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Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy
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| Zeitschriftentitel: | ChemistryOpen |
|---|---|
| Personen und Körperschaften: | , , , , |
| In: | ChemistryOpen, 8, 2019, 7, S. 972-983 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Szpecht, Andrea Zajac, Adrian Zielinski, Dawid Maciejewski, Hieronim Smiglak, Marcin Szpecht, Andrea Zajac, Adrian Zielinski, Dawid Maciejewski, Hieronim Smiglak, Marcin |
|---|---|
| author |
Szpecht, Andrea Zajac, Adrian Zielinski, Dawid Maciejewski, Hieronim Smiglak, Marcin |
| spellingShingle |
Szpecht, Andrea Zajac, Adrian Zielinski, Dawid Maciejewski, Hieronim Smiglak, Marcin ChemistryOpen Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy General Chemistry |
| author_sort |
szpecht, andrea |
| spelling |
Szpecht, Andrea Zajac, Adrian Zielinski, Dawid Maciejewski, Hieronim Smiglak, Marcin 2191-1363 2191-1363 Wiley General Chemistry http://dx.doi.org/10.1002/open.201900217 <jats:title>Abstract</jats:title><jats:p>A new synthetic approach and full spectral (NMR, IR, MS) and ion chromatographic characterization (IC) of nitrogen‐based ionic liquids bearing allyl‐ or ethyl‐ substituent and triflate, tosylate, methyl sulfate or methanesulfonate anion has been presented. On a sample of 16 new ionic liquids, the versatility of the anion exchange method has been proven. In the metathesis reactions that have been carried out, the halide anion was exchanged in ionic liquid with an alkyl sulfonate based anion using alkylating agents. The results obtained using ion chromatographic analysis on the newly synthesized compounds have been discussed. Also, the utilization of a gaseous methyl halide by‐product, obtained in the metathesis reaction and otherwise difficult to synthesize, has been presented. This approach ensured high atom economy of the overall process, which makes the proposed methodology sustainable and eco‐friendly.</jats:p> Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy ChemistryOpen |
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| title |
Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_unstemmed |
Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_full |
Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_fullStr |
Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_full_unstemmed |
Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_short |
Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_sort |
versatile method for the simultaneous synthesis of two ionic liquids, otherwise difficult to obtain, with high atom economy |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.1002/open.201900217 |
| publishDate |
2019 |
| physical |
972-983 |
| description |
<jats:title>Abstract</jats:title><jats:p>A new synthetic approach and full spectral (NMR, IR, MS) and ion chromatographic characterization (IC) of nitrogen‐based ionic liquids bearing allyl‐ or ethyl‐ substituent and triflate, tosylate, methyl sulfate or methanesulfonate anion has been presented. On a sample of 16 new ionic liquids, the versatility of the anion exchange method has been proven. In the metathesis reactions that have been carried out, the halide anion was exchanged in ionic liquid with an alkyl sulfonate based anion using alkylating agents. The results obtained using ion chromatographic analysis on the newly synthesized compounds have been discussed. Also, the utilization of a gaseous methyl halide by‐product, obtained in the metathesis reaction and otherwise difficult to synthesize, has been presented. This approach ensured high atom economy of the overall process, which makes the proposed methodology sustainable and eco‐friendly.</jats:p> |
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| author | Szpecht, Andrea, Zajac, Adrian, Zielinski, Dawid, Maciejewski, Hieronim, Smiglak, Marcin |
| author_facet | Szpecht, Andrea, Zajac, Adrian, Zielinski, Dawid, Maciejewski, Hieronim, Smiglak, Marcin, Szpecht, Andrea, Zajac, Adrian, Zielinski, Dawid, Maciejewski, Hieronim, Smiglak, Marcin |
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| description | <jats:title>Abstract</jats:title><jats:p>A new synthetic approach and full spectral (NMR, IR, MS) and ion chromatographic characterization (IC) of nitrogen‐based ionic liquids bearing allyl‐ or ethyl‐ substituent and triflate, tosylate, methyl sulfate or methanesulfonate anion has been presented. On a sample of 16 new ionic liquids, the versatility of the anion exchange method has been proven. In the metathesis reactions that have been carried out, the halide anion was exchanged in ionic liquid with an alkyl sulfonate based anion using alkylating agents. The results obtained using ion chromatographic analysis on the newly synthesized compounds have been discussed. Also, the utilization of a gaseous methyl halide by‐product, obtained in the metathesis reaction and otherwise difficult to synthesize, has been presented. This approach ensured high atom economy of the overall process, which makes the proposed methodology sustainable and eco‐friendly.</jats:p> |
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| spelling | Szpecht, Andrea Zajac, Adrian Zielinski, Dawid Maciejewski, Hieronim Smiglak, Marcin 2191-1363 2191-1363 Wiley General Chemistry http://dx.doi.org/10.1002/open.201900217 <jats:title>Abstract</jats:title><jats:p>A new synthetic approach and full spectral (NMR, IR, MS) and ion chromatographic characterization (IC) of nitrogen‐based ionic liquids bearing allyl‐ or ethyl‐ substituent and triflate, tosylate, methyl sulfate or methanesulfonate anion has been presented. On a sample of 16 new ionic liquids, the versatility of the anion exchange method has been proven. In the metathesis reactions that have been carried out, the halide anion was exchanged in ionic liquid with an alkyl sulfonate based anion using alkylating agents. The results obtained using ion chromatographic analysis on the newly synthesized compounds have been discussed. Also, the utilization of a gaseous methyl halide by‐product, obtained in the metathesis reaction and otherwise difficult to synthesize, has been presented. This approach ensured high atom economy of the overall process, which makes the proposed methodology sustainable and eco‐friendly.</jats:p> Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy ChemistryOpen |
| spellingShingle | Szpecht, Andrea, Zajac, Adrian, Zielinski, Dawid, Maciejewski, Hieronim, Smiglak, Marcin, ChemistryOpen, Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy, General Chemistry |
| title | Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_full | Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_fullStr | Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_full_unstemmed | Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_short | Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| title_sort | versatile method for the simultaneous synthesis of two ionic liquids, otherwise difficult to obtain, with high atom economy |
| title_unstemmed | Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy |
| topic | General Chemistry |
| url | http://dx.doi.org/10.1002/open.201900217 |