Eintrag weiter verarbeiten
Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems
Gespeichert in:
| Zeitschriftentitel: | Polymer Engineering & Science |
|---|---|
| Personen und Körperschaften: | , , , |
| In: | Polymer Engineering & Science, 48, 2008, 10, S. 1931-1938 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Vrsaljko, Domagoj Leskovac, Mirela Blagojević, Sanja Lučić Kovačević, Vera Vrsaljko, Domagoj Leskovac, Mirela Blagojević, Sanja Lučić Kovačević, Vera |
|---|---|
| author |
Vrsaljko, Domagoj Leskovac, Mirela Blagojević, Sanja Lučić Kovačević, Vera |
| spellingShingle |
Vrsaljko, Domagoj Leskovac, Mirela Blagojević, Sanja Lučić Kovačević, Vera Polymer Engineering & Science Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry |
| author_sort |
vrsaljko, domagoj |
| spelling |
Vrsaljko, Domagoj Leskovac, Mirela Blagojević, Sanja Lučić Kovačević, Vera 0032-3888 1548-2634 Wiley Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry http://dx.doi.org/10.1002/pen.21055 <jats:title>Abstract</jats:title><jats:p>Polyurethane (PU) and poly(vinyl acetate) (PVAc) are partially miscible polymers. The aim of this study was to investigate the influence of untreated and surface pretreated calcium carbonate (CaCO<jats:sub>3</jats:sub>) on the interphase properties of PU/PVAc polymer blends with possible compatibilization effects when the conditions of effective adhesion are achieved. With the aim to modify interface between filler and matrices, CaCO<jats:sub>3</jats:sub> was pretreated by grafting PVAc on the filler surface using <jats:sup>60</jats:sup>Co γ‐ray irradiation polymerization of vinyl acetate. A series of the PU/PVAc blends without and with the addition of CaCO<jats:sub>3</jats:sub> were prepared using a Brabender plasticorder at 140°C. Surface characterization of the PU and PVAc polymers as well as the untreated and surface pretreated CaCO<jats:sub>3</jats:sub> fillers was carried out by determination of the surface free energy. The adhesion between CaCO<jats:sub>3</jats:sub> and phases in the polymer blends was predicted on the basis of the calculated adhesion parameters (interfacial free energy, spreading coefficient and work of adhesion) obtained from the surface free energy of components. Thermal and mechanical properties were investigated by tensile strength measurements and differential scanning calorimetry (DSC). The adhesion parameters were correlated with the mechanical and thermal properties as well as phase morphology observations. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers</jats:p> Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems Polymer Engineering & Science |
| doi_str_mv |
10.1002/pen.21055 |
| facet_avail |
Online |
| finc_class_facet |
Chemie und Pharmazie |
| format |
ElectronicArticle |
| fullrecord |
blob:ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wZW4uMjEwNTU |
| id |
ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wZW4uMjEwNTU |
| institution |
DE-D275 DE-Bn3 DE-Brt1 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 |
| imprint |
Wiley, 2008 |
| imprint_str_mv |
Wiley, 2008 |
| issn |
0032-3888 1548-2634 |
| issn_str_mv |
0032-3888 1548-2634 |
| language |
English |
| mega_collection |
Wiley (CrossRef) |
| match_str |
vrsaljko2008interphasephenomenainnanoparticulatefilledpolyurethanepolyvinylacetatepolymersystems |
| publishDateSort |
2008 |
| publisher |
Wiley |
| recordtype |
ai |
| record_format |
ai |
| series |
Polymer Engineering & Science |
| source_id |
49 |
| title |
Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_unstemmed |
Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_full |
Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_fullStr |
Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_full_unstemmed |
Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_short |
Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_sort |
interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| topic |
Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry |
| url |
http://dx.doi.org/10.1002/pen.21055 |
| publishDate |
2008 |
| physical |
1931-1938 |
| description |
