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Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium]
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| Zeitschriftentitel: | Acta Crystallographica Section E Structure Reports Online |
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| Personen und Körperschaften: | |
| In: | Acta Crystallographica Section E Structure Reports Online, 70, 2014, 1, S. m23-m23 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
International Union of Crystallography (IUCr)
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| Schlagwörter: |
| author_facet |
Smith, Graham Smith, Graham |
|---|---|
| author |
Smith, Graham |
| spellingShingle |
Smith, Graham Acta Crystallographica Section E Structure Reports Online Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] Condensed Matter Physics General Materials Science General Chemistry |
| author_sort |
smith, graham |
| spelling |
Smith, Graham 1600-5368 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s1600536813033503 <jats:p>In the title compound, [K<jats:sub>2</jats:sub>(C<jats:sub>7</jats:sub>H<jats:sub>3</jats:sub>Cl<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)]<jats:sub> <jats:italic>n</jats:italic> </jats:sub>, the potassium salt of 2,4-dichlorobenzoic acid, the repeating unit in the polymeric structure consists of two identical irregular KO<jats:sub>6</jats:sub>Cl units related by twofold rotational symmetry, linked by a bridging water molecule lying on the twofold axis. The coordination polyhedron about the K<jats:sup>+</jats:sup> ion comprises a carboxylate O atom and a Cl-atom donor from a bidentate chelate ligand interaction, four O-atom donors from a doubly bridging bidentate carboxylate <jats:italic>O</jats:italic>,<jats:italic>O</jats:italic>′-chelate interaction and the water molecule. A two-dimensional polymeric structure lying parallel to (100) is generated through a series of conjoined cyclic bridges between K<jats:sup>+</jats:sup> ions and is stabilized by water–carboxylate O—H...O hydrogen-bonding interactions.</jats:p> Poly[μ-aqua-bis(μ<sub>5</sub>-2,4-dichlorobenzoato)dipotassium] Acta Crystallographica Section E Structure Reports Online |
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10.1107/s1600536813033503 |
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Physik |
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DE-D275 DE-Bn3 DE-Brt1 DE-D161 DE-Zwi2 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 |
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International Union of Crystallography (IUCr), 2014 |
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International Union of Crystallography (IUCr), 2014 |
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1600-5368 |
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1600-5368 |
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International Union of Crystallography (IUCr) (CrossRef) |
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Acta Crystallographica Section E Structure Reports Online |
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49 |
| title |
Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_unstemmed |
Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_full |
Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_fullStr |
Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_full_unstemmed |
Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_short |
Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_sort |
poly[μ-aqua-bis(μ<sub>5</sub>-2,4-dichlorobenzoato)dipotassium] |
| topic |
Condensed Matter Physics General Materials Science General Chemistry |
| url |
http://dx.doi.org/10.1107/s1600536813033503 |
| publishDate |
2014 |
| physical |
m23-m23 |
| description |
<jats:p>In the title compound, [K<jats:sub>2</jats:sub>(C<jats:sub>7</jats:sub>H<jats:sub>3</jats:sub>Cl<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)]<jats:sub>
<jats:italic>n</jats:italic>
</jats:sub>, the potassium salt of 2,4-dichlorobenzoic acid, the repeating unit in the polymeric structure consists of two identical irregular KO<jats:sub>6</jats:sub>Cl units related by twofold rotational symmetry, linked by a bridging water molecule lying on the twofold axis. The coordination polyhedron about the K<jats:sup>+</jats:sup> ion comprises a carboxylate O atom and a Cl-atom donor from a bidentate chelate ligand interaction, four O-atom donors from a doubly bridging bidentate carboxylate <jats:italic>O</jats:italic>,<jats:italic>O</jats:italic>′-chelate interaction and the water molecule. A two-dimensional polymeric structure lying parallel to (100) is generated through a series of conjoined cyclic bridges between K<jats:sup>+</jats:sup> ions and is stabilized by water–carboxylate O—H...O hydrogen-bonding interactions.</jats:p> |
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| author | Smith, Graham |
| author_facet | Smith, Graham, Smith, Graham |
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| description | <jats:p>In the title compound, [K<jats:sub>2</jats:sub>(C<jats:sub>7</jats:sub>H<jats:sub>3</jats:sub>Cl<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)]<jats:sub> <jats:italic>n</jats:italic> </jats:sub>, the potassium salt of 2,4-dichlorobenzoic acid, the repeating unit in the polymeric structure consists of two identical irregular KO<jats:sub>6</jats:sub>Cl units related by twofold rotational symmetry, linked by a bridging water molecule lying on the twofold axis. The coordination polyhedron about the K<jats:sup>+</jats:sup> ion comprises a carboxylate O atom and a Cl-atom donor from a bidentate chelate ligand interaction, four O-atom donors from a doubly bridging bidentate carboxylate <jats:italic>O</jats:italic>,<jats:italic>O</jats:italic>′-chelate interaction and the water molecule. A two-dimensional polymeric structure lying parallel to (100) is generated through a series of conjoined cyclic bridges between K<jats:sup>+</jats:sup> ions and is stabilized by water–carboxylate O—H...O hydrogen-bonding interactions.</jats:p> |
| doi_str_mv | 10.1107/s1600536813033503 |
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| imprint | International Union of Crystallography (IUCr), 2014 |
| imprint_str_mv | International Union of Crystallography (IUCr), 2014 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zwi2, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
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| mega_collection | International Union of Crystallography (IUCr) (CrossRef) |
| physical | m23-m23 |
| publishDate | 2014 |
| publishDateSort | 2014 |
| publisher | International Union of Crystallography (IUCr) |
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| series | Acta Crystallographica Section E Structure Reports Online |
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| spelling | Smith, Graham 1600-5368 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s1600536813033503 <jats:p>In the title compound, [K<jats:sub>2</jats:sub>(C<jats:sub>7</jats:sub>H<jats:sub>3</jats:sub>Cl<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)]<jats:sub> <jats:italic>n</jats:italic> </jats:sub>, the potassium salt of 2,4-dichlorobenzoic acid, the repeating unit in the polymeric structure consists of two identical irregular KO<jats:sub>6</jats:sub>Cl units related by twofold rotational symmetry, linked by a bridging water molecule lying on the twofold axis. The coordination polyhedron about the K<jats:sup>+</jats:sup> ion comprises a carboxylate O atom and a Cl-atom donor from a bidentate chelate ligand interaction, four O-atom donors from a doubly bridging bidentate carboxylate <jats:italic>O</jats:italic>,<jats:italic>O</jats:italic>′-chelate interaction and the water molecule. A two-dimensional polymeric structure lying parallel to (100) is generated through a series of conjoined cyclic bridges between K<jats:sup>+</jats:sup> ions and is stabilized by water–carboxylate O—H...O hydrogen-bonding interactions.</jats:p> Poly[μ-aqua-bis(μ<sub>5</sub>-2,4-dichlorobenzoato)dipotassium] Acta Crystallographica Section E Structure Reports Online |
| spellingShingle | Smith, Graham, Acta Crystallographica Section E Structure Reports Online, Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium], Condensed Matter Physics, General Materials Science, General Chemistry |
| title | Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_full | Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_fullStr | Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_full_unstemmed | Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_short | Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| title_sort | poly[μ-aqua-bis(μ<sub>5</sub>-2,4-dichlorobenzoato)dipotassium] |
| title_unstemmed | Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium] |
| topic | Condensed Matter Physics, General Materials Science, General Chemistry |
| url | http://dx.doi.org/10.1107/s1600536813033503 |