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A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions
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| Zeitschriftentitel: | Journal of the American Oil Chemists' Society |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Journal of the American Oil Chemists' Society, 72, 1995, 7, S. 823-826 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Alexandridis, Paschalis Holzwarth, Josef F. Alan Hatton, T. Alexandridis, Paschalis Holzwarth, Josef F. Alan Hatton, T. |
|---|---|
| author |
Alexandridis, Paschalis Holzwarth, Josef F. Alan Hatton, T. |
| spellingShingle |
Alexandridis, Paschalis Holzwarth, Josef F. Alan Hatton, T. Journal of the American Oil Chemists' Society A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions Organic Chemistry General Chemical Engineering |
| author_sort |
alexandridis, paschalis |
| spelling |
Alexandridis, Paschalis Holzwarth, Josef F. Alan Hatton, T. 0003-021X 1558-9331 Wiley Organic Chemistry General Chemical Engineering http://dx.doi.org/10.1007/bf02541032 <jats:title>Abstract</jats:title><jats:p>An empirical correlation is presented for the estimation of critical micellization concentrations (CMC) and critical micellization temperatures (CMT) for poly(ethylene oxide)‐<jats:italic>block</jats:italic>‐poly(propylene oxide)‐<jats:italic>block</jats:italic>‐poly(ethylene oxide) copolymers in aqueous solutions. The CMC and CMT are expressed as a function of the polyol molecular weight, composition, and temperature (for CMC determination) or concentration (in the case of CMT). The correlation was developed from experimental CMT data for a set of 12 polyols that covered a wide range of molecular weights (2900–14600) and poly(ethylene oxide) contents (30–80 wt%) and is based on a simple expression for the standard free energy of micellization. Such a correlation should be useful to practitioners of the field as it allows easy prediction of CMC and CMT for a wide range of polyols with a minimal number of input parameters.</jats:p> A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions Journal of the American Oil Chemists' Society |
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Journal of the American Oil Chemists' Society |
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| title |
A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_unstemmed |
A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_full |
A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_fullStr |
A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_full_unstemmed |
A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_short |
A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_sort |
a correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| topic |
Organic Chemistry General Chemical Engineering |
| url |
http://dx.doi.org/10.1007/bf02541032 |
| publishDate |
1995 |
| physical |
823-826 |
| description |
<jats:title>Abstract</jats:title><jats:p>An empirical correlation is presented for the estimation of critical micellization concentrations (CMC) and critical micellization temperatures (CMT) for poly(ethylene oxide)‐<jats:italic>block</jats:italic>‐poly(propylene oxide)‐<jats:italic>block</jats:italic>‐poly(ethylene oxide) copolymers in aqueous solutions. The CMC and CMT are expressed as a function of the polyol molecular weight, composition, and temperature (for CMC determination) or concentration (in the case of CMT). The correlation was developed from experimental CMT data for a set of 12 polyols that covered a wide range of molecular weights (2900–14600) and poly(ethylene oxide) contents (30–80 wt%) and is based on a simple expression for the standard free energy of micellization. Such a correlation should be useful to practitioners of the field as it allows easy prediction of CMC and CMT for a wide range of polyols with a minimal number of input parameters.</jats:p> |
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| author | Alexandridis, Paschalis, Holzwarth, Josef F., Alan Hatton, T. |
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| description | <jats:title>Abstract</jats:title><jats:p>An empirical correlation is presented for the estimation of critical micellization concentrations (CMC) and critical micellization temperatures (CMT) for poly(ethylene oxide)‐<jats:italic>block</jats:italic>‐poly(propylene oxide)‐<jats:italic>block</jats:italic>‐poly(ethylene oxide) copolymers in aqueous solutions. The CMC and CMT are expressed as a function of the polyol molecular weight, composition, and temperature (for CMC determination) or concentration (in the case of CMT). The correlation was developed from experimental CMT data for a set of 12 polyols that covered a wide range of molecular weights (2900–14600) and poly(ethylene oxide) contents (30–80 wt%) and is based on a simple expression for the standard free energy of micellization. Such a correlation should be useful to practitioners of the field as it allows easy prediction of CMC and CMT for a wide range of polyols with a minimal number of input parameters.</jats:p> |
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| imprint | Wiley, 1995 |
| imprint_str_mv | Wiley, 1995 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
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| spelling | Alexandridis, Paschalis Holzwarth, Josef F. Alan Hatton, T. 0003-021X 1558-9331 Wiley Organic Chemistry General Chemical Engineering http://dx.doi.org/10.1007/bf02541032 <jats:title>Abstract</jats:title><jats:p>An empirical correlation is presented for the estimation of critical micellization concentrations (CMC) and critical micellization temperatures (CMT) for poly(ethylene oxide)‐<jats:italic>block</jats:italic>‐poly(propylene oxide)‐<jats:italic>block</jats:italic>‐poly(ethylene oxide) copolymers in aqueous solutions. The CMC and CMT are expressed as a function of the polyol molecular weight, composition, and temperature (for CMC determination) or concentration (in the case of CMT). The correlation was developed from experimental CMT data for a set of 12 polyols that covered a wide range of molecular weights (2900–14600) and poly(ethylene oxide) contents (30–80 wt%) and is based on a simple expression for the standard free energy of micellization. Such a correlation should be useful to practitioners of the field as it allows easy prediction of CMC and CMT for a wide range of polyols with a minimal number of input parameters.</jats:p> A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions Journal of the American Oil Chemists' Society |
| spellingShingle | Alexandridis, Paschalis, Holzwarth, Josef F., Alan Hatton, T., Journal of the American Oil Chemists' Society, A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions, Organic Chemistry, General Chemical Engineering |
| title | A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_full | A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_fullStr | A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_full_unstemmed | A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_short | A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_sort | a correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| title_unstemmed | A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions |
| topic | Organic Chemistry, General Chemical Engineering |
| url | http://dx.doi.org/10.1007/bf02541032 |