Eintrag weiter verarbeiten
Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups
Gespeichert in:
Zeitschriftentitel: | Journal of Polymer Science Part A: Polymer Chemistry |
---|---|
Personen und Körperschaften: | , , , |
In: | Journal of Polymer Science Part A: Polymer Chemistry, 48, 2010, 3, S. 719-729 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Wiley
|
Schlagwörter: |
author_facet |
Cerrada, M. L. Sánchez‐chaves, M. Ruiz, C. Fernández‐García, M. Cerrada, M. L. Sánchez‐chaves, M. Ruiz, C. Fernández‐García, M. |
---|---|
author |
Cerrada, M. L. Sánchez‐chaves, M. Ruiz, C. Fernández‐García, M. |
spellingShingle |
Cerrada, M. L. Sánchez‐chaves, M. Ruiz, C. Fernández‐García, M. Journal of Polymer Science Part A: Polymer Chemistry Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups Materials Chemistry Organic Chemistry Polymers and Plastics |
author_sort |
cerrada, m. l. |
spelling |
Cerrada, M. L. Sánchez‐chaves, M. Ruiz, C. Fernández‐García, M. 0887-624X 1099-0518 Wiley Materials Chemistry Organic Chemistry Polymers and Plastics http://dx.doi.org/10.1002/pola.23837 <jats:title>Abstract</jats:title><jats:p>Glycopolymers based on the incorporation of a diaminobutylmaltotrionolactone onto activated ethylene‐vinyl alcohol, EVOH, copolymers with distinct composition in the former counit have been prepared. Previous transformation of initial hydroxyl EVOH groups to other more reactive functional groups has been required. The activation has been performed in this current investigation by functionalization with either 4‐nitrophenyl carbonate or <jats:italic>o</jats:italic>‐phthalic acid groups. The structure of the resulting novel water‐soluble glycopolymers has been confirmed by FTIR, <jats:sup>1</jats:sup>H and <jats:sup>13</jats:sup>C‐NMR spectroscopies. In addition, the glass transition temperatures and thermal stability as well as the viscoelastic behavior in bulk and in water solution have been examined as a function of chemical linkage nature. The rheological evaluation confirms the reversible gel formation in all the cases. Finally, their affinity to Concanavalin A lectin has been also analyzed proving the feasible use of these glycopolymers as molecular recognition materials. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 719–729, 2010</jats:p> Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups Journal of Polymer Science Part A: Polymer Chemistry |
doi_str_mv |
10.1002/pola.23837 |
facet_avail |
Online |
finc_class_facet |
Chemie und Pharmazie |
format |
ElectronicArticle |
fullrecord |
blob:ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wb2xhLjIzODM3 |
id |
ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wb2xhLjIzODM3 |
institution |
DE-D275 DE-Bn3 DE-Brt1 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Rs1 DE-Pl11 DE-105 DE-14 DE-Ch1 DE-L229 |
imprint |
Wiley, 2010 |
imprint_str_mv |
Wiley, 2010 |
issn |
0887-624X 1099-0518 |
issn_str_mv |
0887-624X 1099-0518 |
language |
English |
mega_collection |
Wiley (CrossRef) |
match_str |
cerrada2010specificlectininteractionsandtemperatureinducedreversiblegelsinnovelwatersolubleglycopolymersbearingmaltotrionolactonependantgroups |
publishDateSort |
2010 |
publisher |
Wiley |
recordtype |
ai |
record_format |
ai |
series |
Journal of Polymer Science Part A: Polymer Chemistry |
source_id |
49 |
title |
Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_unstemmed |
Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_full |
Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_fullStr |
Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_full_unstemmed |
Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_short |
Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_sort |
specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
topic |
Materials Chemistry Organic Chemistry Polymers and Plastics |
url |
http://dx.doi.org/10.1002/pola.23837 |
publishDate |
2010 |
physical |
719-729 |
description |
