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Rheology and morphology of poly(vinyl acetate) + calcite films
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Zeitschriftentitel: | Polymer Engineering & Science |
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Personen und Körperschaften: | , , , |
In: | Polymer Engineering & Science, 36, 1996, 8, S. 1134-1139 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Wiley
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Schlagwörter: |
author_facet |
Kovacevic, Vera Lucic, Sanja Hace, Drago Glasnovic, Antun Kovacevic, Vera Lucic, Sanja Hace, Drago Glasnovic, Antun |
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author |
Kovacevic, Vera Lucic, Sanja Hace, Drago Glasnovic, Antun |
spellingShingle |
Kovacevic, Vera Lucic, Sanja Hace, Drago Glasnovic, Antun Polymer Engineering & Science Rheology and morphology of poly(vinyl acetate) + calcite films Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry |
author_sort |
kovacevic, vera |
spelling |
Kovacevic, Vera Lucic, Sanja Hace, Drago Glasnovic, Antun 0032-3888 1548-2634 Wiley Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry http://dx.doi.org/10.1002/pen.10507 <jats:title>Abstract</jats:title><jats:p>We have studied mechanical and rheological behavior of poly(vinyl acetate) (PVAC) composites filled with calcite as a function of filler particle geometry, particle size distribution, and active surface area. Detailed morphological characteristic were investigated. Tensile properties of PVAC composites were evaluated in the composition range 5–20 wt% calcite. The elongation at break decreases as consequence of matrix mobility restriction by filer particles. By contrast, the strength at break increases as a result of fewer stress concentration points produced by small calcite particles. Large calcite particles decrease the strength of the PVAC composite because of lack of structural continuity. Failure is then dominated by the dewetting. Understanding the deformation as it relates to structure, mechanism of failure, and strength of interactions makes development of improved PVAC composites for adhesives possible.</jats:p> Rheology and morphology of poly(vinyl acetate) + calcite films Polymer Engineering & Science |
doi_str_mv |
10.1002/pen.10507 |
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Online |
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Chemie und Pharmazie |
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DE-105 DE-14 DE-Ch1 DE-L229 DE-D275 DE-Bn3 DE-Brt1 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 |
imprint |
Wiley, 1996 |
imprint_str_mv |
Wiley, 1996 |
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0032-3888 1548-2634 |
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0032-3888 1548-2634 |
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English |
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1996 |
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Wiley |
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Polymer Engineering & Science |
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49 |
title |
Rheology and morphology of poly(vinyl acetate) + calcite films |
title_unstemmed |
Rheology and morphology of poly(vinyl acetate) + calcite films |
title_full |
Rheology and morphology of poly(vinyl acetate) + calcite films |
title_fullStr |
Rheology and morphology of poly(vinyl acetate) + calcite films |
title_full_unstemmed |
Rheology and morphology of poly(vinyl acetate) + calcite films |
title_short |
Rheology and morphology of poly(vinyl acetate) + calcite films |
title_sort |
rheology and morphology of poly(vinyl acetate) + calcite films |
topic |
Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry |
url |
http://dx.doi.org/10.1002/pen.10507 |
publishDate |
1996 |
physical |
1134-1139 |
description |
<jats:title>Abstract</jats:title><jats:p>We have studied mechanical and rheological behavior of poly(vinyl acetate) (PVAC) composites filled with calcite as a function of filler particle geometry, particle size distribution, and active surface area. Detailed morphological characteristic were investigated. Tensile properties of PVAC composites were evaluated in the composition range 5–20 wt% calcite. The elongation at break decreases as consequence of matrix mobility restriction by filer particles. By contrast, the strength at break increases as a result of fewer stress concentration points produced by small calcite particles. Large calcite particles decrease the strength of the PVAC composite because of lack of structural continuity. Failure is then dominated by the dewetting. Understanding the deformation as it relates to structure, mechanism of failure, and strength of interactions makes development of improved PVAC composites for adhesives possible.</jats:p> |
