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The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene)
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| Zeitschriftentitel: | Zeitschrift für Naturforschung B |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für Naturforschung B, 35, 1980, 1, S. 25-30 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
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| Schlagwörter: |
| author_facet |
Weiss, Armin Beil, Gerd Meyer, Heinrich Weiss, Armin Beil, Gerd Meyer, Heinrich |
|---|---|
| author |
Weiss, Armin Beil, Gerd Meyer, Heinrich |
| spellingShingle |
Weiss, Armin Beil, Gerd Meyer, Heinrich Zeitschrift für Naturforschung B The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) General Chemistry |
| author_sort |
weiss, armin |
| spelling |
Weiss, Armin Beil, Gerd Meyer, Heinrich 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1980-0108 <jats:title>Abstract</jats:title> <jats:p> Kautsky’s siloxene was prepared in a topochemical reaction from large crystals of CaSi<jats:sub>2</jats:sub>. The structure model was revised. Siloxene is a subsiliceous acid [Si<jats:sub>6</jats:sub>]H<jats:sub>3</jats:sub>(OH)<jats:sub>3</jats:sub> and consists of two-dimensional corrugated Si-layers with three Si-Si bonds per silicon and an OH-or H-ligand, respectively. Ordering of adjacent layers is turbostratic. The layer lattice is capable of forming intercalation complexes. On intercalation only the layer distance is changed. </jats:p> <jats:p>The alkoxylated derivatives Si<jats:sub>6</jats:sub>H<jats:sub>3</jats:sub>(OCH<jats:sub>3</jats:sub>)<jats:sub>3n</jats:sub> and Si<jats:sub>6</jats:sub>H<jats:sub>3</jats:sub>(OC<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)<jats:sub>3n</jats:sub> are also able to intercalate polar molecules.</jats:p> The Topochemical Reaction of CaSi<sub>2</sub> to a Two-Dimensional Subsiliceous Acid Si<sub>6</sub>H<sub>3</sub>(OH)<sub>3</sub> ( = Kautskys’ Siloxene) Zeitschrift für Naturforschung B |
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Walter de Gruyter GmbH, 1980 |
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Walter de Gruyter GmbH, 1980 |
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0932-0776 1865-7117 |
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1980 |
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Walter de Gruyter GmbH |
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Zeitschrift für Naturforschung B |
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49 |
| title |
The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_unstemmed |
The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_full |
The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_fullStr |
The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_full_unstemmed |
The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_short |
The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_sort |
the topochemical reaction of casi<sub>2</sub> to a two-dimensional subsiliceous acid si<sub>6</sub>h<sub>3</sub>(oh)<sub>3</sub> ( = kautskys’ siloxene) |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1515/znb-1980-0108 |
| publishDate |
1980 |
| physical |
25-30 |
| description |
<jats:title>Abstract</jats:title>
<jats:p> Kautsky’s siloxene was prepared in a topochemical reaction from large crystals of CaSi<jats:sub>2</jats:sub>. The structure model was revised. Siloxene is a subsiliceous acid [Si<jats:sub>6</jats:sub>]H<jats:sub>3</jats:sub>(OH)<jats:sub>3</jats:sub> and consists of two-dimensional corrugated Si-layers with three Si-Si bonds per silicon and an OH-or H-ligand, respectively. Ordering of adjacent layers is turbostratic. The layer lattice is capable of forming intercalation complexes. On intercalation only the layer distance is changed. </jats:p>
<jats:p>The alkoxylated derivatives Si<jats:sub>6</jats:sub>H<jats:sub>3</jats:sub>(OCH<jats:sub>3</jats:sub>)<jats:sub>3n</jats:sub> and Si<jats:sub>6</jats:sub>H<jats:sub>3</jats:sub>(OC<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)<jats:sub>3n</jats:sub> are also able to intercalate polar molecules.</jats:p> |
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| description | <jats:title>Abstract</jats:title> <jats:p> Kautsky’s siloxene was prepared in a topochemical reaction from large crystals of CaSi<jats:sub>2</jats:sub>. The structure model was revised. Siloxene is a subsiliceous acid [Si<jats:sub>6</jats:sub>]H<jats:sub>3</jats:sub>(OH)<jats:sub>3</jats:sub> and consists of two-dimensional corrugated Si-layers with three Si-Si bonds per silicon and an OH-or H-ligand, respectively. Ordering of adjacent layers is turbostratic. The layer lattice is capable of forming intercalation complexes. On intercalation only the layer distance is changed. </jats:p> <jats:p>The alkoxylated derivatives Si<jats:sub>6</jats:sub>H<jats:sub>3</jats:sub>(OCH<jats:sub>3</jats:sub>)<jats:sub>3n</jats:sub> and Si<jats:sub>6</jats:sub>H<jats:sub>3</jats:sub>(OC<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)<jats:sub>3n</jats:sub> are also able to intercalate polar molecules.</jats:p> |
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| imprint | Walter de Gruyter GmbH, 1980 |
| imprint_str_mv | Walter de Gruyter GmbH, 1980 |
| institution | DE-15, DE-Pl11, DE-Rs1, DE-14, DE-105, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Zi4, DE-Gla1 |
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| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 25-30 |
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| series | Zeitschrift für Naturforschung B |
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| spelling | Weiss, Armin Beil, Gerd Meyer, Heinrich 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1980-0108 <jats:title>Abstract</jats:title> <jats:p> Kautsky’s siloxene was prepared in a topochemical reaction from large crystals of CaSi<jats:sub>2</jats:sub>. The structure model was revised. Siloxene is a subsiliceous acid [Si<jats:sub>6</jats:sub>]H<jats:sub>3</jats:sub>(OH)<jats:sub>3</jats:sub> and consists of two-dimensional corrugated Si-layers with three Si-Si bonds per silicon and an OH-or H-ligand, respectively. Ordering of adjacent layers is turbostratic. The layer lattice is capable of forming intercalation complexes. On intercalation only the layer distance is changed. </jats:p> <jats:p>The alkoxylated derivatives Si<jats:sub>6</jats:sub>H<jats:sub>3</jats:sub>(OCH<jats:sub>3</jats:sub>)<jats:sub>3n</jats:sub> and Si<jats:sub>6</jats:sub>H<jats:sub>3</jats:sub>(OC<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)<jats:sub>3n</jats:sub> are also able to intercalate polar molecules.</jats:p> The Topochemical Reaction of CaSi<sub>2</sub> to a Two-Dimensional Subsiliceous Acid Si<sub>6</sub>H<sub>3</sub>(OH)<sub>3</sub> ( = Kautskys’ Siloxene) Zeitschrift für Naturforschung B |
| spellingShingle | Weiss, Armin, Beil, Gerd, Meyer, Heinrich, Zeitschrift für Naturforschung B, The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene), General Chemistry |
| title | The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_full | The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_fullStr | The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_full_unstemmed | The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_short | The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| title_sort | the topochemical reaction of casi<sub>2</sub> to a two-dimensional subsiliceous acid si<sub>6</sub>h<sub>3</sub>(oh)<sub>3</sub> ( = kautskys’ siloxene) |
| title_unstemmed | The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene) |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1515/znb-1980-0108 |