<jats:title>Abstract</jats:title><jats:p>Glycopolymers based on the incorporation of a diaminobutylmaltotrionolactone onto activated ethylene‐vinyl alcohol, EVOH, copolymers with distinct composition in the former counit have been prepared. Previous transformation of initial hydroxyl EVOH groups to other more reactive functional groups has been required. The activation has been performed in this current investigation by functionalization with either 4‐nitrophenyl carbonate or <jats:italic>o</jats:italic>‐phthalic acid groups. The structure of the resulting novel water‐soluble glycopolymers has been confirmed by FTIR, <jats:sup>1</jats:sup>H and <jats:sup>13</jats:sup>C‐NMR spectroscopies. In addition, the glass transition temperatures and thermal stability as well as the viscoelastic behavior in bulk and in water solution have been examined as a function of chemical linkage nature. The rheological evaluation confirms the reversible gel formation in all the cases. Finally, their affinity to Concanavalin A lectin has been also analyzed proving the feasible use of these glycopolymers as molecular recognition materials. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 719–729, 2010</jats:p> |
container_issue |
3 |
container_start_page |
719 |
container_title |
Journal of Polymer Science Part A: Polymer Chemistry |
container_volume |
48 |
format_de105 |
Article, E-Article |
format_de14 |
Article, E-Article |
format_de15 |
Article, E-Article |
format_de520 |
Article, E-Article |
format_de540 |
Article, E-Article |
format_dech1 |
Article, E-Article |
format_ded117 |
Article, E-Article |
format_degla1 |
E-Article |
format_del152 |
Buch |
format_del189 |
Article, E-Article |
format_dezi4 |
Article |
format_dezwi2 |
Article, E-Article |
format_finc |
Article, E-Article |
format_nrw |
Article, E-Article |
_version_ |
1792336129966473230 |
geogr_code |
not assigned |
last_indexed |
2024-03-01T14:55:32.613Z |
geogr_code_person |
not assigned |
openURL |
url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Specific+lectin+interactions+and+temperature%E2%80%90induced+reversible+gels+in+novel+water%E2%80%90soluble+glycopolymers+bearing+maltotrionolactone+pendant+groups&rft.date=2010-02-01&genre=article&issn=1099-0518&volume=48&issue=3&spage=719&epage=729&pages=719-729&jtitle=Journal+of+Polymer+Science+Part+A%3A+Polymer+Chemistry&atitle=Specific+lectin+interactions+and+temperature%E2%80%90induced+reversible+gels+in+novel+water%E2%80%90soluble+glycopolymers+bearing+maltotrionolactone+pendant+groups&aulast=Fern%C3%A1ndez%E2%80%90Garc%C3%ADa&aufirst=M.&rft_id=info%3Adoi%2F10.1002%2Fpola.23837&rft.language%5B0%5D=eng |
SOLR | |
_version_ | 1792336129966473230 |
author | Cerrada, M. L., Sánchez‐chaves, M., Ruiz, C., Fernández‐García, M. |
author_facet | Cerrada, M. L., Sánchez‐chaves, M., Ruiz, C., Fernández‐García, M., Cerrada, M. L., Sánchez‐chaves, M., Ruiz, C., Fernández‐García, M. |
author_sort | cerrada, m. l. |
container_issue | 3 |
container_start_page | 719 |
container_title | Journal of Polymer Science Part A: Polymer Chemistry |
container_volume | 48 |
description | <jats:title>Abstract</jats:title><jats:p>Glycopolymers based on the incorporation of a diaminobutylmaltotrionolactone onto activated ethylene‐vinyl alcohol, EVOH, copolymers with distinct composition in the former counit have been prepared. Previous transformation of initial hydroxyl EVOH groups to other more reactive functional groups has been required. The activation has been performed in this current investigation by functionalization with either 4‐nitrophenyl carbonate or <jats:italic>o</jats:italic>‐phthalic acid groups. The structure of the resulting novel water‐soluble glycopolymers has been confirmed by FTIR, <jats:sup>1</jats:sup>H and <jats:sup>13</jats:sup>C‐NMR spectroscopies. In addition, the glass transition temperatures and thermal stability as well as the viscoelastic behavior in bulk and in water solution have been examined as a function of chemical linkage nature. The rheological evaluation confirms the reversible gel formation in all the cases. Finally, their affinity to Concanavalin A lectin has been also analyzed proving the feasible use of these glycopolymers as molecular recognition materials. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 719–729, 2010</jats:p> |
