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Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds
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| Zeitschriftentitel: | Dalton Transactions |
|---|---|
| Personen und Körperschaften: | , , , , |
| In: | Dalton Transactions, 45, 2016, 43, S. 17464-17473 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Royal Society of Chemistry (RSC)
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| Schlagwörter: |
| author_facet |
Sachs, Ulf Schaper, Gerrit Winkler, Daniela Kratzert, Daniel Kurz, Philipp Sachs, Ulf Schaper, Gerrit Winkler, Daniela Kratzert, Daniel Kurz, Philipp |
|---|---|
| author |
Sachs, Ulf Schaper, Gerrit Winkler, Daniela Kratzert, Daniel Kurz, Philipp |
| spellingShingle |
Sachs, Ulf Schaper, Gerrit Winkler, Daniela Kratzert, Daniel Kurz, Philipp Dalton Transactions Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds Inorganic Chemistry |
| author_sort |
sachs, ulf |
| spelling |
Sachs, Ulf Schaper, Gerrit Winkler, Daniela Kratzert, Daniel Kurz, Philipp 1477-9226 1477-9234 Royal Society of Chemistry (RSC) Inorganic Chemistry http://dx.doi.org/10.1039/c6dt02020h <p>The substitution of the carbonyl ligands of [Mn<sup>I</sup>(CO)<sub>3</sub>(κ<sup>3</sup>-L)] complexes can be triggered in two different ways: by near-UV irradiation or by electrochemical oxidation of Mn<sup>I</sup> to Mn<sup>II</sup>.</p> Light- or oxidation-triggered CO release from [Mn<sup>I</sup>(CO)<sub>3</sub>(κ<sup>3</sup>-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)<sub>2</sub>(L)<sub>2</sub>] compounds Dalton Transactions |
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| title |
Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_unstemmed |
Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_full |
Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_fullStr |
Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_full_unstemmed |
Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_short |
Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_sort |
light- or oxidation-triggered co release from [mn<sup>i</sup>(co)<sub>3</sub>(κ<sup>3</sup>-l)] complexes: reaction intermediates and a new synthetic route to [mniii/iv2(μ-o)<sub>2</sub>(l)<sub>2</sub>] compounds |
| topic |
Inorganic Chemistry |
| url |
http://dx.doi.org/10.1039/c6dt02020h |
| publishDate |
2016 |
| physical |
17464-17473 |
| description |
<p>The substitution of the carbonyl ligands of [Mn<sup>I</sup>(CO)<sub>3</sub>(κ<sup>3</sup>-L)] complexes can be triggered in two different ways: by near-UV irradiation or by electrochemical oxidation of Mn<sup>I</sup> to Mn<sup>II</sup>.</p> |
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| author | Sachs, Ulf, Schaper, Gerrit, Winkler, Daniela, Kratzert, Daniel, Kurz, Philipp |
| author_facet | Sachs, Ulf, Schaper, Gerrit, Winkler, Daniela, Kratzert, Daniel, Kurz, Philipp, Sachs, Ulf, Schaper, Gerrit, Winkler, Daniela, Kratzert, Daniel, Kurz, Philipp |
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| description | <p>The substitution of the carbonyl ligands of [Mn<sup>I</sup>(CO)<sub>3</sub>(κ<sup>3</sup>-L)] complexes can be triggered in two different ways: by near-UV irradiation or by electrochemical oxidation of Mn<sup>I</sup> to Mn<sup>II</sup>.</p> |
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| physical | 17464-17473 |
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| spelling | Sachs, Ulf Schaper, Gerrit Winkler, Daniela Kratzert, Daniel Kurz, Philipp 1477-9226 1477-9234 Royal Society of Chemistry (RSC) Inorganic Chemistry http://dx.doi.org/10.1039/c6dt02020h <p>The substitution of the carbonyl ligands of [Mn<sup>I</sup>(CO)<sub>3</sub>(κ<sup>3</sup>-L)] complexes can be triggered in two different ways: by near-UV irradiation or by electrochemical oxidation of Mn<sup>I</sup> to Mn<sup>II</sup>.</p> Light- or oxidation-triggered CO release from [Mn<sup>I</sup>(CO)<sub>3</sub>(κ<sup>3</sup>-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)<sub>2</sub>(L)<sub>2</sub>] compounds Dalton Transactions |
| spellingShingle | Sachs, Ulf, Schaper, Gerrit, Winkler, Daniela, Kratzert, Daniel, Kurz, Philipp, Dalton Transactions, Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds, Inorganic Chemistry |
| title | Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_full | Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_fullStr | Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_full_unstemmed | Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_short | Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| title_sort | light- or oxidation-triggered co release from [mn<sup>i</sup>(co)<sub>3</sub>(κ<sup>3</sup>-l)] complexes: reaction intermediates and a new synthetic route to [mniii/iv2(μ-o)<sub>2</sub>(l)<sub>2</sub>] compounds |
| title_unstemmed | Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds |
| topic | Inorganic Chemistry |
| url | http://dx.doi.org/10.1039/c6dt02020h |