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Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(...
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , |
| In: | Zeitschrift für Naturforschung B, 36, 1981, 6, S. 662-665 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Schweda, Eberhard Strähle, Joachim Schweda, Eberhard Strähle, Joachim |
|---|---|
| author |
Schweda, Eberhard Strähle, Joachim |
| spellingShingle |
Schweda, Eberhard Strähle, Joachim Zeitschrift für Naturforschung B Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) General Chemistry |
| author_sort |
schweda, eberhard |
| spelling |
Schweda, Eberhard Strähle, Joachim 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1981-0602 <jats:title>Abstract</jats:title> <jats:p> The explosive nitrido azido complexes MoN(N<jats:sub>3</jats:sub>)Cl<jats:sub>2</jats:sub> · py and MoN(N<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>py are prepared by the reaction of MoCl<jats:sub>4</jats:sub>(py)<jats:sub>2</jats:sub> with (CH<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>SiN<jats:sub>3</jats:sub> in 1,2-dichloroethane. Both compounds hydrolyze quickly in moist air. After separation of the insoluble, black MoN(N<jats:sub>3</jats:sub>)Cl<jats:sub>2</jats:sub> · py from the solution of MoN(N<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>py, the latter can be obtained in form of monoclinic, red crystals of the space group C2/c. Its structure consists of monomeric complexes, wherein the Mo atom has a square pyramidal coordination. The nitrido ligand occupies the apex and forms a strong multiple bond of 163.4 pm to the Mo atom. σ-Bonds of different strength exist between the Mo atom and the basal ligands: MO-N<jats:sub>3</jats:sub> - 204.3 pm; Mo-py = 225.8 pm. The α-N atoms of the azido groups are sp<jats:sup>2</jats:sup> hybridized, with their lone pair pointing away from the nitrido ligand. The pyridine ligand forms an angle of 61.6° to the basal plane of the coordination polyhedron.</jats:p> Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N<sub>3</sub>)<sub>3</sub>(NC<sub>5</sub>H<sub>5</sub>) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N<sub>3</sub>)<sub>3</sub>(NC<sub>5</sub>H<sub>5</sub>) Zeitschrift für Naturforschung B |
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10.1515/znb-1981-0602 |
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Online Free |
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| imprint |
Walter de Gruyter GmbH, 1981 |
| imprint_str_mv |
Walter de Gruyter GmbH, 1981 |
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1865-7117 0932-0776 |
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1865-7117 0932-0776 |
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English |
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Walter de Gruyter GmbH (CrossRef) |
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schweda1981nitridoazidokomplexedesmolybdansvisyntheseundkristallstrukturvonmonn33nc5h5nitridoazidocomplexesofmolybdenumvisynthesisandcrystalstructureofmonn33nc5h5 |
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1981 |
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Walter de Gruyter GmbH |
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Zeitschrift für Naturforschung B |
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49 |
| title |
Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_unstemmed |
Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_full |
Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_fullStr |
Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_full_unstemmed |
Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_short |
Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_sort |
nitrido-azido-komplexe des molybdäns(vi) synthese und kristallstruktur von mon(n<sub>3</sub>)<sub>3</sub>(nc<sub>5</sub>h<sub>5</sub>) / nitrido azido complexes of molybdenum (vi) synthesis and crystal structure of mon(n<sub>3</sub>)<sub>3</sub>(nc<sub>5</sub>h<sub>5</sub>) |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-1981-0602 |
| publishDate |
1981 |
| physical |
662-665 |
| description |
<jats:title>Abstract</jats:title>
<jats:p> The explosive nitrido azido complexes MoN(N<jats:sub>3</jats:sub>)Cl<jats:sub>2</jats:sub> · py and MoN(N<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>py are prepared by the reaction of MoCl<jats:sub>4</jats:sub>(py)<jats:sub>2</jats:sub> with (CH<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>SiN<jats:sub>3</jats:sub> in 1,2-dichloroethane. Both compounds hydrolyze quickly in moist air. After separation of the insoluble, black MoN(N<jats:sub>3</jats:sub>)Cl<jats:sub>2</jats:sub> · py from the solution of MoN(N<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>py, the latter can be obtained in form of monoclinic, red crystals of the space group C2/c. Its structure consists of monomeric complexes, wherein the Mo atom has a square pyramidal coordination. The nitrido ligand occupies the apex and forms a strong multiple bond of 163.4 pm to the Mo atom. σ-Bonds of different strength exist between the Mo atom and the basal ligands: MO-N<jats:sub>3</jats:sub> - 204.3 pm; Mo-py = 225.8 pm. The α-N atoms of the azido groups are sp<jats:sup>2</jats:sup> hybridized, with their lone pair pointing away from the nitrido ligand. The pyridine ligand forms an angle of 61.6° to the basal plane of the coordination polyhedron.</jats:p> |