doi_str_mv | 10.1002/pola.23837 |
facet_avail | Online |
finc_class_facet | Chemie und Pharmazie |
format | ElectronicArticle |
format_de105 | Article, E-Article |
format_de14 | Article, E-Article |
format_de15 | Article, E-Article |
format_de520 | Article, E-Article |
format_de540 | Article, E-Article |
format_dech1 | Article, E-Article |
format_ded117 | Article, E-Article |
format_degla1 | E-Article |
format_del152 | Buch |
format_del189 | Article, E-Article |
format_dezi4 | Article |
format_dezwi2 | Article, E-Article |
format_finc | Article, E-Article |
format_nrw | Article, E-Article |
geogr_code | not assigned |
geogr_code_person | not assigned |
id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wb2xhLjIzODM3 |
imprint | Wiley, 2010 |
imprint_str_mv | Wiley, 2010 |
institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Rs1, DE-Pl11, DE-105, DE-14, DE-Ch1, DE-L229 |
issn | 0887-624X, 1099-0518 |
issn_str_mv | 0887-624X, 1099-0518 |
language | English |
last_indexed | 2024-03-01T14:55:32.613Z |
match_str | cerrada2010specificlectininteractionsandtemperatureinducedreversiblegelsinnovelwatersolubleglycopolymersbearingmaltotrionolactonependantgroups |
mega_collection | Wiley (CrossRef) |
physical | 719-729 |
publishDate | 2010 |
publishDateSort | 2010 |
publisher | Wiley |
record_format | ai |
recordtype | ai |
series | Journal of Polymer Science Part A: Polymer Chemistry |
source_id | 49 |
spelling | Cerrada, M. L. Sánchez‐chaves, M. Ruiz, C. Fernández‐García, M. 0887-624X 1099-0518 Wiley Materials Chemistry Organic Chemistry Polymers and Plastics http://dx.doi.org/10.1002/pola.23837 <jats:title>Abstract</jats:title><jats:p>Glycopolymers based on the incorporation of a diaminobutylmaltotrionolactone onto activated ethylene‐vinyl alcohol, EVOH, copolymers with distinct composition in the former counit have been prepared. Previous transformation of initial hydroxyl EVOH groups to other more reactive functional groups has been required. The activation has been performed in this current investigation by functionalization with either 4‐nitrophenyl carbonate or <jats:italic>o</jats:italic>‐phthalic acid groups. The structure of the resulting novel water‐soluble glycopolymers has been confirmed by FTIR, <jats:sup>1</jats:sup>H and <jats:sup>13</jats:sup>C‐NMR spectroscopies. In addition, the glass transition temperatures and thermal stability as well as the viscoelastic behavior in bulk and in water solution have been examined as a function of chemical linkage nature. The rheological evaluation confirms the reversible gel formation in all the cases. Finally, their affinity to Concanavalin A lectin has been also analyzed proving the feasible use of these glycopolymers as molecular recognition materials. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 719–729, 2010</jats:p> Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups Journal of Polymer Science Part A: Polymer Chemistry |
spellingShingle | Cerrada, M. L., Sánchez‐chaves, M., Ruiz, C., Fernández‐García, M., Journal of Polymer Science Part A: Polymer Chemistry, Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups, Materials Chemistry, Organic Chemistry, Polymers and Plastics |
title | Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_full | Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_fullStr | Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_full_unstemmed | Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_short | Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_sort | specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
title_unstemmed | Specific lectin interactions and temperature‐induced reversible gels in novel water‐soluble glycopolymers bearing maltotrionolactone pendant groups |
topic | Materials Chemistry, Organic Chemistry, Polymers and Plastics |
url | http://dx.doi.org/10.1002/pola.23837 |