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author | Kovacevic, Vera, Lucic, Sanja, Hace, Drago, Glasnovic, Antun |
author_facet | Kovacevic, Vera, Lucic, Sanja, Hace, Drago, Glasnovic, Antun, Kovacevic, Vera, Lucic, Sanja, Hace, Drago, Glasnovic, Antun |
author_sort | kovacevic, vera |
container_issue | 8 |
container_start_page | 1134 |
container_title | Polymer Engineering & Science |
container_volume | 36 |
description | <jats:title>Abstract</jats:title><jats:p>We have studied mechanical and rheological behavior of poly(vinyl acetate) (PVAC) composites filled with calcite as a function of filler particle geometry, particle size distribution, and active surface area. Detailed morphological characteristic were investigated. Tensile properties of PVAC composites were evaluated in the composition range 5–20 wt% calcite. The elongation at break decreases as consequence of matrix mobility restriction by filer particles. By contrast, the strength at break increases as a result of fewer stress concentration points produced by small calcite particles. Large calcite particles decrease the strength of the PVAC composite because of lack of structural continuity. Failure is then dominated by the dewetting. Understanding the deformation as it relates to structure, mechanism of failure, and strength of interactions makes development of improved PVAC composites for adhesives possible.</jats:p> |
doi_str_mv | 10.1002/pen.10507 |
facet_avail | Online |
finc_class_facet | Chemie und Pharmazie |
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id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9wZW4uMTA1MDc |
imprint | Wiley, 1996 |
imprint_str_mv | Wiley, 1996 |
institution | DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1 |
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language | English |
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match_str | kovacevic1996rheologyandmorphologyofpolyvinylacetatecalcitefilms |
mega_collection | Wiley (CrossRef) |
physical | 1134-1139 |
publishDate | 1996 |
publishDateSort | 1996 |
publisher | Wiley |
record_format | ai |
recordtype | ai |
series | Polymer Engineering & Science |
source_id | 49 |
spelling | Kovacevic, Vera Lucic, Sanja Hace, Drago Glasnovic, Antun 0032-3888 1548-2634 Wiley Materials Chemistry Polymers and Plastics General Chemistry Materials Chemistry Polymers and Plastics General Chemistry http://dx.doi.org/10.1002/pen.10507 <jats:title>Abstract</jats:title><jats:p>We have studied mechanical and rheological behavior of poly(vinyl acetate) (PVAC) composites filled with calcite as a function of filler particle geometry, particle size distribution, and active surface area. Detailed morphological characteristic were investigated. Tensile properties of PVAC composites were evaluated in the composition range 5–20 wt% calcite. The elongation at break decreases as consequence of matrix mobility restriction by filer particles. By contrast, the strength at break increases as a result of fewer stress concentration points produced by small calcite particles. Large calcite particles decrease the strength of the PVAC composite because of lack of structural continuity. Failure is then dominated by the dewetting. Understanding the deformation as it relates to structure, mechanism of failure, and strength of interactions makes development of improved PVAC composites for adhesives possible.</jats:p> Rheology and morphology of poly(vinyl acetate) + calcite films Polymer Engineering & Science |
spellingShingle | Kovacevic, Vera, Lucic, Sanja, Hace, Drago, Glasnovic, Antun, Polymer Engineering & Science, Rheology and morphology of poly(vinyl acetate) + calcite films, Materials Chemistry, Polymers and Plastics, General Chemistry, Materials Chemistry, Polymers and Plastics, General Chemistry |
title | Rheology and morphology of poly(vinyl acetate) + calcite films |
title_full | Rheology and morphology of poly(vinyl acetate) + calcite films |
title_fullStr | Rheology and morphology of poly(vinyl acetate) + calcite films |
title_full_unstemmed | Rheology and morphology of poly(vinyl acetate) + calcite films |
title_short | Rheology and morphology of poly(vinyl acetate) + calcite films |
title_sort | rheology and morphology of poly(vinyl acetate) + calcite films |
title_unstemmed | Rheology and morphology of poly(vinyl acetate) + calcite films |
topic | Materials Chemistry, Polymers and Plastics, General Chemistry, Materials Chemistry, Polymers and Plastics, General Chemistry |
url | http://dx.doi.org/10.1002/pen.10507 |