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79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3...

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Zeitschriftentitel: Zeitschrift für Naturforschung A
Personen und Körperschaften: Hartmann, Jutta, Weiss, Alarich
In: Zeitschrift für Naturforschung A, 46, 1991, 4, S. 367-375
Format: E-Article
Sprache: Englisch
veröffentlicht:
Walter de Gruyter GmbH
Schlagwörter:
Physical and Theoretical Chemistry
General Physics and Astronomy
Mathematical Physics
author_facet Hartmann, Jutta
Weiss, Alarich
Hartmann, Jutta
Weiss, Alarich
author Hartmann, Jutta
Weiss, Alarich
spellingShingle Hartmann, Jutta
Weiss, Alarich
Zeitschrift für Naturforschung A
79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
Physical and Theoretical Chemistry
General Physics and Astronomy
Mathematical Physics
author_sort hartmann, jutta
spelling Hartmann, Jutta Weiss, Alarich 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-1991-0412 <jats:title>Abstract</jats:title> <jats:p> The <jats:sup>79</jats:sup>Br and <jats:sup>127</jats:sup>I nuclear quadrupole resonance, NQR, spectra of ortho-substituted anilinium bromides and iodides 2-RC<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> X<jats:sup>⊖</jats:sup> with X = Br, I and R = CI, CN, C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>, NH<jats:sub>2</jats:sub>, and NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> X<jats:sup>⊖</jats:sup> have been investigated in the temperature range 77 &lt; T/K &lt;420. Phase transitions occur in 2-(C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> Br<jats:sup>⊖</jats:sup> ½H<jats:sub>2</jats:sub>O at Tc= 164 K. in 2-(C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> I<jats:sup>⊖</jats:sup> at Tc = 214 K, in [1,2-C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>(N(H,D)<jats:sub>3</jats:sub>)-]2<jats:sup>⊕</jats:sup>[Br<jats:sup>⊖</jats:sup>]2 at Tc = 209 K, and in [1,2-C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>(NH<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>]2<jats:sup>⊕</jats:sup>[I<jats:sup>⊖</jats:sup>]<jats:sub>2</jats:sub> at Tc = 173 K. The NQR data are discussed and compared with NQR spectra of para-substituted anilinium halides</jats:p> <sup>79</sup>Br and <sup>127</sup>І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC<sub>6</sub>H<sub>4</sub>NH<sub>3</sub> <sup>⊕</sup> X<sup>⊖</sup> with X = Br, I and R = CI, CN, C<sub>2</sub>H<sub>5</sub>, NH<sub>2</sub>, and NH<sub>3</sub> <sup>⊕</sup> X<sup>⊖</sup> Zeitschrift für Naturforschung A
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match_str hartmann199179brand127inuclearquadrupoleresonanceinvestigationsoforthosubstitutedaniliniumhalides2rc6h4nh3xwithxbriandrcicnc2h5nh2andnh3x
publishDateSort 1991
publisher Walter de Gruyter GmbH
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series Zeitschrift für Naturforschung A
source_id 49
title 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_unstemmed 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_full 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_fullStr 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_full_unstemmed 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_short 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_sort <sup>79</sup>br and <sup>127</sup>і nuclear quadrupole resonance investigations of ortho-substituted anilinium halides, 2-rc<sub>6</sub>h<sub>4</sub>nh<sub>3</sub> <sup>⊕</sup> x<sup>⊖</sup> with x = br, i and r = ci, cn, c<sub>2</sub>h<sub>5</sub>, nh<sub>2</sub>, and nh<sub>3</sub> <sup>⊕</sup> x<sup>⊖</sup>
topic Physical and Theoretical Chemistry
General Physics and Astronomy
Mathematical Physics
url http://dx.doi.org/10.1515/zna-1991-0412
publishDate 1991
physical 367-375
description <jats:title>Abstract</jats:title> <jats:p> The <jats:sup>79</jats:sup>Br and <jats:sup>127</jats:sup>I nuclear quadrupole resonance, NQR, spectra of ortho-substituted anilinium bromides and iodides 2-RC<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> X<jats:sup>⊖</jats:sup> with X = Br, I and R = CI, CN, C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>, NH<jats:sub>2</jats:sub>, and NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> X<jats:sup>⊖</jats:sup> have been investigated in the temperature range 77 &lt; T/K &lt;420. Phase transitions occur in 2-(C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> Br<jats:sup>⊖</jats:sup> ½H<jats:sub>2</jats:sub>O at Tc= 164 K. in 2-(C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> I<jats:sup>⊖</jats:sup> at Tc = 214 K, in [1,2-C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>(N(H,D)<jats:sub>3</jats:sub>)-]2<jats:sup>⊕</jats:sup>[Br<jats:sup>⊖</jats:sup>]2 at Tc = 209 K, and in [1,2-C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>(NH<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>]2<jats:sup>⊕</jats:sup>[I<jats:sup>⊖</jats:sup>]<jats:sub>2</jats:sub> at Tc = 173 K. The NQR data are discussed and compared with NQR spectra of para-substituted anilinium halides</jats:p>