<jats:title>Abstract</jats:title><jats:p>Polyurethane (PU) and poly(vinyl acetate) (PVAc) are partially miscible polymers. The aim of this study was to investigate the influence of untreated and surface pretreated calcium carbonate (CaCO<jats:sub>3</jats:sub>) on the interphase properties of PU/PVAc polymer blends with possible compatibilization effects when the conditions of effective adhesion are achieved. With the aim to modify interface between filler and matrices, CaCO<jats:sub>3</jats:sub> was pretreated by grafting PVAc on the filler surface using <jats:sup>60</jats:sup>Co γ‐ray irradiation polymerization of vinyl acetate. A series of the PU/PVAc blends without and with the addition of CaCO<jats:sub>3</jats:sub> were prepared using a Brabender plasticorder at 140°C. Surface characterization of the PU and PVAc polymers as well as the untreated and surface pretreated CaCO<jats:sub>3</jats:sub> fillers was carried out by determination of the surface free energy. The adhesion between CaCO<jats:sub>3</jats:sub> and phases in the polymer blends was predicted on the basis of the calculated adhesion parameters (interfacial free energy, spreading coefficient and work of adhesion) obtained from the surface free energy of components. Thermal and mechanical properties were investigated by tensile strength measurements and differential scanning calorimetry (DSC). The adhesion parameters were correlated with the mechanical and thermal properties as well as phase morphology observations. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers</jats:p> |
| container_issue |
10 |
| container_start_page |
1931 |
| container_title |
Polymer Engineering & Science |
| container_volume |
48 |
| format_de105 |
Article, E-Article |
| format_de14 |
Article, E-Article |
| format_de15 |
Article, E-Article |
| format_de520 |
Article, E-Article |
| format_de540 |
Article, E-Article |
| format_dech1 |
Article, E-Article |
| format_ded117 |
Article, E-Article |
| format_degla1 |
E-Article |
| format_del152 |
Buch |
| format_del189 |
Article, E-Article |
| format_dezi4 |
Article |
| format_dezwi2 |
Article, E-Article |
| format_finc |
Article, E-Article |
| format_nrw |
Article, E-Article |
| _version_ |
1792335457155022859 |
| geogr_code |
not assigned |
| last_indexed |
2024-03-01T14:44:51.312Z |
| geogr_code_person |
not assigned |
| openURL |
url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Interphase+phenomena+in+nanoparticulate+filled+polyurethane%2Fpoly%28vinyl+acetate%29+polymer+systems&rft.date=2008-10-01&genre=article&issn=1548-2634&volume=48&issue=10&spage=1931&epage=1938&pages=1931-1938&jtitle=Polymer+Engineering+%26+Science&atitle=Interphase+phenomena+in+nanoparticulate+filled+polyurethane%2Fpoly%28vinyl+acetate%29+polymer+systems&aulast=Kova%C4%8Devi%C4%87&aufirst=Vera&rft_id=info%3Adoi%2F10.1002%2Fpen.21055&rft.language%5B0%5D=eng |
| SOLR | |
| _version_ | 1792335457155022859 |
| author | Vrsaljko, Domagoj, Leskovac, Mirela, Blagojević, Sanja Lučić, Kovačević, Vera |
| author_facet | Vrsaljko, Domagoj, Leskovac, Mirela, Blagojević, Sanja Lučić, Kovačević, Vera, Vrsaljko, Domagoj, Leskovac, Mirela, Blagojević, Sanja Lučić, Kovačević, Vera |
| author_sort | vrsaljko, domagoj |
| container_issue | 10 |
| container_start_page | 1931 |
| container_title | Polymer Engineering & Science |
| container_volume | 48 |
| description | <jats:title>Abstract</jats:title><jats:p>Polyurethane (PU) and poly(vinyl acetate) (PVAc) are partially miscible polymers. The aim of this study was to investigate the influence of untreated and surface pretreated calcium carbonate (CaCO<jats:sub>3</jats:sub>) on the interphase properties of PU/PVAc polymer blends with possible compatibilization effects when the conditions of effective adhesion are achieved. With the aim to modify interface between filler and matrices, CaCO<jats:sub>3</jats:sub> was pretreated by grafting PVAc on the filler surface using <jats:sup>60</jats:sup>Co γ‐ray irradiation polymerization of vinyl acetate. A series of the PU/PVAc blends without and with the addition of CaCO<jats:sub>3</jats:sub> were prepared using a Brabender plasticorder at 140°C. Surface characterization of the PU and PVAc polymers as well as the untreated and surface pretreated CaCO<jats:sub>3</jats:sub> fillers was carried out by determination of the surface free energy. The adhesion between CaCO<jats:sub>3</jats:sub> and phases in the polymer blends was predicted on the basis of the calculated adhesion parameters (interfacial free energy, spreading coefficient and work of adhesion) obtained from the surface free energy of components. Thermal and mechanical properties were investigated by tensile strength measurements and differential scanning calorimetry (DSC). The adhesion parameters were correlated with the mechanical and thermal properties as well as phase morphology observations. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers</jats:p> |
