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An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity
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| Zeitschriftentitel: | Surface and Interface Analysis |
|---|---|
| Personen und Körperschaften: | , |
| In: | Surface and Interface Analysis, 2, 1980, 5, S. 191-196 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Proctor, A. Sherwood, P. M. A. Proctor, A. Sherwood, P. M. A. |
|---|---|
| author |
Proctor, A. Sherwood, P. M. A. |
| spellingShingle |
Proctor, A. Sherwood, P. M. A. Surface and Interface Analysis An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity Materials Chemistry Surfaces, Coatings and Films Surfaces and Interfaces Condensed Matter Physics General Chemistry |
| author_sort |
proctor, a. |
| spelling |
Proctor, A. Sherwood, P. M. A. 0142-2421 1096-9918 Wiley Materials Chemistry Surfaces, Coatings and Films Surfaces and Interfaces Condensed Matter Physics General Chemistry http://dx.doi.org/10.1002/sia.740020508 <jats:title>Abstract</jats:title><jats:p>The paper reports the detection by XPS of a bulk antimony impurity in a gold foil sample, as a result of its surface segregation upon heating <jats:italic>in vacuo</jats:italic> at 600 °C. The O 1s spectra indicate at least two possible oxygen species present in the vicinity of the gold surface. The interaction of the surface segregated antimony with oxygen does not appear to be as is reported for calcium impurities, the antimony showing the binding energy corresponding to metal. Also the amount of surface segregated antimony impurity does not seem to be as dependent as calcium impurities on previously adsorbed or gas‐phase oxygen. The use of the carbon 1s peak rather than the gold 4f peaks is found to be a more reliable calibration reference.</jats:p> An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity Surface and Interface Analysis |
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Wiley, 1980 |
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Wiley, 1980 |
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Surface and Interface Analysis |
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| title |
An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_unstemmed |
An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_full |
An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_fullStr |
An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_full_unstemmed |
An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_short |
An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_sort |
an x‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| topic |
Materials Chemistry Surfaces, Coatings and Films Surfaces and Interfaces Condensed Matter Physics General Chemistry |
| url |
http://dx.doi.org/10.1002/sia.740020508 |
| publishDate |
1980 |
| physical |
191-196 |
| description |
<jats:title>Abstract</jats:title><jats:p>The paper reports the detection by XPS of a bulk antimony impurity in a gold foil sample, as a result of its surface segregation upon heating <jats:italic>in vacuo</jats:italic> at 600 °C. The O 1s spectra indicate at least two possible oxygen species present in the vicinity of the gold surface. The interaction of the surface segregated antimony with oxygen does not appear to be as is reported for calcium impurities, the antimony showing the binding energy corresponding to metal. Also the amount of surface segregated antimony impurity does not seem to be as dependent as calcium impurities on previously adsorbed or gas‐phase oxygen. The use of the carbon 1s peak rather than the gold 4f peaks is found to be a more reliable calibration reference.</jats:p> |
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| author | Proctor, A., Sherwood, P. M. A. |
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| author_sort | proctor, a. |
| container_issue | 5 |
| container_start_page | 191 |
| container_title | Surface and Interface Analysis |
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| description | <jats:title>Abstract</jats:title><jats:p>The paper reports the detection by XPS of a bulk antimony impurity in a gold foil sample, as a result of its surface segregation upon heating <jats:italic>in vacuo</jats:italic> at 600 °C. The O 1s spectra indicate at least two possible oxygen species present in the vicinity of the gold surface. The interaction of the surface segregated antimony with oxygen does not appear to be as is reported for calcium impurities, the antimony showing the binding energy corresponding to metal. Also the amount of surface segregated antimony impurity does not seem to be as dependent as calcium impurities on previously adsorbed or gas‐phase oxygen. The use of the carbon 1s peak rather than the gold 4f peaks is found to be a more reliable calibration reference.</jats:p> |
| doi_str_mv | 10.1002/sia.740020508 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9zaWEuNzQwMDIwNTA4 |
| imprint | Wiley, 1980 |
| imprint_str_mv | Wiley, 1980 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Rs1, DE-Pl11, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161 |
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| language | English |
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| physical | 191-196 |
| publishDate | 1980 |
| publishDateSort | 1980 |
| publisher | Wiley |
| record_format | ai |
| recordtype | ai |
| series | Surface and Interface Analysis |
| source_id | 49 |
| spelling | Proctor, A. Sherwood, P. M. A. 0142-2421 1096-9918 Wiley Materials Chemistry Surfaces, Coatings and Films Surfaces and Interfaces Condensed Matter Physics General Chemistry http://dx.doi.org/10.1002/sia.740020508 <jats:title>Abstract</jats:title><jats:p>The paper reports the detection by XPS of a bulk antimony impurity in a gold foil sample, as a result of its surface segregation upon heating <jats:italic>in vacuo</jats:italic> at 600 °C. The O 1s spectra indicate at least two possible oxygen species present in the vicinity of the gold surface. The interaction of the surface segregated antimony with oxygen does not appear to be as is reported for calcium impurities, the antimony showing the binding energy corresponding to metal. Also the amount of surface segregated antimony impurity does not seem to be as dependent as calcium impurities on previously adsorbed or gas‐phase oxygen. The use of the carbon 1s peak rather than the gold 4f peaks is found to be a more reliable calibration reference.</jats:p> An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity Surface and Interface Analysis |
| spellingShingle | Proctor, A., Sherwood, P. M. A., Surface and Interface Analysis, An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity, Materials Chemistry, Surfaces, Coatings and Films, Surfaces and Interfaces, Condensed Matter Physics, General Chemistry |
| title | An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_full | An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_fullStr | An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_full_unstemmed | An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_short | An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_sort | an x‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| title_unstemmed | An X‐ray photoelectron spectroscopic study of gold containing a bulk antimony impurity |
| topic | Materials Chemistry, Surfaces, Coatings and Films, Surfaces and Interfaces, Condensed Matter Physics, General Chemistry |
| url | http://dx.doi.org/10.1002/sia.740020508 |