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url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Nitrido-azido-Komplexe+des+Molybd%C3%A4ns%28VI%29+Synthese+und+Kristallstruktur+von+MoN%28N3%293%28NC5H5%29+%2F+Nitrido+Azido+Complexes+of+Molybdenum+%28VI%29+Synthesis+and+Crystal+Structure+of+MoN%28N3%293%28NC5H5%29&rft.date=1981-06-01&genre=article&issn=0932-0776&volume=36&issue=6&spage=662&epage=665&pages=662-665&jtitle=Zeitschrift+f%C3%BCr+Naturforschung+B&atitle=Nitrido-azido-Komplexe+des+Molybd%C3%A4ns%28VI%29+Synthese+und+Kristallstruktur+von+MoN%28N%3Csub%3E3%3C%2Fsub%3E%29%3Csub%3E3%3C%2Fsub%3E%28NC%3Csub%3E5%3C%2Fsub%3EH%3Csub%3E5%3C%2Fsub%3E%29+%2F+Nitrido+Azido+Complexes+of+Molybdenum+%28VI%29+Synthesis+and+Crystal+Structure+of+MoN%28N%3Csub%3E3%3C%2Fsub%3E%29%3Csub%3E3%3C%2Fsub%3E%28NC%3Csub%3E5%3C%2Fsub%3EH%3Csub%3E5%3C%2Fsub%3E%29&aulast=Str%C3%A4hle&aufirst=Joachim&rft_id=info%3Adoi%2F10.1515%2Fznb-1981-0602&rft.language%5B0%5D=eng |
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| author | Schweda, Eberhard, Strähle, Joachim |
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| description | <jats:title>Abstract</jats:title> <jats:p> The explosive nitrido azido complexes MoN(N<jats:sub>3</jats:sub>)Cl<jats:sub>2</jats:sub> · py and MoN(N<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>py are prepared by the reaction of MoCl<jats:sub>4</jats:sub>(py)<jats:sub>2</jats:sub> with (CH<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>SiN<jats:sub>3</jats:sub> in 1,2-dichloroethane. Both compounds hydrolyze quickly in moist air. After separation of the insoluble, black MoN(N<jats:sub>3</jats:sub>)Cl<jats:sub>2</jats:sub> · py from the solution of MoN(N<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>py, the latter can be obtained in form of monoclinic, red crystals of the space group C2/c. Its structure consists of monomeric complexes, wherein the Mo atom has a square pyramidal coordination. The nitrido ligand occupies the apex and forms a strong multiple bond of 163.4 pm to the Mo atom. σ-Bonds of different strength exist between the Mo atom and the basal ligands: MO-N<jats:sub>3</jats:sub> - 204.3 pm; Mo-py = 225.8 pm. The α-N atoms of the azido groups are sp<jats:sup>2</jats:sup> hybridized, with their lone pair pointing away from the nitrido ligand. The pyridine ligand forms an angle of 61.6° to the basal plane of the coordination polyhedron.</jats:p> |
| doi_str_mv | 10.1515/znb-1981-0602 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTUxNS96bmItMTk4MS0wNjAy |
| imprint | Walter de Gruyter GmbH, 1981 |
| imprint_str_mv | Walter de Gruyter GmbH, 1981 |
| institution | DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15 |
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| match_str | schweda1981nitridoazidokomplexedesmolybdansvisyntheseundkristallstrukturvonmonn33nc5h5nitridoazidocomplexesofmolybdenumvisynthesisandcrystalstructureofmonn33nc5h5 |
| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 662-665 |
| publishDate | 1981 |
| publishDateSort | 1981 |
| publisher | Walter de Gruyter GmbH |
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| recordtype | ai |
| series | Zeitschrift für Naturforschung B |
| source_id | 49 |
| spelling | Schweda, Eberhard Strähle, Joachim 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1981-0602 <jats:title>Abstract</jats:title> <jats:p> The explosive nitrido azido complexes MoN(N<jats:sub>3</jats:sub>)Cl<jats:sub>2</jats:sub> · py and MoN(N<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>py are prepared by the reaction of MoCl<jats:sub>4</jats:sub>(py)<jats:sub>2</jats:sub> with (CH<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>SiN<jats:sub>3</jats:sub> in 1,2-dichloroethane. Both compounds hydrolyze quickly in moist air. After separation of the insoluble, black MoN(N<jats:sub>3</jats:sub>)Cl<jats:sub>2</jats:sub> · py from the solution of MoN(N<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub>py, the latter can be obtained in form of monoclinic, red crystals of the space group C2/c. Its structure consists of monomeric complexes, wherein the Mo atom has a square pyramidal coordination. The nitrido ligand occupies the apex and forms a strong multiple bond of 163.4 pm to the Mo atom. σ-Bonds of different strength exist between the Mo atom and the basal ligands: MO-N<jats:sub>3</jats:sub> - 204.3 pm; Mo-py = 225.8 pm. The α-N atoms of the azido groups are sp<jats:sup>2</jats:sup> hybridized, with their lone pair pointing away from the nitrido ligand. The pyridine ligand forms an angle of 61.6° to the basal plane of the coordination polyhedron.</jats:p> Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N<sub>3</sub>)<sub>3</sub>(NC<sub>5</sub>H<sub>5</sub>) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N<sub>3</sub>)<sub>3</sub>(NC<sub>5</sub>H<sub>5</sub>) Zeitschrift für Naturforschung B |
| spellingShingle | Schweda, Eberhard, Strähle, Joachim, Zeitschrift für Naturforschung B, Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5), General Chemistry |
| title | Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_full | Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_fullStr | Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_full_unstemmed | Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_short | Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| title_sort | nitrido-azido-komplexe des molybdäns(vi) synthese und kristallstruktur von mon(n<sub>3</sub>)<sub>3</sub>(nc<sub>5</sub>h<sub>5</sub>) / nitrido azido complexes of molybdenum (vi) synthesis and crystal structure of mon(n<sub>3</sub>)<sub>3</sub>(nc<sub>5</sub>h<sub>5</sub>) |
| title_unstemmed | Nitrido-azido-Komplexe des Molybdäns(VI) Synthese und Kristallstruktur von MoN(N3)3(NC5H5) / Nitrido Azido Complexes of Molybdenum (VI) Synthesis and Crystal Structure of MoN(N3)3(NC5H5) |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-1981-0602 |