author_facet Kovacevic, Vera
Lucic, Sanja
Hace, Drago
Glasnovic, Antun
Kovacevic, Vera
Lucic, Sanja
Hace, Drago
Glasnovic, Antun
author Kovacevic, Vera
Lucic, Sanja
Hace, Drago
Glasnovic, Antun
spellingShingle Kovacevic, Vera
Lucic, Sanja
Hace, Drago
Glasnovic, Antun
Polymer Engineering & Science
Rheology and morphology of poly(vinyl acetate) + calcite films
Materials Chemistry
Polymers and Plastics
General Chemistry
Materials Chemistry
Polymers and Plastics
General Chemistry
author_sort kovacevic, vera
spelling Kovacevic, Vera Lucic, Sanja Hace, Drago Glasnovic, Antun 0032-3888 1548-2634 Wiley Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry http://dx.doi.org/10.1002/pen.10507 <jats:title>Abstract</jats:title><jats:p>We have studied mechanical and rheological behavior of poly(vinyl acetate) (PVAC) composites filled with calcite as a function of filler particle geometry, particle size distribution, and active surface area. Detailed morphological characteristic were investigated. Tensile properties of PVAC composites were evaluated in the composition range 5–20 wt% calcite. The elongation at break decreases as consequence of matrix mobility restriction by filer particles. By contrast, the strength at break increases as a result of fewer stress concentration points produced by small calcite particles. Large calcite particles decrease the strength of the PVAC composite because of lack of structural continuity. Failure is then dominated by the dewetting. Understanding the deformation as it relates to structure, mechanism of failure, and strength of interactions makes development of improved PVAC composites for adhesives possible.</jats:p> Rheology and morphology of poly(vinyl acetate) + calcite films Polymer Engineering & Science
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imprint Wiley, 1996
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series Polymer Engineering & Science
source_id 49
title Rheology and morphology of poly(vinyl acetate) + calcite films
title_unstemmed Rheology and morphology of poly(vinyl acetate) + calcite films
title_full Rheology and morphology of poly(vinyl acetate) + calcite films
title_fullStr Rheology and morphology of poly(vinyl acetate) + calcite films
title_full_unstemmed Rheology and morphology of poly(vinyl acetate) + calcite films
title_short Rheology and morphology of poly(vinyl acetate) + calcite films
title_sort rheology and morphology of poly(vinyl acetate) + calcite films
topic Materials Chemistry
Polymers and Plastics
General Chemistry
Materials Chemistry
Polymers and Plastics
General Chemistry
url http://dx.doi.org/10.1002/pen.10507
publishDate 1996
physical 1134-1139
description <jats:title>Abstract</jats:title><jats:p>We have studied mechanical and rheological behavior of poly(vinyl acetate) (PVAC) composites filled with calcite as a function of filler particle geometry, particle size distribution, and active surface area. Detailed morphological characteristic were investigated. Tensile properties of PVAC composites were evaluated in the composition range 5–20 wt% calcite. The elongation at break decreases as consequence of matrix mobility restriction by filer particles. By contrast, the strength at break increases as a result of fewer stress concentration points produced by small calcite particles. Large calcite particles decrease the strength of the PVAC composite because of lack of structural continuity. Failure is then dominated by the dewetting. Understanding the deformation as it relates to structure, mechanism of failure, and strength of interactions makes development of improved PVAC composites for adhesives possible.</jats:p>
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author Kovacevic, Vera, Lucic, Sanja, Hace, Drago, Glasnovic, Antun
author_facet Kovacevic, Vera, Lucic, Sanja, Hace, Drago, Glasnovic, Antun, Kovacevic, Vera, Lucic, Sanja, Hace, Drago, Glasnovic, Antun
author_sort kovacevic, vera
container_issue 8
container_start_page 1134
container_title Polymer Engineering & Science
container_volume 36
description <jats:title>Abstract</jats:title><jats:p>We have studied mechanical and rheological behavior of poly(vinyl acetate) (PVAC) composites filled with calcite as a function of filler particle geometry, particle size distribution, and active surface area. Detailed morphological characteristic were investigated. Tensile properties of PVAC composites were evaluated in the composition range 5–20 wt% calcite. The elongation at break decreases as consequence of matrix mobility restriction by filer particles. By contrast, the strength at break increases as a result of fewer stress concentration points produced by small calcite particles. Large calcite particles decrease the strength of the PVAC composite because of lack of structural continuity. Failure is then dominated by the dewetting. Understanding the deformation as it relates to structure, mechanism of failure, and strength of interactions makes development of improved PVAC composites for adhesives possible.</jats:p>
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id ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wZW4uMTA1MDc
imprint Wiley, 1996
imprint_str_mv Wiley, 1996
institution DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1
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physical 1134-1139
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publisher Wiley
record_format ai
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series Polymer Engineering & Science
source_id 49
spelling Kovacevic, Vera Lucic, Sanja Hace, Drago Glasnovic, Antun 0032-3888 1548-2634 Wiley Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry http://dx.doi.org/10.1002/pen.10507 <jats:title>Abstract</jats:title><jats:p>We have studied mechanical and rheological behavior of poly(vinyl acetate) (PVAC) composites filled with calcite as a function of filler particle geometry, particle size distribution, and active surface area. Detailed morphological characteristic were investigated. Tensile properties of PVAC composites were evaluated in the composition range 5–20 wt% calcite. The elongation at break decreases as consequence of matrix mobility restriction by filer particles. By contrast, the strength at break increases as a result of fewer stress concentration points produced by small calcite particles. Large calcite particles decrease the strength of the PVAC composite because of lack of structural continuity. Failure is then dominated by the dewetting. Understanding the deformation as it relates to structure, mechanism of failure, and strength of interactions makes development of improved PVAC composites for adhesives possible.</jats:p> Rheology and morphology of poly(vinyl acetate) + calcite films Polymer Engineering & Science
spellingShingle Kovacevic, Vera, Lucic, Sanja, Hace, Drago, Glasnovic, Antun, Polymer Engineering & Science, Rheology and morphology of poly(vinyl acetate) + calcite films, Materials Chemistry, Polymers and Plastics, General Chemistry, Materials Chemistry, Polymers and Plastics, General Chemistry
title Rheology and morphology of poly(vinyl acetate) + calcite films
title_full Rheology and morphology of poly(vinyl acetate) + calcite films
title_fullStr Rheology and morphology of poly(vinyl acetate) + calcite films
title_full_unstemmed Rheology and morphology of poly(vinyl acetate) + calcite films
title_short Rheology and morphology of poly(vinyl acetate) + calcite films
title_sort rheology and morphology of poly(vinyl acetate) + calcite films
title_unstemmed Rheology and morphology of poly(vinyl acetate) + calcite films
topic Materials Chemistry, Polymers and Plastics, General Chemistry, Materials Chemistry, Polymers and Plastics, General Chemistry
url http://dx.doi.org/10.1002/pen.10507