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Boron Nuclear Quadrupole Coupling in BF(OH)2
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| Zeitschriftentitel: | Zeitschrift für Naturforschung A |
|---|---|
| Personen und Körperschaften: | , |
| In: | Zeitschrift für Naturforschung A, 52, 1997, 12, S. 874-876 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Storm, V. Dreizler, H. Storm, V. Dreizler, H. |
|---|---|
| author |
Storm, V. Dreizler, H. |
| spellingShingle |
Storm, V. Dreizler, H. Zeitschrift für Naturforschung A Boron Nuclear Quadrupole Coupling in BF(OH)2 Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
| author_sort |
storm, v. |
| spelling |
Storm, V. Dreizler, H. 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-1997-1207 <jats:p>We investigated the nuclear quadrupole coupling of the <jats:sup>11</jats:sup>B and <jats:sup>10</jats:sup>B nuclei in fluorodihydroxy borane, BF(OH)<jats:sub>2</jats:sub>. An analysis of the hyperfine splittings resulted in the coupling constants %<jats:sub>aa</jats:sub> = -1.414(11) MHz, %<jats:sub>bb</jats:sub> = - 1.206(11) MHz, %<jats:sub>cc</jats:sub> = 2.620(11) MHz for <jats:sup>11</jats:sup>B and %<jats:sub>aa</jats:sub> = -2.872(67) MHz, y M = -2.525(69) MHz, %cc = 5.397(69) MHz for <jats:sup>10</jats:sup>B. From these constants the ratio r of the quadrupole moments r = Q(<jats:sup>10</jats:sup>B)/Q(<jats:sup>11</jats:sup>B) = 2.051 (44) could be derived and compared to data taken from the literature</jats:p> Boron Nuclear Quadrupole Coupling in BF(OH)<sub>2</sub> Zeitschrift für Naturforschung A |
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Walter de Gruyter GmbH, 1997 |
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Walter de Gruyter GmbH, 1997 |
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1865-7109 0932-0784 |
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1997 |
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Zeitschrift für Naturforschung A |
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| title |
Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| title_unstemmed |
Boron Nuclear Quadrupole Coupling in BF(OH)2 |
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Boron Nuclear Quadrupole Coupling in BF(OH)2 |
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Boron Nuclear Quadrupole Coupling in BF(OH)2 |
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Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| title_short |
Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| title_sort |
boron nuclear quadrupole coupling in bf(oh)<sub>2</sub> |
| topic |
Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
| url |
http://dx.doi.org/10.1515/zna-1997-1207 |
| publishDate |
1997 |
| physical |
874-876 |
| description |
<jats:p>We investigated the nuclear quadrupole coupling of the <jats:sup>11</jats:sup>B and <jats:sup>10</jats:sup>B nuclei in fluorodihydroxy borane, BF(OH)<jats:sub>2</jats:sub>. An analysis of the hyperfine splittings resulted in the coupling constants %<jats:sub>aa</jats:sub> = -1.414(11) MHz, %<jats:sub>bb</jats:sub> = - 1.206(11) MHz, %<jats:sub>cc</jats:sub> = 2.620(11) MHz for <jats:sup>11</jats:sup>B and %<jats:sub>aa</jats:sub> = -2.872(67) MHz, y M = -2.525(69) MHz, %cc = 5.397(69) MHz for <jats:sup>10</jats:sup>B. From these constants the ratio r of the quadrupole moments r = Q(<jats:sup>10</jats:sup>B)/Q(<jats:sup>11</jats:sup>B) = 2.051 (44) could be derived and compared to data taken from the literature</jats:p> |
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| description | <jats:p>We investigated the nuclear quadrupole coupling of the <jats:sup>11</jats:sup>B and <jats:sup>10</jats:sup>B nuclei in fluorodihydroxy borane, BF(OH)<jats:sub>2</jats:sub>. An analysis of the hyperfine splittings resulted in the coupling constants %<jats:sub>aa</jats:sub> = -1.414(11) MHz, %<jats:sub>bb</jats:sub> = - 1.206(11) MHz, %<jats:sub>cc</jats:sub> = 2.620(11) MHz for <jats:sup>11</jats:sup>B and %<jats:sub>aa</jats:sub> = -2.872(67) MHz, y M = -2.525(69) MHz, %cc = 5.397(69) MHz for <jats:sup>10</jats:sup>B. From these constants the ratio r of the quadrupole moments r = Q(<jats:sup>10</jats:sup>B)/Q(<jats:sup>11</jats:sup>B) = 2.051 (44) could be derived and compared to data taken from the literature</jats:p> |
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| physical | 874-876 |
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| spelling | Storm, V. Dreizler, H. 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-1997-1207 <jats:p>We investigated the nuclear quadrupole coupling of the <jats:sup>11</jats:sup>B and <jats:sup>10</jats:sup>B nuclei in fluorodihydroxy borane, BF(OH)<jats:sub>2</jats:sub>. An analysis of the hyperfine splittings resulted in the coupling constants %<jats:sub>aa</jats:sub> = -1.414(11) MHz, %<jats:sub>bb</jats:sub> = - 1.206(11) MHz, %<jats:sub>cc</jats:sub> = 2.620(11) MHz for <jats:sup>11</jats:sup>B and %<jats:sub>aa</jats:sub> = -2.872(67) MHz, y M = -2.525(69) MHz, %cc = 5.397(69) MHz for <jats:sup>10</jats:sup>B. From these constants the ratio r of the quadrupole moments r = Q(<jats:sup>10</jats:sup>B)/Q(<jats:sup>11</jats:sup>B) = 2.051 (44) could be derived and compared to data taken from the literature</jats:p> Boron Nuclear Quadrupole Coupling in BF(OH)<sub>2</sub> Zeitschrift für Naturforschung A |
| spellingShingle | Storm, V., Dreizler, H., Zeitschrift für Naturforschung A, Boron Nuclear Quadrupole Coupling in BF(OH)2, Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics |
| title | Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| title_full | Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| title_fullStr | Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| title_full_unstemmed | Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| title_short | Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| title_sort | boron nuclear quadrupole coupling in bf(oh)<sub>2</sub> |
| title_unstemmed | Boron Nuclear Quadrupole Coupling in BF(OH)2 |
| topic | Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics |
| url | http://dx.doi.org/10.1515/zna-1997-1207 |