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Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type
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| Zeitschriftentitel: | Journal of Polymer Science Part A: Polymer Chemistry |
|---|---|
| Personen und Körperschaften: | , , , |
| In: | Journal of Polymer Science Part A: Polymer Chemistry, 26, 1988, 1, S. 255-265 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Bizzarri, P. Costa Casa, C. Della Fiorini, M. Porzio, W. Bizzarri, P. Costa Casa, C. Della Fiorini, M. Porzio, W. |
|---|---|
| author |
Bizzarri, P. Costa Casa, C. Della Fiorini, M. Porzio, W. |
| spellingShingle |
Bizzarri, P. Costa Casa, C. Della Fiorini, M. Porzio, W. Journal of Polymer Science Part A: Polymer Chemistry Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type Materials Chemistry Organic Chemistry Polymers and Plastics |
| author_sort |
bizzarri, p. costa |
| spelling |
Bizzarri, P. Costa Casa, C. Della Fiorini, M. Porzio, W. 0887-624X 1099-0518 Wiley Materials Chemistry Organic Chemistry Polymers and Plastics http://dx.doi.org/10.1002/pola.1988.080260125 <jats:title>Abstract</jats:title><jats:p>Oligomers containing thianthrene units in the chain are synthesized by AlCl<jats:sub>3</jats:sub>‐catalyzed reaction of diphenylsulfide, thianthrene, poly(<jats:italic>p</jats:italic>‐phenylene sulfide), and poly(<jats:italic>m</jats:italic>‐phenylene disulfide) with sulfur at 80°C. The products are compared with that obtained by the reaction of diphenylsulfide with AlCl<jats:sub>3</jats:sub> at 225°C. IR spectra and elemental analyses are consistent with cyclic chain structures and show a higher cyclization for CHCl<jats:sub>3</jats:sub>‐insoluble fractions. X‐ray diffraction analysis indicates the same structure for the samples obtained with the different methods of synthesis. A possible structural model is tentatively proposed.</jats:p> Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type Journal of Polymer Science Part A: Polymer Chemistry |
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Journal of Polymer Science Part A: Polymer Chemistry |
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| title |
Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_unstemmed |
Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_full |
Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_fullStr |
Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_full_unstemmed |
Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_short |
Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_sort |
synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| topic |
Materials Chemistry Organic Chemistry Polymers and Plastics |
| url |
http://dx.doi.org/10.1002/pola.1988.080260125 |
| publishDate |
1988 |
| physical |
255-265 |
| description |
<jats:title>Abstract</jats:title><jats:p>Oligomers containing thianthrene units in the chain are synthesized by AlCl<jats:sub>3</jats:sub>‐catalyzed reaction of diphenylsulfide, thianthrene, poly(<jats:italic>p</jats:italic>‐phenylene sulfide), and poly(<jats:italic>m</jats:italic>‐phenylene disulfide) with sulfur at 80°C. The products are compared with that obtained by the reaction of diphenylsulfide with AlCl<jats:sub>3</jats:sub> at 225°C. IR spectra and elemental analyses are consistent with cyclic chain structures and show a higher cyclization for CHCl<jats:sub>3</jats:sub>‐insoluble fractions. X‐ray diffraction analysis indicates the same structure for the samples obtained with the different methods of synthesis. A possible structural model is tentatively proposed.</jats:p> |
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| author | Bizzarri, P. Costa, Casa, C. Della, Fiorini, M., Porzio, W. |
| author_facet | Bizzarri, P. Costa, Casa, C. Della, Fiorini, M., Porzio, W., Bizzarri, P. Costa, Casa, C. Della, Fiorini, M., Porzio, W. |
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| description | <jats:title>Abstract</jats:title><jats:p>Oligomers containing thianthrene units in the chain are synthesized by AlCl<jats:sub>3</jats:sub>‐catalyzed reaction of diphenylsulfide, thianthrene, poly(<jats:italic>p</jats:italic>‐phenylene sulfide), and poly(<jats:italic>m</jats:italic>‐phenylene disulfide) with sulfur at 80°C. The products are compared with that obtained by the reaction of diphenylsulfide with AlCl<jats:sub>3</jats:sub> at 225°C. IR spectra and elemental analyses are consistent with cyclic chain structures and show a higher cyclization for CHCl<jats:sub>3</jats:sub>‐insoluble fractions. X‐ray diffraction analysis indicates the same structure for the samples obtained with the different methods of synthesis. A possible structural model is tentatively proposed.</jats:p> |
| doi_str_mv | 10.1002/pola.1988.080260125 |
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| format_del189 | Article, E-Article |
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| format_dezwi2 | Article, E-Article |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wb2xhLjE5ODguMDgwMjYwMTI1 |
| imprint | Wiley, 1988 |
| imprint_str_mv | Wiley, 1988 |
| institution | DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4 |
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| physical | 255-265 |
| publishDate | 1988 |
| publishDateSort | 1988 |
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| series | Journal of Polymer Science Part A: Polymer Chemistry |
| source_id | 49 |
| spelling | Bizzarri, P. Costa Casa, C. Della Fiorini, M. Porzio, W. 0887-624X 1099-0518 Wiley Materials Chemistry Organic Chemistry Polymers and Plastics http://dx.doi.org/10.1002/pola.1988.080260125 <jats:title>Abstract</jats:title><jats:p>Oligomers containing thianthrene units in the chain are synthesized by AlCl<jats:sub>3</jats:sub>‐catalyzed reaction of diphenylsulfide, thianthrene, poly(<jats:italic>p</jats:italic>‐phenylene sulfide), and poly(<jats:italic>m</jats:italic>‐phenylene disulfide) with sulfur at 80°C. The products are compared with that obtained by the reaction of diphenylsulfide with AlCl<jats:sub>3</jats:sub> at 225°C. IR spectra and elemental analyses are consistent with cyclic chain structures and show a higher cyclization for CHCl<jats:sub>3</jats:sub>‐insoluble fractions. X‐ray diffraction analysis indicates the same structure for the samples obtained with the different methods of synthesis. A possible structural model is tentatively proposed.</jats:p> Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type Journal of Polymer Science Part A: Polymer Chemistry |
| spellingShingle | Bizzarri, P. Costa, Casa, C. Della, Fiorini, M., Porzio, W., Journal of Polymer Science Part A: Polymer Chemistry, Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type, Materials Chemistry, Organic Chemistry, Polymers and Plastics |
| title | Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_full | Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_fullStr | Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_full_unstemmed | Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_short | Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_sort | synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| title_unstemmed | Synthesis of intramolecularly cyclized poly(phenylene sulfide)s of the thianthrene‐type |
| topic | Materials Chemistry, Organic Chemistry, Polymers and Plastics |
| url | http://dx.doi.org/10.1002/pola.1988.080260125 |