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Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures
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Zeitschriftentitel: | Propellants, Explosives, Pyrotechnics |
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Personen und Körperschaften: | , |
In: | Propellants, Explosives, Pyrotechnics, 41, 2016, 4, S. 709-712 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Wiley
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Schlagwörter: |
author_facet |
Manh, Tung Nguyen Kim, Kwang‐Joo Manh, Tung Nguyen Kim, Kwang‐Joo |
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author |
Manh, Tung Nguyen Kim, Kwang‐Joo |
spellingShingle |
Manh, Tung Nguyen Kim, Kwang‐Joo Propellants, Explosives, Pyrotechnics Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures General Chemical Engineering General Chemistry |
author_sort |
manh, tung nguyen |
spelling |
Manh, Tung Nguyen Kim, Kwang‐Joo 0721-3115 1521-4087 Wiley General Chemical Engineering General Chemistry http://dx.doi.org/10.1002/prep.201500214 <jats:title>Abstract</jats:title><jats:p>The solubility of N‐guanylurea dinitramide (GUDN, Fox‐12) in binary solvent mixtures was measured. Binary solvents such as dimethyl sulfoxide (DMSO)/water and <jats:italic>N,N</jats:italic>‐dimethylacetamide (DMA)/water were investigated. The temperature was in the range of 0 °C to 70 °C for DMA‐water and 20 °C to 70 °C for DMSO‐water. The temperature dependence on the solubility was higher in DMA‐water than in DMSO‐water at the same fraction of water. On the other hand, the modeling data was obtained by using the Apelblat equation. The average relative errors are less than 3 %. Supersaturation for crystallization of GUDN in solution can be easily generated by adding water in DMSO (or DMA).</jats:p> Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures Propellants, Explosives, Pyrotechnics |
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title |
Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_unstemmed |
Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_full |
Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_fullStr |
Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_full_unstemmed |
Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_short |
Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_sort |
solubility of n‐guanylurea dinitramide in binary solvent mixtures |
topic |
General Chemical Engineering General Chemistry |
url |
http://dx.doi.org/10.1002/prep.201500214 |
publishDate |
2016 |
physical |
709-712 |
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<jats:title>Abstract</jats:title><jats:p>The solubility of N‐guanylurea dinitramide (GUDN, Fox‐12) in binary solvent mixtures was measured. Binary solvents such as dimethyl sulfoxide (DMSO)/water and <jats:italic>N,N</jats:italic>‐dimethylacetamide (DMA)/water were investigated. The temperature was in the range of 0 °C to 70 °C for DMA‐water and 20 °C to 70 °C for DMSO‐water. The temperature dependence on the solubility was higher in DMA‐water than in DMSO‐water at the same fraction of water. On the other hand, the modeling data was obtained by using the Apelblat equation. The average relative errors are less than 3 %. Supersaturation for crystallization of GUDN in solution can be easily generated by adding water in DMSO (or DMA).</jats:p> |
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author | Manh, Tung Nguyen, Kim, Kwang‐Joo |
author_facet | Manh, Tung Nguyen, Kim, Kwang‐Joo, Manh, Tung Nguyen, Kim, Kwang‐Joo |
author_sort | manh, tung nguyen |
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container_start_page | 709 |
container_title | Propellants, Explosives, Pyrotechnics |
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description | <jats:title>Abstract</jats:title><jats:p>The solubility of N‐guanylurea dinitramide (GUDN, Fox‐12) in binary solvent mixtures was measured. Binary solvents such as dimethyl sulfoxide (DMSO)/water and <jats:italic>N,N</jats:italic>‐dimethylacetamide (DMA)/water were investigated. The temperature was in the range of 0 °C to 70 °C for DMA‐water and 20 °C to 70 °C for DMSO‐water. The temperature dependence on the solubility was higher in DMA‐water than in DMSO‐water at the same fraction of water. On the other hand, the modeling data was obtained by using the Apelblat equation. The average relative errors are less than 3 %. Supersaturation for crystallization of GUDN in solution can be easily generated by adding water in DMSO (or DMA).</jats:p> |
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source_id | 49 |
spelling | Manh, Tung Nguyen Kim, Kwang‐Joo 0721-3115 1521-4087 Wiley General Chemical Engineering General Chemistry http://dx.doi.org/10.1002/prep.201500214 <jats:title>Abstract</jats:title><jats:p>The solubility of N‐guanylurea dinitramide (GUDN, Fox‐12) in binary solvent mixtures was measured. Binary solvents such as dimethyl sulfoxide (DMSO)/water and <jats:italic>N,N</jats:italic>‐dimethylacetamide (DMA)/water were investigated. The temperature was in the range of 0 °C to 70 °C for DMA‐water and 20 °C to 70 °C for DMSO‐water. The temperature dependence on the solubility was higher in DMA‐water than in DMSO‐water at the same fraction of water. On the other hand, the modeling data was obtained by using the Apelblat equation. The average relative errors are less than 3 %. Supersaturation for crystallization of GUDN in solution can be easily generated by adding water in DMSO (or DMA).</jats:p> Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures Propellants, Explosives, Pyrotechnics |
spellingShingle | Manh, Tung Nguyen, Kim, Kwang‐Joo, Propellants, Explosives, Pyrotechnics, Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures, General Chemical Engineering, General Chemistry |
title | Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_full | Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_fullStr | Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_full_unstemmed | Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_short | Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
title_sort | solubility of n‐guanylurea dinitramide in binary solvent mixtures |
title_unstemmed | Solubility of N‐Guanylurea Dinitramide in Binary Solvent Mixtures |
topic | General Chemical Engineering, General Chemistry |
url | http://dx.doi.org/10.1002/prep.201500214 |