Eintrag weiter verarbeiten
Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide
Gespeichert in:
| Zeitschriftentitel: | Journal of the American Ceramic Society |
|---|---|
| Personen und Körperschaften: | |
| In: | Journal of the American Ceramic Society, 101, 2018, 2, S. 509-514 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Tsuyumoto, Isao Tsuyumoto, Isao |
|---|---|
| author |
Tsuyumoto, Isao |
| spellingShingle |
Tsuyumoto, Isao Journal of the American Ceramic Society Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide Materials Chemistry Ceramics and Composites |
| author_sort |
tsuyumoto, isao |
| spelling |
Tsuyumoto, Isao 0002-7820 1551-2916 Wiley Materials Chemistry Ceramics and Composites http://dx.doi.org/10.1111/jace.15250 <jats:title>Abstract</jats:title><jats:p>A hexagonal form of tungsten trioxide (h‐WO<jats:sub>3</jats:sub>, particle size: 15.9‐57.1 nm) was found to be formed by a direct reaction between metallic tungsten powder (W, particle size: 0.45‐0.59 μm) and 15%‐30% hydrogen peroxide (H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>) aq solution. Oxide film on the powder surface having the similar crystal structure as h‐WO<jats:sub>3</jats:sub> was essential for the formation, and the surface oxide film was formed by aging the powder in air at 45°C, a relative humidity of 100% (<jats:italic>P</jats:italic><jats:sub>H2O</jats:sub> 96 hPa) for 3‐28 days or in ambient atmosphere at room temperature for 12 years. The Rietveld analysis performed in the space group <jats:italic>P</jats:italic>6<jats:sub>3</jats:sub>/<jats:italic>mcm</jats:italic> (<jats:italic>Z</jats:italic> = 6) indicated the crystal structures were the same as those of the reported h‐WO<jats:sub>3</jats:sub> and that the crystallographic characteristic was as follows: <jats:italic>a</jats:italic> = 0.74219 nm, <jats:italic>c</jats:italic> = 0.77198 nm for h‐WO<jats:sub>3</jats:sub> from the 28‐day aged powder, and <jats:italic>a</jats:italic> = 0.74538 nm, <jats:italic>c</jats:italic> = 0.77194 nm for h‐WO<jats:sub>3</jats:sub> from the 12‐year aged powder.</jats:p> Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide Journal of the American Ceramic Society |
| doi_str_mv |
10.1111/jace.15250 |
| facet_avail |
Online |
| finc_class_facet |
Chemie und Pharmazie Technik |
| format |
ElectronicArticle |
| fullrecord |
blob:ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTExMS9qYWNlLjE1MjUw |
| id |
ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTExMS9qYWNlLjE1MjUw |
| institution |
DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 DE-D275 DE-Bn3 DE-Brt1 DE-D161 |
| imprint |
Wiley, 2018 |
| imprint_str_mv |
Wiley, 2018 |
| issn |
0002-7820 1551-2916 |
| issn_str_mv |
0002-7820 1551-2916 |
| language |
English |
| mega_collection |
Wiley (CrossRef) |
| match_str |
tsuyumoto2018facilesynthesisofnanocrystallinehexagonaltungstentrioxidefrommetallictungstenpowderandhydrogenperoxide |
| publishDateSort |
2018 |
| publisher |
Wiley |
| recordtype |
ai |
| record_format |
ai |
| series |
Journal of the American Ceramic Society |
| source_id |
49 |
| title |
Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_unstemmed |
Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_full |
Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_fullStr |
Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_full_unstemmed |
Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_short |
Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_sort |
facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| topic |
Materials Chemistry Ceramics and Composites |
| url |
http://dx.doi.org/10.1111/jace.15250 |
| publishDate |
2018 |
| physical |
509-514 |
| description |
