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Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs
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| Zeitschriftentitel: | ChemistrySelect |
|---|---|
| Personen und Körperschaften: | |
| In: | ChemistrySelect, 4, 2019, 6, S. 1866-1871 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Santra, Biswajit Santra, Biswajit |
|---|---|
| author |
Santra, Biswajit |
| spellingShingle |
Santra, Biswajit ChemistrySelect Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs General Chemistry |
| author_sort |
santra, biswajit |
| spelling |
Santra, Biswajit 2365-6549 2365-6549 Wiley General Chemistry http://dx.doi.org/10.1002/slct.201803427 <jats:title>Abstract</jats:title><jats:p>A trinuclear Cu(I)‐NHC [Cu<jats:sub>3</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)<jats:sub>3</jats:sub> (<jats:bold>1</jats:bold>) has been synthesized in a very short period of time (5‐10 min) in multi‐gram scale using less expensive Cu(OAc)<jats:sub>2</jats:sub>⋅H<jats:sub>2</jats:sub>O and py<jats:sub>2</jats:sub>imH⋅PF<jats:sub>6</jats:sub> in presence of L‐ascorbic acid in CH<jats:sub>3</jats:sub>OH under aerobic conditions at room temperature. Further, a very facile synthetic route has been developed to obtain a mononuclear [Cu(py<jats:sub>2</jats:sub>im)(phen)](PF<jats:sub>6</jats:sub>) (<jats:bold>3</jats:bold>), binuclear [Cu<jats:sub>2</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)<jats:sub>2</jats:sub> (<jats:bold>2</jats:bold>) and 1D polymeric chain of Cu(I)‐NHC {[Cu(py<jats:sub>2</jats:sub>im)(4,4′‐bpy)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>4</jats:bold>), {[Cu(py<jats:sub>2</jats:sub>im)(bpe)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>5</jats:bold>), {[Cu(py<jats:sub>2</jats:sub>im)(bpe)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub><jats:sup>.</jats:sup>{[Cu<jats:sub>2</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>6</jats:bold>) and {[Cu(py<jats:sub>2</jats:sub>im)(azpy)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>7</jats:bold>) from a trinuclear Cu(I)‐NHC cluster (<jats:bold>1</jats:bold>) using additional linear bridging co‐ligands such as 4,4′‐bipyridine (bpy), trans‐1,2‐bis(4‐pyridyl)ethene (bpe), 4,4′‐azobispyridine (azpy) etc. In CH<jats:sub>3</jats:sub>CN, <jats:bold>4</jats:bold> and <jats:bold>5</jats:bold> were rearranged to adamantanoid core 3D Cu(I)‐MOF {[Cu(bpy)<jats:sub>2</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>8</jats:bold>) and {[Cu(bpe)<jats:sub>2</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>9</jats:bold>), respectively. X‐ray crystallographic structure of <jats:bold>6</jats:bold> exhibits two molecules of <jats:bold>2</jats:bold> which was trapped between two polymeric chains.</jats:p> Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs ChemistrySelect |
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10.1002/slct.201803427 |
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Online |
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DE-14 DE-105 DE-Ch1 DE-L229 DE-D275 DE-Bn3 DE-Brt1 DE-D161 DE-Zi4 DE-Gla1 DE-15 DE-Pl11 DE-Rs1 |
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Wiley, 2019 |
| imprint_str_mv |
Wiley, 2019 |
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2365-6549 |
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2365-6549 |
| language |
English |
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Wiley (CrossRef) |
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santra2019molecularrearrangementoftrinuclearcuinhcsynthesisofmonobinuclearandpolymericcuinhcs |
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2019 |
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Wiley |
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ChemistrySelect |
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49 |
| title |
Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_unstemmed |
Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_full |
Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_fullStr |
Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_full_unstemmed |
Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_short |
Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_sort |
molecular rearrangement of trinuclear cu(i)‐nhc: synthesis of mono, binuclear and polymeric cu(i)‐nhcs |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1002/slct.201803427 |
| publishDate |
2019 |
