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Site-selective bromination of sp3 C–H bonds
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Zeitschriftentitel: | Chemical Science |
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Personen und Körperschaften: | , , , , |
In: | Chemical Science, 9, 2018, 1, S. 100-104 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Royal Society of Chemistry (RSC)
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Schlagwörter: |
author_facet |
Sathyamoorthi, Shyam Banerjee, Shibdas Du Bois, J. Burns, Noah Z. Zare, Richard N. Sathyamoorthi, Shyam Banerjee, Shibdas Du Bois, J. Burns, Noah Z. Zare, Richard N. |
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author |
Sathyamoorthi, Shyam Banerjee, Shibdas Du Bois, J. Burns, Noah Z. Zare, Richard N. |
spellingShingle |
Sathyamoorthi, Shyam Banerjee, Shibdas Du Bois, J. Burns, Noah Z. Zare, Richard N. Chemical Science Site-selective bromination of sp3 C–H bonds General Chemistry |
author_sort |
sathyamoorthi, shyam |
spelling |
Sathyamoorthi, Shyam Banerjee, Shibdas Du Bois, J. Burns, Noah Z. Zare, Richard N. 2041-6520 2041-6539 Royal Society of Chemistry (RSC) General Chemistry http://dx.doi.org/10.1039/c7sc04611a <p>A method for converting sp<sup>3</sup> C–H to C–Br bonds using an <italic>N</italic>-methyl sulfamate directing group is described. For all sulfamates examined, bromination occurs with high selectivity at the γ-carbon, affording a predictable method for C–H bond halogenation.</p> Site-selective bromination of sp<sup>3</sup> C–H bonds Chemical Science |
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10.1039/c7sc04611a |
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Royal Society of Chemistry (RSC), 2018 |
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Royal Society of Chemistry (RSC), 2018 |
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2041-6520 2041-6539 |
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2018 |
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Royal Society of Chemistry (RSC) |
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Chemical Science |
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title |
Site-selective bromination of sp3 C–H bonds |
title_unstemmed |
Site-selective bromination of sp3 C–H bonds |
title_full |
Site-selective bromination of sp3 C–H bonds |
title_fullStr |
Site-selective bromination of sp3 C–H bonds |
title_full_unstemmed |
Site-selective bromination of sp3 C–H bonds |
title_short |
Site-selective bromination of sp3 C–H bonds |
title_sort |
site-selective bromination of sp<sup>3</sup> c–h bonds |
topic |
General Chemistry |
url |
http://dx.doi.org/10.1039/c7sc04611a |
publishDate |
2018 |
physical |
100-104 |
description |
<p>A method for converting sp<sup>3</sup> C–H to C–Br bonds using an <italic>N</italic>-methyl sulfamate directing group is described. For all sulfamates examined, bromination occurs with high selectivity at the γ-carbon, affording a predictable method for C–H bond halogenation.</p> |
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author | Sathyamoorthi, Shyam, Banerjee, Shibdas, Du Bois, J., Burns, Noah Z., Zare, Richard N. |
author_facet | Sathyamoorthi, Shyam, Banerjee, Shibdas, Du Bois, J., Burns, Noah Z., Zare, Richard N., Sathyamoorthi, Shyam, Banerjee, Shibdas, Du Bois, J., Burns, Noah Z., Zare, Richard N. |
author_sort | sathyamoorthi, shyam |
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container_start_page | 100 |
container_title | Chemical Science |
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description | <p>A method for converting sp<sup>3</sup> C–H to C–Br bonds using an <italic>N</italic>-methyl sulfamate directing group is described. For all sulfamates examined, bromination occurs with high selectivity at the γ-carbon, affording a predictable method for C–H bond halogenation.</p> |
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imprint | Royal Society of Chemistry (RSC), 2018 |
imprint_str_mv | Royal Society of Chemistry (RSC), 2018 |
institution | DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1 |
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physical | 100-104 |
publishDate | 2018 |
publishDateSort | 2018 |
publisher | Royal Society of Chemistry (RSC) |
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series | Chemical Science |
source_id | 49 |
spelling | Sathyamoorthi, Shyam Banerjee, Shibdas Du Bois, J. Burns, Noah Z. Zare, Richard N. 2041-6520 2041-6539 Royal Society of Chemistry (RSC) General Chemistry http://dx.doi.org/10.1039/c7sc04611a <p>A method for converting sp<sup>3</sup> C–H to C–Br bonds using an <italic>N</italic>-methyl sulfamate directing group is described. For all sulfamates examined, bromination occurs with high selectivity at the γ-carbon, affording a predictable method for C–H bond halogenation.</p> Site-selective bromination of sp<sup>3</sup> C–H bonds Chemical Science |
spellingShingle | Sathyamoorthi, Shyam, Banerjee, Shibdas, Du Bois, J., Burns, Noah Z., Zare, Richard N., Chemical Science, Site-selective bromination of sp3 C–H bonds, General Chemistry |
title | Site-selective bromination of sp3 C–H bonds |
title_full | Site-selective bromination of sp3 C–H bonds |
title_fullStr | Site-selective bromination of sp3 C–H bonds |
title_full_unstemmed | Site-selective bromination of sp3 C–H bonds |
title_short | Site-selective bromination of sp3 C–H bonds |
title_sort | site-selective bromination of sp<sup>3</sup> c–h bonds |
title_unstemmed | Site-selective bromination of sp3 C–H bonds |
topic | General Chemistry |
url | http://dx.doi.org/10.1039/c7sc04611a |