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Multiple coupling of silanes with imido complexes of Mo
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| Zeitschriftentitel: | Dalton Trans. |
|---|---|
| Personen und Körperschaften: | , , , , , , |
| In: | Dalton Trans., 43, 2014, 22, S. 8446-8453 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Royal Society of Chemistry (RSC)
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| Schlagwörter: |
| author_facet |
Khalimon, Andrey Y. McLeod, Nicolas A. Ignatov, Stanislav K. Okhapkin, Andrey I. Kuzmina, Lyudmila G. Howard, Judith A. K. Nikonov, Georgii I. Khalimon, Andrey Y. McLeod, Nicolas A. Ignatov, Stanislav K. Okhapkin, Andrey I. Kuzmina, Lyudmila G. Howard, Judith A. K. Nikonov, Georgii I. |
|---|---|
| author |
Khalimon, Andrey Y. McLeod, Nicolas A. Ignatov, Stanislav K. Okhapkin, Andrey I. Kuzmina, Lyudmila G. Howard, Judith A. K. Nikonov, Georgii I. |
| spellingShingle |
Khalimon, Andrey Y. McLeod, Nicolas A. Ignatov, Stanislav K. Okhapkin, Andrey I. Kuzmina, Lyudmila G. Howard, Judith A. K. Nikonov, Georgii I. Dalton Trans. Multiple coupling of silanes with imido complexes of Mo Inorganic Chemistry |
| author_sort |
khalimon, andrey y. |
| spelling |
Khalimon, Andrey Y. McLeod, Nicolas A. Ignatov, Stanislav K. Okhapkin, Andrey I. Kuzmina, Lyudmila G. Howard, Judith A. K. Nikonov, Georgii I. 1477-9226 1477-9234 Royal Society of Chemistry (RSC) Inorganic Chemistry http://dx.doi.org/10.1039/c4dt00154k <p>Coupling of (<sup>t</sup>BuN)<sub>2</sub>Mo(PMe<sub>3</sub>)(L) (L = PMe<sub>2</sub>, C<sub>2</sub>H<sub>4</sub>) with PhSiH<sub>3</sub>results in a product of triple silane addition, (<sup>t</sup>BuN){μ-<sup>t</sup>BuN(SiHPh)<sub>2</sub>}Mo(H)(SiH<sub>2</sub>Ph)(PMe<sub>3</sub>)<sub>2</sub>(<bold>3</bold>), formation of which proceeds<italic>via</italic>a series of silanimine and Si–H⋯Mo agostic species.</p> Multiple coupling of silanes with imido complexes of Mo Dalton Trans. |
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| title |
Multiple coupling of silanes with imido complexes of Mo |
| title_unstemmed |
Multiple coupling of silanes with imido complexes of Mo |
| title_full |
Multiple coupling of silanes with imido complexes of Mo |
| title_fullStr |
Multiple coupling of silanes with imido complexes of Mo |
| title_full_unstemmed |
Multiple coupling of silanes with imido complexes of Mo |
| title_short |
Multiple coupling of silanes with imido complexes of Mo |
| title_sort |
multiple coupling of silanes with imido complexes of mo |
| topic |
Inorganic Chemistry |
| url |
http://dx.doi.org/10.1039/c4dt00154k |
| publishDate |
2014 |
| physical |
8446-8453 |
| description |
<p>Coupling of (<sup>t</sup>BuN)<sub>2</sub>Mo(PMe<sub>3</sub>)(L) (L = PMe<sub>2</sub>, C<sub>2</sub>H<sub>4</sub>) with PhSiH<sub>3</sub>results in a product of triple silane addition, (<sup>t</sup>BuN){μ-<sup>t</sup>BuN(SiHPh)<sub>2</sub>}Mo(H)(SiH<sub>2</sub>Ph)(PMe<sub>3</sub>)<sub>2</sub>(<bold>3</bold>), formation of which proceeds<italic>via</italic>a series of silanimine and Si–H⋯Mo agostic species.</p> |
