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Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis: Quadrupole Hyperfine Structure and Centrifugal D...
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| Zeitschriftentitel: | Zeitschrift für Naturforschung A |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Zeitschrift für Naturforschung A, 38, 1983, 11, S. 1238-1247 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Walter de Gruyter GmbH
|
| Schlagwörter: |
| author_facet |
Hübner, Dirk Fliege, Eckhard Sutter, Dieter H. Hübner, Dirk Fliege, Eckhard Sutter, Dieter H. |
|---|---|
| author |
Hübner, Dirk Fliege, Eckhard Sutter, Dieter H. |
| spellingShingle |
Hübner, Dirk Fliege, Eckhard Sutter, Dieter H. Zeitschrift für Naturforschung A Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
| author_sort |
hübner, dirk |
| spelling |
Hübner, Dirk Fliege, Eckhard Sutter, Dieter H. 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-1983-1110 <jats:p>The rotational spectrum of 3-bromothiophene was investigated in the frequency range between 8 and 18 GHz by use of a microwave Fourier transform spectrometer. Both a- and b-type spectra were assigned for the vibronic ground state. Rotational constants, quartic centrifugal distortion constants and quadrupole coupling constants were obtained for the <jats:sup>79</jats:sup>Br- and <jats:sup>81</jats:sup>Br-isotopic species. For the analysis, the effective rotational Hamiltonian including centrifugal distortion in the form of Van Eijck's symmetric top reduction and bromine quadrupole coupling was set up in the coupled basis of the limiting symmetric top, J, K, I, F, M<jats:sub>F</jats:sub>>, and was diagonalized numerically. Spin rotation interaction was neglected</jats:p> Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis Zeitschrift für Naturforschung A |
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Walter de Gruyter GmbH, 1983 |
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Walter de Gruyter GmbH, 1983 |
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1865-7109 0932-0784 |
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Zeitschrift für Naturforschung A |
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| title_sub |
Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title |
Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_unstemmed |
Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_full |
Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_fullStr |
Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_full_unstemmed |
Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_short |
Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_sort |
vibronic ground state rotational spectrum of 3-bromothiophene : quadrupole hyperfine structure and centrifugal distortion analysis |
| topic |
Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
| url |
http://dx.doi.org/10.1515/zna-1983-1110 |
| publishDate |
1983 |
| physical |
1238-1247 |
| description |
<jats:p>The rotational spectrum of 3-bromothiophene was investigated in the frequency range between 8 and 18 GHz by use of a microwave Fourier transform spectrometer. Both a- and b-type spectra were assigned for the vibronic ground state. Rotational constants, quartic centrifugal distortion constants and quadrupole coupling constants were obtained for the <jats:sup>79</jats:sup>Br- and <jats:sup>81</jats:sup>Br-isotopic species. For the analysis, the effective rotational Hamiltonian including centrifugal distortion in the form of Van Eijck's symmetric top reduction and bromine quadrupole coupling was set up in the coupled basis of the limiting symmetric top, J, K, I, F, M<jats:sub>F</jats:sub>>, and was diagonalized numerically. Spin rotation interaction was neglected</jats:p> |
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| author | Hübner, Dirk, Fliege, Eckhard, Sutter, Dieter H. |
| author_facet | Hübner, Dirk, Fliege, Eckhard, Sutter, Dieter H., Hübner, Dirk, Fliege, Eckhard, Sutter, Dieter H. |
| author_sort | hübner, dirk |
| container_issue | 11 |
| container_start_page | 1238 |
| container_title | Zeitschrift für Naturforschung A |
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| description | <jats:p>The rotational spectrum of 3-bromothiophene was investigated in the frequency range between 8 and 18 GHz by use of a microwave Fourier transform spectrometer. Both a- and b-type spectra were assigned for the vibronic ground state. Rotational constants, quartic centrifugal distortion constants and quadrupole coupling constants were obtained for the <jats:sup>79</jats:sup>Br- and <jats:sup>81</jats:sup>Br-isotopic species. For the analysis, the effective rotational Hamiltonian including centrifugal distortion in the form of Van Eijck's symmetric top reduction and bromine quadrupole coupling was set up in the coupled basis of the limiting symmetric top, J, K, I, F, M<jats:sub>F</jats:sub>>, and was diagonalized numerically. Spin rotation interaction was neglected</jats:p> |
| doi_str_mv | 10.1515/zna-1983-1110 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTUxNS96bmEtMTk4My0xMTEw |
| imprint | Walter de Gruyter GmbH, 1983 |
| imprint_str_mv | Walter de Gruyter GmbH, 1983 |
| institution | DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1 |
| issn | 1865-7109, 0932-0784 |
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| mega_collection | Walter de Gruyter GmbH (CrossRef) |
| physical | 1238-1247 |
| publishDate | 1983 |
| publishDateSort | 1983 |
| publisher | Walter de Gruyter GmbH |
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| series | Zeitschrift für Naturforschung A |
| source_id | 49 |
| spelling | Hübner, Dirk Fliege, Eckhard Sutter, Dieter H. 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-1983-1110 <jats:p>The rotational spectrum of 3-bromothiophene was investigated in the frequency range between 8 and 18 GHz by use of a microwave Fourier transform spectrometer. Both a- and b-type spectra were assigned for the vibronic ground state. Rotational constants, quartic centrifugal distortion constants and quadrupole coupling constants were obtained for the <jats:sup>79</jats:sup>Br- and <jats:sup>81</jats:sup>Br-isotopic species. For the analysis, the effective rotational Hamiltonian including centrifugal distortion in the form of Van Eijck's symmetric top reduction and bromine quadrupole coupling was set up in the coupled basis of the limiting symmetric top, J, K, I, F, M<jats:sub>F</jats:sub>>, and was diagonalized numerically. Spin rotation interaction was neglected</jats:p> Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis Zeitschrift für Naturforschung A |
| spellingShingle | Hübner, Dirk, Fliege, Eckhard, Sutter, Dieter H., Zeitschrift für Naturforschung A, Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis, Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics |
| title | Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_full | Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_fullStr | Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_full_unstemmed | Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_short | Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_sort | vibronic ground state rotational spectrum of 3-bromothiophene : quadrupole hyperfine structure and centrifugal distortion analysis |
| title_sub | Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| title_unstemmed | Vibronic Ground State Rotational Spectrum of 3-Bromothiophene : Quadrupole Hyperfine Structure and Centrifugal Distortion Analysis |
| topic | Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics |
| url | http://dx.doi.org/10.1515/zna-1983-1110 |