<jats:title>Abstract</jats:title><jats:p>A hexagonal form of tungsten trioxide (h‐WO<jats:sub>3</jats:sub>, particle size: 15.9‐57.1 nm) was found to be formed by a direct reaction between metallic tungsten powder (W, particle size: 0.45‐0.59 μm) and 15%‐30% hydrogen peroxide (H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>) aq solution. Oxide film on the powder surface having the similar crystal structure as h‐WO<jats:sub>3</jats:sub> was essential for the formation, and the surface oxide film was formed by aging the powder in air at 45°C, a relative humidity of 100% (<jats:italic>P</jats:italic><jats:sub>H2O</jats:sub> 96 hPa) for 3‐28 days or in ambient atmosphere at room temperature for 12 years. The Rietveld analysis performed in the space group <jats:italic>P</jats:italic>6<jats:sub>3</jats:sub>/<jats:italic>mcm</jats:italic> (<jats:italic>Z</jats:italic> = 6) indicated the crystal structures were the same as those of the reported h‐WO<jats:sub>3</jats:sub> and that the crystallographic characteristic was as follows: <jats:italic>a</jats:italic> = 0.74219 nm, <jats:italic>c</jats:italic> = 0.77198 nm for h‐WO<jats:sub>3</jats:sub> from the 28‐day aged powder, and <jats:italic>a</jats:italic> = 0.74538 nm, <jats:italic>c</jats:italic> = 0.77194 nm for h‐WO<jats:sub>3</jats:sub> from the 12‐year aged powder.</jats:p> |
| container_issue |
2 |
| container_start_page |
509 |
| container_title |
Journal of the American Ceramic Society |
| container_volume |
101 |
| format_de105 |
Article, E-Article |
| format_de14 |
Article, E-Article |
| format_de15 |
Article, E-Article |
| format_de520 |
Article, E-Article |
| format_de540 |
Article, E-Article |
| format_dech1 |
Article, E-Article |
| format_ded117 |
Article, E-Article |
| format_degla1 |
E-Article |
| format_del152 |
Buch |
| format_del189 |
Article, E-Article |
| format_dezi4 |
Article |
| format_dezwi2 |
Article, E-Article |
| format_finc |
Article, E-Article |
| format_nrw |
Article, E-Article |
| _version_ |
1792337698118172682 |
| geogr_code |
not assigned |
| last_indexed |
2024-03-01T15:20:28.224Z |
| geogr_code_person |
not assigned |
| openURL |
url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Facile+synthesis+of+nanocrystalline+hexagonal+tungsten+trioxide+from+metallic+tungsten+powder+and+hydrogen+peroxide&rft.date=2018-02-01&genre=article&issn=1551-2916&volume=101&issue=2&spage=509&epage=514&pages=509-514&jtitle=Journal+of+the+American+Ceramic+Society&atitle=Facile+synthesis+of+nanocrystalline+hexagonal+tungsten+trioxide+from+metallic+tungsten+powder+and+hydrogen+peroxide&aulast=Tsuyumoto&aufirst=Isao&rft_id=info%3Adoi%2F10.1111%2Fjace.15250&rft.language%5B0%5D=eng |
| SOLR | |
| _version_ | 1792337698118172682 |
| author | Tsuyumoto, Isao |
| author_facet | Tsuyumoto, Isao, Tsuyumoto, Isao |
| author_sort | tsuyumoto, isao |
| container_issue | 2 |
| container_start_page | 509 |
| container_title | Journal of the American Ceramic Society |
| container_volume | 101 |
| description | <jats:title>Abstract</jats:title><jats:p>A hexagonal form of tungsten trioxide (h‐WO<jats:sub>3</jats:sub>, particle size: 15.9‐57.1 nm) was found to be formed by a direct reaction between metallic tungsten powder (W, particle size: 0.45‐0.59 μm) and 15%‐30% hydrogen peroxide (H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>) aq solution. Oxide film on the powder surface having the similar crystal structure as h‐WO<jats:sub>3</jats:sub> was essential for the formation, and the surface oxide film was formed by aging the powder in air at 45°C, a relative humidity of 100% (<jats:italic>P</jats:italic><jats:sub>H2O</jats:sub> 96 hPa) for 3‐28 days or in ambient atmosphere at room temperature for 12 years. The Rietveld analysis performed in the space group <jats:italic>P</jats:italic>6<jats:sub>3</jats:sub>/<jats:italic>mcm</jats:italic> (<jats:italic>Z</jats:italic> = 6) indicated the crystal structures were the same as those of the reported h‐WO<jats:sub>3</jats:sub> and that the crystallographic characteristic was as follows: <jats:italic>a</jats:italic> = 0.74219 nm, <jats:italic>c</jats:italic> = 0.77198 nm for h‐WO<jats:sub>3</jats:sub> from the 28‐day aged powder, and <jats:italic>a</jats:italic> = 0.74538 nm, <jats:italic>c</jats:italic> = 0.77194 nm for h‐WO<jats:sub>3</jats:sub> from the 12‐year aged powder.</jats:p> |