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| author | Khalimon, Andrey Y., McLeod, Nicolas A., Ignatov, Stanislav K., Okhapkin, Andrey I., Kuzmina, Lyudmila G., Howard, Judith A. K., Nikonov, Georgii I. |
| author_facet | Khalimon, Andrey Y., McLeod, Nicolas A., Ignatov, Stanislav K., Okhapkin, Andrey I., Kuzmina, Lyudmila G., Howard, Judith A. K., Nikonov, Georgii I., Khalimon, Andrey Y., McLeod, Nicolas A., Ignatov, Stanislav K., Okhapkin, Andrey I., Kuzmina, Lyudmila G., Howard, Judith A. K., Nikonov, Georgii I. |
| author_sort | khalimon, andrey y. |
| container_issue | 22 |
| container_start_page | 8446 |
| container_title | Dalton Trans. |
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| description | <p>Coupling of (<sup>t</sup>BuN)<sub>2</sub>Mo(PMe<sub>3</sub>)(L) (L = PMe<sub>2</sub>, C<sub>2</sub>H<sub>4</sub>) with PhSiH<sub>3</sub>results in a product of triple silane addition, (<sup>t</sup>BuN){μ-<sup>t</sup>BuN(SiHPh)<sub>2</sub>}Mo(H)(SiH<sub>2</sub>Ph)(PMe<sub>3</sub>)<sub>2</sub>(<bold>3</bold>), formation of which proceeds<italic>via</italic>a series of silanimine and Si–H⋯Mo agostic species.</p> |
| doi_str_mv | 10.1039/c4dt00154k |
| facet_avail | Online |
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| physical | 8446-8453 |
| publishDate | 2014 |
| publishDateSort | 2014 |
| publisher | Royal Society of Chemistry (RSC) |
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| series | Dalton Trans. |
| source_id | 49 |
| spelling | Khalimon, Andrey Y. McLeod, Nicolas A. Ignatov, Stanislav K. Okhapkin, Andrey I. Kuzmina, Lyudmila G. Howard, Judith A. K. Nikonov, Georgii I. 1477-9226 1477-9234 Royal Society of Chemistry (RSC) Inorganic Chemistry http://dx.doi.org/10.1039/c4dt00154k <p>Coupling of (<sup>t</sup>BuN)<sub>2</sub>Mo(PMe<sub>3</sub>)(L) (L = PMe<sub>2</sub>, C<sub>2</sub>H<sub>4</sub>) with PhSiH<sub>3</sub>results in a product of triple silane addition, (<sup>t</sup>BuN){μ-<sup>t</sup>BuN(SiHPh)<sub>2</sub>}Mo(H)(SiH<sub>2</sub>Ph)(PMe<sub>3</sub>)<sub>2</sub>(<bold>3</bold>), formation of which proceeds<italic>via</italic>a series of silanimine and Si–H⋯Mo agostic species.</p> Multiple coupling of silanes with imido complexes of Mo Dalton Trans. |
| spellingShingle | Khalimon, Andrey Y., McLeod, Nicolas A., Ignatov, Stanislav K., Okhapkin, Andrey I., Kuzmina, Lyudmila G., Howard, Judith A. K., Nikonov, Georgii I., Dalton Trans., Multiple coupling of silanes with imido complexes of Mo, Inorganic Chemistry |
| title | Multiple coupling of silanes with imido complexes of Mo |
| title_full | Multiple coupling of silanes with imido complexes of Mo |
| title_fullStr | Multiple coupling of silanes with imido complexes of Mo |
| title_full_unstemmed | Multiple coupling of silanes with imido complexes of Mo |
| title_short | Multiple coupling of silanes with imido complexes of Mo |
| title_sort | multiple coupling of silanes with imido complexes of mo |
| title_unstemmed | Multiple coupling of silanes with imido complexes of Mo |
| topic | Inorganic Chemistry |
| url | http://dx.doi.org/10.1039/c4dt00154k |