| physical |
1866-1871 |
| description |
<jats:title>Abstract</jats:title><jats:p>A trinuclear Cu(I)‐NHC [Cu<jats:sub>3</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)<jats:sub>3</jats:sub> (<jats:bold>1</jats:bold>) has been synthesized in a very short period of time (5‐10 min) in multi‐gram scale using less expensive Cu(OAc)<jats:sub>2</jats:sub>⋅H<jats:sub>2</jats:sub>O and py<jats:sub>2</jats:sub>imH⋅PF<jats:sub>6</jats:sub> in presence of L‐ascorbic acid in CH<jats:sub>3</jats:sub>OH under aerobic conditions at room temperature. Further, a very facile synthetic route has been developed to obtain a mononuclear [Cu(py<jats:sub>2</jats:sub>im)(phen)](PF<jats:sub>6</jats:sub>) (<jats:bold>3</jats:bold>), binuclear [Cu<jats:sub>2</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)<jats:sub>2</jats:sub> (<jats:bold>2</jats:bold>) and 1D polymeric chain of Cu(I)‐NHC {[Cu(py<jats:sub>2</jats:sub>im)(4,4′‐bpy)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>4</jats:bold>), {[Cu(py<jats:sub>2</jats:sub>im)(bpe)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>5</jats:bold>), {[Cu(py<jats:sub>2</jats:sub>im)(bpe)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub><jats:sup>.</jats:sup>{[Cu<jats:sub>2</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>6</jats:bold>) and {[Cu(py<jats:sub>2</jats:sub>im)(azpy)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>7</jats:bold>) from a trinuclear Cu(I)‐NHC cluster (<jats:bold>1</jats:bold>) using additional linear bridging co‐ligands such as 4,4′‐bipyridine (bpy), trans‐1,2‐bis(4‐pyridyl)ethene (bpe), 4,4′‐azobispyridine (azpy) etc. In CH<jats:sub>3</jats:sub>CN, <jats:bold>4</jats:bold> and <jats:bold>5</jats:bold> were rearranged to adamantanoid core 3D Cu(I)‐MOF {[Cu(bpy)<jats:sub>2</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>8</jats:bold>) and {[Cu(bpe)<jats:sub>2</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>9</jats:bold>), respectively. X‐ray crystallographic structure of <jats:bold>6</jats:bold> exhibits two molecules of <jats:bold>2</jats:bold> which was trapped between two polymeric chains.</jats:p> |
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url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Molecular+Rearrangement+of+Trinuclear+Cu%28I%29%E2%80%90NHC%3A+Synthesis+of+Mono%2C+Binuclear+and+Polymeric+Cu%28I%29%E2%80%90NHCs&rft.date=2019-02-14&genre=article&issn=2365-6549&volume=4&issue=6&spage=1866&epage=1871&pages=1866-1871&jtitle=ChemistrySelect&atitle=Molecular+Rearrangement+of+Trinuclear+Cu%28I%29%E2%80%90NHC%3A+Synthesis+of+Mono%2C+Binuclear+and+Polymeric+Cu%28I%29%E2%80%90NHCs&aulast=Santra&aufirst=Biswajit&rft_id=info%3Adoi%2F10.1002%2Fslct.201803427&rft.language%5B0%5D=eng |
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| author | Santra, Biswajit |
| author_facet | Santra, Biswajit, Santra, Biswajit |
| author_sort | santra, biswajit |
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| description | <jats:title>Abstract</jats:title><jats:p>A trinuclear Cu(I)‐NHC [Cu<jats:sub>3</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)<jats:sub>3</jats:sub> (<jats:bold>1</jats:bold>) has been synthesized in a very short period of time (5‐10 min) in multi‐gram scale using less expensive Cu(OAc)<jats:sub>2</jats:sub>⋅H<jats:sub>2</jats:sub>O and py<jats:sub>2</jats:sub>imH⋅PF<jats:sub>6</jats:sub> in presence of L‐ascorbic acid in CH<jats:sub>3</jats:sub>OH under aerobic conditions at room temperature. Further, a very facile synthetic route has been developed to obtain a mononuclear [Cu(py<jats:sub>2</jats:sub>im)(phen)](PF<jats:sub>6</jats:sub>) (<jats:bold>3</jats:bold>), binuclear [Cu<jats:sub>2</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)<jats:sub>2</jats:sub> (<jats:bold>2</jats:bold>) and 1D polymeric chain of Cu(I)‐NHC {[Cu(py<jats:sub>2</jats:sub>im)(4,4′‐bpy)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>4</jats:bold>), {[Cu(py<jats:sub>2</jats:sub>im)(bpe)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>5</jats:bold>), {[Cu(py<jats:sub>2</jats:sub>im)(bpe)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub><jats:sup>.</jats:sup>{[Cu<jats:sub>2</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>6</jats:bold>) and {[Cu(py<jats:sub>2</jats:sub>im)(azpy)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>7</jats:bold>) from a trinuclear Cu(I)‐NHC cluster (<jats:bold>1</jats:bold>) using additional linear bridging co‐ligands such as 4,4′‐bipyridine (bpy), trans‐1,2‐bis(4‐pyridyl)ethene (bpe), 4,4′‐azobispyridine (azpy) etc. In CH<jats:sub>3</jats:sub>CN, <jats:bold>4</jats:bold> and <jats:bold>5</jats:bold> were rearranged to adamantanoid core 3D Cu(I)‐MOF {[Cu(bpy)<jats:sub>2</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>8</jats:bold>) and {[Cu(bpe)<jats:sub>2</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>9</jats:bold>), respectively. X‐ray crystallographic structure of <jats:bold>6</jats:bold> exhibits two molecules of <jats:bold>2</jats:bold> which was trapped between two polymeric chains.</jats:p> |
