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Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III)
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| Zeitschriftentitel: | Zeitschrift für Naturforschung A |
|---|---|
| Personen und Körperschaften: | , , , , |
| In: | Zeitschrift für Naturforschung A, 57, 2002, 6-7, S. 603-606 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
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| Schlagwörter: |
| author_facet |
Iijima, S. Mizutani, F. Miyasaka, H. Matsumoto, N. Ōkawa, H. Iijima, S. Mizutani, F. Miyasaka, H. Matsumoto, N. Ōkawa, H. |
|---|---|
| author |
Iijima, S. Mizutani, F. Miyasaka, H. Matsumoto, N. Ōkawa, H. |
| spellingShingle |
Iijima, S. Mizutani, F. Miyasaka, H. Matsumoto, N. Ōkawa, H. Zeitschrift für Naturforschung A Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
| author_sort |
iijima, s. |
| spelling |
Iijima, S. Mizutani, F. Miyasaka, H. Matsumoto, N. Ōkawa, H. 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-2002-6-757 <jats:p>Variable-temperature <jats:sup>57</jats:sup>Fe Mössbauer measurements on cyanide-bridged 2-D bimetallic assemblies NEt<jats:sub>4</jats:sub>[Mn(salen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>] (1), K[Mn(3-MeOsalen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>] (2) and K[Mn(3- MeOsalen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>]<jats:sub>2</jats:sub> DMF (3), where salen<jats:sup>2-</jats:sup> = N,N'-ethylenebis(salicylidene iminato) dianion, revealed that these compounds exhibit a long range magnetic ordering below ca. 10 K under zero applied field. The quadrupole splittings of 1 - 3 showed intermediate values between those of typical cyano-bridged 1-D and 3-D complexes. The paramagnetic state of K[Mn(5-Clsalen)]<jats:sub>2</jats:sub>- [Fe(CN)<jats:sub>6</jats:sub>] 4 H<jats:sub>2</jats:sub>O (4) turned to a bulk magnetic one with desolvation</jats:p> Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) Zeitschrift für Naturforschung A |
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10.1515/zna-2002-6-757 |
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| title |
Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_unstemmed |
Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_full |
Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_fullStr |
Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_full_unstemmed |
Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_short |
Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_sort |
mössbauer spectroscopic studies of molecule-based magnets: two-dimensional complexes derived from metal schiff-bases and hexacyanoferrate(iii) |
| topic |
Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
| url |
http://dx.doi.org/10.1515/zna-2002-6-757 |
| publishDate |
2002 |
| physical |
603-606 |
| description |
<jats:p>Variable-temperature <jats:sup>57</jats:sup>Fe Mössbauer measurements on cyanide-bridged 2-D bimetallic assemblies NEt<jats:sub>4</jats:sub>[Mn(salen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>] (1), K[Mn(3-MeOsalen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>] (2) and K[Mn(3- MeOsalen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>]<jats:sub>2</jats:sub> DMF (3), where salen<jats:sup>2-</jats:sup> = N,N'-ethylenebis(salicylidene iminato) dianion, revealed that these compounds exhibit a long range magnetic ordering below ca. 10 K under zero applied field. The quadrupole splittings of 1 - 3 showed intermediate values between those of typical cyano-bridged 1-D and 3-D complexes. The paramagnetic state of K[Mn(5-Clsalen)]<jats:sub>2</jats:sub>- [Fe(CN)<jats:sub>6</jats:sub>] 4 H<jats:sub>2</jats:sub>O (4) turned to a bulk magnetic one with desolvation</jats:p> |
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| author | Iijima, S., Mizutani, F., Miyasaka, H., Matsumoto, N., Ōkawa, H. |
| author_facet | Iijima, S., Mizutani, F., Miyasaka, H., Matsumoto, N., Ōkawa, H., Iijima, S., Mizutani, F., Miyasaka, H., Matsumoto, N., Ōkawa, H. |
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| description | <jats:p>Variable-temperature <jats:sup>57</jats:sup>Fe Mössbauer measurements on cyanide-bridged 2-D bimetallic assemblies NEt<jats:sub>4</jats:sub>[Mn(salen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>] (1), K[Mn(3-MeOsalen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>] (2) and K[Mn(3- MeOsalen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>]<jats:sub>2</jats:sub> DMF (3), where salen<jats:sup>2-</jats:sup> = N,N'-ethylenebis(salicylidene iminato) dianion, revealed that these compounds exhibit a long range magnetic ordering below ca. 10 K under zero applied field. The quadrupole splittings of 1 - 3 showed intermediate values between those of typical cyano-bridged 1-D and 3-D complexes. The paramagnetic state of K[Mn(5-Clsalen)]<jats:sub>2</jats:sub>- [Fe(CN)<jats:sub>6</jats:sub>] 4 H<jats:sub>2</jats:sub>O (4) turned to a bulk magnetic one with desolvation</jats:p> |
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| spelling | Iijima, S. Mizutani, F. Miyasaka, H. Matsumoto, N. Ōkawa, H. 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-2002-6-757 <jats:p>Variable-temperature <jats:sup>57</jats:sup>Fe Mössbauer measurements on cyanide-bridged 2-D bimetallic assemblies NEt<jats:sub>4</jats:sub>[Mn(salen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>] (1), K[Mn(3-MeOsalen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>] (2) and K[Mn(3- MeOsalen)]<jats:sub>2</jats:sub>[Fe(CN)<jats:sub>6</jats:sub>]<jats:sub>2</jats:sub> DMF (3), where salen<jats:sup>2-</jats:sup> = N,N'-ethylenebis(salicylidene iminato) dianion, revealed that these compounds exhibit a long range magnetic ordering below ca. 10 K under zero applied field. The quadrupole splittings of 1 - 3 showed intermediate values between those of typical cyano-bridged 1-D and 3-D complexes. The paramagnetic state of K[Mn(5-Clsalen)]<jats:sub>2</jats:sub>- [Fe(CN)<jats:sub>6</jats:sub>] 4 H<jats:sub>2</jats:sub>O (4) turned to a bulk magnetic one with desolvation</jats:p> Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) Zeitschrift für Naturforschung A |
| spellingShingle | Iijima, S., Mizutani, F., Miyasaka, H., Matsumoto, N., Ōkawa, H., Zeitschrift für Naturforschung A, Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III), Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics |
| title | Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_full | Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_fullStr | Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_full_unstemmed | Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_short | Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| title_sort | mössbauer spectroscopic studies of molecule-based magnets: two-dimensional complexes derived from metal schiff-bases and hexacyanoferrate(iii) |
| title_unstemmed | Mössbauer Spectroscopic Studies of Molecule-Based Magnets: Two-Dimensional Complexes Derived from Metal Schiff-Bases and Hexacyanoferrate(III) |
| topic | Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics |
| url | http://dx.doi.org/10.1515/zna-2002-6-757 |