplatinacetylidkomplexe1monomericbisdiphenylphosphinomethanplatinumacetylidecomplexes1 |
| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 1481-1484 |
| publishDate | 1985 |
| publishDateSort | 1985 |
| publisher | Walter de Gruyter GmbH |
| record_format | ai |
| recordtype | ai |
| series | Zeitschrift für Naturforschung B |
| source_id | 49 |
| spelling | Sebald, Angelika Wrackmeyer, Bernd 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1985-1110 <jats:p>The reaction of [dppmPtCl<jats:sub>2</jats:sub>] (dppm = bis(diphenylphosphino)methane) with bis(alkynyl)-dimethylstannanes leads to monomeric complexes [dppmPt(C≡C−R)<jats:sub>2</jats:sub>], 2 (R = H, CH<jats:sub>3</jats:sub>, C<jats:sub>4</jats:sub>H<jats:sub>9</jats:sub> <jats:sup>t</jats:sup>, C<jats:sub>6</jats:sub>H<jats:sub>5</jats:sub>) in >90% yield. Rearrangement of 2 into the dimeric complexes 3, trans,trans- [Pt<jats:sub>2</jats:sub>(C≡C−R)<jats:sub>4</jats:sub>(dppm)<jats:sub>2</jats:sub>] is catalyzed by traces of various phosphanes. All products are characterized by <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, <jats:sup>31</jats:sup>P and <jats:sup>195</jats:sup>Pt NMR spectroscopy. </jats:p> Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] Zeitschrift für Naturforschung B |
| spellingShingle | Sebald, Angelika, Wrackmeyer, Bernd, Zeitschrift für Naturforschung B, Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1], General Chemistry |
| title | Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_full | Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_fullStr | Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_full_unstemmed | Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_short | Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| title_sort | monomere [bis(diphenylphosphino)methan]platin-acetylid-komplexe [1] / monomeric [bis(diphenylphosphino)methan]platinum acetylide complexes [1] |
| title_unstemmed | Monomere [Bis(diphenylphosphino)methan]platin-acetylid-Komplexe [1] / Monomeric [Bis(diphenylphosphino)methan]platinum Acetylide Complexes [1] |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-1985-1110 |