| doi_str_mv | 10.1002/pen.21055 |
| facet_avail | Online |
| finc_class_facet | Chemie und Pharmazie |
| format | ElectronicArticle |
| format_de105 | Article, E-Article |
| format_de14 | Article, E-Article |
| format_de15 | Article, E-Article |
| format_de520 | Article, E-Article |
| format_de540 | Article, E-Article |
| format_dech1 | Article, E-Article |
| format_ded117 | Article, E-Article |
| format_degla1 | E-Article |
| format_del152 | Buch |
| format_del189 | Article, E-Article |
| format_dezi4 | Article |
| format_dezwi2 | Article, E-Article |
| format_finc | Article, E-Article |
| format_nrw | Article, E-Article |
| geogr_code | not assigned |
| geogr_code_person | not assigned |
| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wZW4uMjEwNTU |
| imprint | Wiley, 2008 |
| imprint_str_mv | Wiley, 2008 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
| issn | 0032-3888, 1548-2634 |
| issn_str_mv | 0032-3888, 1548-2634 |
| language | English |
| last_indexed | 2024-03-01T14:44:51.312Z |
| match_str | vrsaljko2008interphasephenomenainnanoparticulatefilledpolyurethanepolyvinylacetatepolymersystems |
| mega_collection | Wiley (CrossRef) |
| physical | 1931-1938 |
| publishDate | 2008 |
| publishDateSort | 2008 |
| publisher | Wiley |
| record_format | ai |
| recordtype | ai |
| series | Polymer Engineering & Science |
| source_id | 49 |
| spelling | Vrsaljko, Domagoj Leskovac, Mirela Blagojević, Sanja Lučić Kovačević, Vera 0032-3888 1548-2634 Wiley Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry http://dx.doi.org/10.1002/pen.21055 <jats:title>Abstract</jats:title><jats:p>Polyurethane (PU) and poly(vinyl acetate) (PVAc) are partially miscible polymers. The aim of this study was to investigate the influence of untreated and surface pretreated calcium carbonate (CaCO<jats:sub>3</jats:sub>) on the interphase properties of PU/PVAc polymer blends with possible compatibilization effects when the conditions of effective adhesion are achieved. With the aim to modify interface between filler and matrices, CaCO<jats:sub>3</jats:sub> was pretreated by grafting PVAc on the filler surface using <jats:sup>60</jats:sup>Co γ‐ray irradiation polymerization of vinyl acetate. A series of the PU/PVAc blends without and with the addition of CaCO<jats:sub>3</jats:sub> were prepared using a Brabender plasticorder at 140°C. Surface characterization of the PU and PVAc polymers as well as the untreated and surface pretreated CaCO<jats:sub>3</jats:sub> fillers was carried out by determination of the surface free energy. The adhesion between CaCO<jats:sub>3</jats:sub> and phases in the polymer blends was predicted on the basis of the calculated adhesion parameters (interfacial free energy, spreading coefficient and work of adhesion) obtained from the surface free energy of components. Thermal and mechanical properties were investigated by tensile strength measurements and differential scanning calorimetry (DSC). The adhesion parameters were correlated with the mechanical and thermal properties as well as phase morphology observations. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers</jats:p> Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems Polymer Engineering & Science |
| spellingShingle | Vrsaljko, Domagoj, Leskovac, Mirela, Blagojević, Sanja Lučić, Kovačević, Vera, Polymer Engineering & Science, Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems, Materials Chemistry, Polymers and Plastics, General Chemistry, Materials Chemistry, Polymers and Plastics, General Chemistry |
| title | Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_full | Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_fullStr | Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_full_unstemmed | Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_short | Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_sort | interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| title_unstemmed | Interphase phenomena in nanoparticulate filled polyurethane/poly(vinyl acetate) polymer systems |
| topic | Materials Chemistry, Polymers and Plastics, General Chemistry, Materials Chemistry, Polymers and Plastics, General Chemistry |
| url | http://dx.doi.org/10.1002/pen.21055 |