| doi_str_mv | 10.1002/slct.201803427 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9zbGN0LjIwMTgwMzQyNw |
| imprint | Wiley, 2019 |
| imprint_str_mv | Wiley, 2019 |
| institution | DE-14, DE-105, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zi4, DE-Gla1, DE-15, DE-Pl11, DE-Rs1 |
| issn | 2365-6549 |
| issn_str_mv | 2365-6549 |
| language | English |
| last_indexed | 2024-03-01T14:12:20.844Z |
| match_str | santra2019molecularrearrangementoftrinuclearcuinhcsynthesisofmonobinuclearandpolymericcuinhcs |
| mega_collection | Wiley (CrossRef) |
| physical | 1866-1871 |
| publishDate | 2019 |
| publishDateSort | 2019 |
| publisher | Wiley |
| record_format | ai |
| recordtype | ai |
| series | ChemistrySelect |
| source_id | 49 |
| spelling | Santra, Biswajit 2365-6549 2365-6549 Wiley General Chemistry http://dx.doi.org/10.1002/slct.201803427 <jats:title>Abstract</jats:title><jats:p>A trinuclear Cu(I)‐NHC [Cu<jats:sub>3</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)<jats:sub>3</jats:sub> (<jats:bold>1</jats:bold>) has been synthesized in a very short period of time (5‐10 min) in multi‐gram scale using less expensive Cu(OAc)<jats:sub>2</jats:sub>⋅H<jats:sub>2</jats:sub>O and py<jats:sub>2</jats:sub>imH⋅PF<jats:sub>6</jats:sub> in presence of L‐ascorbic acid in CH<jats:sub>3</jats:sub>OH under aerobic conditions at room temperature. Further, a very facile synthetic route has been developed to obtain a mononuclear [Cu(py<jats:sub>2</jats:sub>im)(phen)](PF<jats:sub>6</jats:sub>) (<jats:bold>3</jats:bold>), binuclear [Cu<jats:sub>2</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)<jats:sub>2</jats:sub> (<jats:bold>2</jats:bold>) and 1D polymeric chain of Cu(I)‐NHC {[Cu(py<jats:sub>2</jats:sub>im)(4,4′‐bpy)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>4</jats:bold>), {[Cu(py<jats:sub>2</jats:sub>im)(bpe)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>5</jats:bold>), {[Cu(py<jats:sub>2</jats:sub>im)(bpe)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub><jats:sup>.</jats:sup>{[Cu<jats:sub>2</jats:sub>(py<jats:sub>2</jats:sub>im)<jats:sub>3</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>6</jats:bold>) and {[Cu(py<jats:sub>2</jats:sub>im)(azpy)](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>7</jats:bold>) from a trinuclear Cu(I)‐NHC cluster (<jats:bold>1</jats:bold>) using additional linear bridging co‐ligands such as 4,4′‐bipyridine (bpy), trans‐1,2‐bis(4‐pyridyl)ethene (bpe), 4,4′‐azobispyridine (azpy) etc. In CH<jats:sub>3</jats:sub>CN, <jats:bold>4</jats:bold> and <jats:bold>5</jats:bold> were rearranged to adamantanoid core 3D Cu(I)‐MOF {[Cu(bpy)<jats:sub>2</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>8</jats:bold>) and {[Cu(bpe)<jats:sub>2</jats:sub>](PF<jats:sub>6</jats:sub>)}<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>9</jats:bold>), respectively. X‐ray crystallographic structure of <jats:bold>6</jats:bold> exhibits two molecules of <jats:bold>2</jats:bold> which was trapped between two polymeric chains.</jats:p> Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs ChemistrySelect |
| spellingShingle | Santra, Biswajit, ChemistrySelect, Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs, General Chemistry |
| title | Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_full | Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_fullStr | Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_full_unstemmed | Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_short | Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| title_sort | molecular rearrangement of trinuclear cu(i)‐nhc: synthesis of mono, binuclear and polymeric cu(i)‐nhcs |
| title_unstemmed | Molecular Rearrangement of Trinuclear Cu(I)‐NHC: Synthesis of Mono, Binuclear and Polymeric Cu(I)‐NHCs |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1002/slct.201803427 |