| doi_str_mv | 10.1111/jace.15250 |
| facet_avail | Online |
| finc_class_facet | Chemie und Pharmazie, Technik |
| format | ElectronicArticle |
| format_de105 | Article, E-Article |
| format_de14 | Article, E-Article |
| format_de15 | Article, E-Article |
| format_de520 | Article, E-Article |
| format_de540 | Article, E-Article |
| format_dech1 | Article, E-Article |
| format_ded117 | Article, E-Article |
| format_degla1 | E-Article |
| format_del152 | Buch |
| format_del189 | Article, E-Article |
| format_dezi4 | Article |
| format_dezwi2 | Article, E-Article |
| format_finc | Article, E-Article |
| format_nrw | Article, E-Article |
| geogr_code | not assigned |
| geogr_code_person | not assigned |
| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTExMS9qYWNlLjE1MjUw |
| imprint | Wiley, 2018 |
| imprint_str_mv | Wiley, 2018 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161 |
| issn | 0002-7820, 1551-2916 |
| issn_str_mv | 0002-7820, 1551-2916 |
| language | English |
| last_indexed | 2024-03-01T15:20:28.224Z |
| match_str | tsuyumoto2018facilesynthesisofnanocrystallinehexagonaltungstentrioxidefrommetallictungstenpowderandhydrogenperoxide |
| mega_collection | Wiley (CrossRef) |
| physical | 509-514 |
| publishDate | 2018 |
| publishDateSort | 2018 |
| publisher | Wiley |
| record_format | ai |
| recordtype | ai |
| series | Journal of the American Ceramic Society |
| source_id | 49 |
| spelling | Tsuyumoto, Isao 0002-7820 1551-2916 Wiley Materials Chemistry Ceramics and Composites http://dx.doi.org/10.1111/jace.15250 <jats:title>Abstract</jats:title><jats:p>A hexagonal form of tungsten trioxide (h‐WO<jats:sub>3</jats:sub>, particle size: 15.9‐57.1 nm) was found to be formed by a direct reaction between metallic tungsten powder (W, particle size: 0.45‐0.59 μm) and 15%‐30% hydrogen peroxide (H<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>) aq solution. Oxide film on the powder surface having the similar crystal structure as h‐WO<jats:sub>3</jats:sub> was essential for the formation, and the surface oxide film was formed by aging the powder in air at 45°C, a relative humidity of 100% (<jats:italic>P</jats:italic><jats:sub>H2O</jats:sub> 96 hPa) for 3‐28 days or in ambient atmosphere at room temperature for 12 years. The Rietveld analysis performed in the space group <jats:italic>P</jats:italic>6<jats:sub>3</jats:sub>/<jats:italic>mcm</jats:italic> (<jats:italic>Z</jats:italic> = 6) indicated the crystal structures were the same as those of the reported h‐WO<jats:sub>3</jats:sub> and that the crystallographic characteristic was as follows: <jats:italic>a</jats:italic> = 0.74219 nm, <jats:italic>c</jats:italic> = 0.77198 nm for h‐WO<jats:sub>3</jats:sub> from the 28‐day aged powder, and <jats:italic>a</jats:italic> = 0.74538 nm, <jats:italic>c</jats:italic> = 0.77194 nm for h‐WO<jats:sub>3</jats:sub> from the 12‐year aged powder.</jats:p> Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide Journal of the American Ceramic Society |
| spellingShingle | Tsuyumoto, Isao, Journal of the American Ceramic Society, Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide, Materials Chemistry, Ceramics and Composites |
| title | Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_full | Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_fullStr | Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_full_unstemmed | Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_short | Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_sort | facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| title_unstemmed | Facile synthesis of nanocrystalline hexagonal tungsten trioxide from metallic tungsten powder and hydrogen peroxide |
| topic | Materials Chemistry, Ceramics and Composites |
| url | http://dx.doi.org/10.1111/jace.15250 |