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description <jats:title>Abstract</jats:title> <jats:p> The <jats:sup>79</jats:sup>Br and <jats:sup>127</jats:sup>I nuclear quadrupole resonance, NQR, spectra of ortho-substituted anilinium bromides and iodides 2-RC<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> X<jats:sup>⊖</jats:sup> with X = Br, I and R = CI, CN, C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>, NH<jats:sub>2</jats:sub>, and NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> X<jats:sup>⊖</jats:sup> have been investigated in the temperature range 77 &lt; T/K &lt;420. Phase transitions occur in 2-(C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> Br<jats:sup>⊖</jats:sup> ½H<jats:sub>2</jats:sub>O at Tc= 164 K. in 2-(C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> I<jats:sup>⊖</jats:sup> at Tc = 214 K, in [1,2-C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>(N(H,D)<jats:sub>3</jats:sub>)-]2<jats:sup>⊕</jats:sup>[Br<jats:sup>⊖</jats:sup>]2 at Tc = 209 K, and in [1,2-C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>(NH<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>]2<jats:sup>⊕</jats:sup>[I<jats:sup>⊖</jats:sup>]<jats:sub>2</jats:sub> at Tc = 173 K. The NQR data are discussed and compared with NQR spectra of para-substituted anilinium halides</jats:p>
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spelling Hartmann, Jutta Weiss, Alarich 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-1991-0412 <jats:title>Abstract</jats:title> <jats:p> The <jats:sup>79</jats:sup>Br and <jats:sup>127</jats:sup>I nuclear quadrupole resonance, NQR, spectra of ortho-substituted anilinium bromides and iodides 2-RC<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> X<jats:sup>⊖</jats:sup> with X = Br, I and R = CI, CN, C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>, NH<jats:sub>2</jats:sub>, and NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> X<jats:sup>⊖</jats:sup> have been investigated in the temperature range 77 &lt; T/K &lt;420. Phase transitions occur in 2-(C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> Br<jats:sup>⊖</jats:sup> ½H<jats:sub>2</jats:sub>O at Tc= 164 K. in 2-(C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>)C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sub>3</jats:sub> <jats:sup>⊕</jats:sup> I<jats:sup>⊖</jats:sup> at Tc = 214 K, in [1,2-C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>(N(H,D)<jats:sub>3</jats:sub>)-]2<jats:sup>⊕</jats:sup>[Br<jats:sup>⊖</jats:sup>]2 at Tc = 209 K, and in [1,2-C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>(NH<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>]2<jats:sup>⊕</jats:sup>[I<jats:sup>⊖</jats:sup>]<jats:sub>2</jats:sub> at Tc = 173 K. The NQR data are discussed and compared with NQR spectra of para-substituted anilinium halides</jats:p> <sup>79</sup>Br and <sup>127</sup>І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC<sub>6</sub>H<sub>4</sub>NH<sub>3</sub> <sup>⊕</sup> X<sup>⊖</sup> with X = Br, I and R = CI, CN, C<sub>2</sub>H<sub>5</sub>, NH<sub>2</sub>, and NH<sub>3</sub> <sup>⊕</sup> X<sup>⊖</sup> Zeitschrift für Naturforschung A
spellingShingle Hartmann, Jutta, Weiss, Alarich, Zeitschrift für Naturforschung A, 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖, Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics
title 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_full 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_fullStr 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_full_unstemmed 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_short 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
title_sort <sup>79</sup>br and <sup>127</sup>і nuclear quadrupole resonance investigations of ortho-substituted anilinium halides, 2-rc<sub>6</sub>h<sub>4</sub>nh<sub>3</sub> <sup>⊕</sup> x<sup>⊖</sup> with x = br, i and r = ci, cn, c<sub>2</sub>h<sub>5</sub>, nh<sub>2</sub>, and nh<sub>3</sub> <sup>⊕</sup> x<sup>⊖</sup>
title_unstemmed 79Br and 127І Nuclear Quadrupole Resonance Investigations of Ortho-Substituted Anilinium Halides, 2-RC6H4NH3 ⊕ X⊖ with X = Br, I and R = CI, CN, C2H5, NH2, and NH3 ⊕ X⊖
topic Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics
url http://dx.doi.org/10.1515/zna-1991-0412