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Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane
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| Zeitschriftentitel: | Magnetic Resonance in Chemistry |
|---|---|
| Personen und Körperschaften: | , , , |
| In: | Magnetic Resonance in Chemistry, 52, 2014, 8, S. 448-452 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Shainyan, Bagrat A. Moskalik, Mikhail Yu. Heydenreich, Matthias Kleinpeter, Erich Shainyan, Bagrat A. Moskalik, Mikhail Yu. Heydenreich, Matthias Kleinpeter, Erich |
|---|---|
| author |
Shainyan, Bagrat A. Moskalik, Mikhail Yu. Heydenreich, Matthias Kleinpeter, Erich |
| spellingShingle |
Shainyan, Bagrat A. Moskalik, Mikhail Yu. Heydenreich, Matthias Kleinpeter, Erich Magnetic Resonance in Chemistry Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane General Materials Science General Chemistry |
| author_sort |
shainyan, bagrat a. |
| spelling |
Shainyan, Bagrat A. Moskalik, Mikhail Yu. Heydenreich, Matthias Kleinpeter, Erich 0749-1581 1097-458X Wiley General Materials Science General Chemistry http://dx.doi.org/10.1002/mrc.4086 <jats:p>Restricted rotation about the N–S partial double bonds in a <jats:italic>bis‐N</jats:italic>‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane derivative 1 has been frozen at low temperature (<jats:italic>Δ</jats:italic>G<jats:sup>≠</jats:sup> = 11.6 kcal mol<jats:sup>−1</jats:sup>), and the existence of all four rotamers about the two N–S bonds, <jats:italic>3‐in,8‐in</jats:italic>, <jats:italic>3‐in,8‐out</jats:italic>, <jats:italic>3‐out,8‐in</jats:italic>, and 3‐<jats:italic>out,8‐out</jats:italic>, respectively, proved experimentally by NMR spectroscopy and theoretically by DFT and MP2 calculations. Copyright © 2014 John Wiley & Sons, Ltd.</jats:p> Conformational equilibrium and dynamic behavior of <i>bis‐N</i>‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane Magnetic Resonance in Chemistry |
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| title |
Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_unstemmed |
Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_full |
Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_fullStr |
Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_full_unstemmed |
Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_short |
Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_sort |
conformational equilibrium and dynamic behavior of <i>bis‐n</i>‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| topic |
General Materials Science General Chemistry |
| url |
http://dx.doi.org/10.1002/mrc.4086 |
| publishDate |
2014 |
| physical |
448-452 |
| description |
<jats:p>Restricted rotation about the N–S partial double bonds in a <jats:italic>bis‐N</jats:italic>‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane derivative 1 has been frozen at low temperature (<jats:italic>Δ</jats:italic>G<jats:sup>≠</jats:sup> = 11.6 kcal mol<jats:sup>−1</jats:sup>), and the existence of all four rotamers about the two N–S bonds, <jats:italic>3‐in,8‐in</jats:italic>, <jats:italic>3‐in,8‐out</jats:italic>, <jats:italic>3‐out,8‐in</jats:italic>, and 3‐<jats:italic>out,8‐out</jats:italic>, respectively, proved experimentally by NMR spectroscopy and theoretically by DFT and MP2 calculations. Copyright © 2014 John Wiley & Sons, Ltd.</jats:p> |
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| author | Shainyan, Bagrat A., Moskalik, Mikhail Yu., Heydenreich, Matthias, Kleinpeter, Erich |
| author_facet | Shainyan, Bagrat A., Moskalik, Mikhail Yu., Heydenreich, Matthias, Kleinpeter, Erich, Shainyan, Bagrat A., Moskalik, Mikhail Yu., Heydenreich, Matthias, Kleinpeter, Erich |
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| description | <jats:p>Restricted rotation about the N–S partial double bonds in a <jats:italic>bis‐N</jats:italic>‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane derivative 1 has been frozen at low temperature (<jats:italic>Δ</jats:italic>G<jats:sup>≠</jats:sup> = 11.6 kcal mol<jats:sup>−1</jats:sup>), and the existence of all four rotamers about the two N–S bonds, <jats:italic>3‐in,8‐in</jats:italic>, <jats:italic>3‐in,8‐out</jats:italic>, <jats:italic>3‐out,8‐in</jats:italic>, and 3‐<jats:italic>out,8‐out</jats:italic>, respectively, proved experimentally by NMR spectroscopy and theoretically by DFT and MP2 calculations. Copyright © 2014 John Wiley & Sons, Ltd.</jats:p> |
| doi_str_mv | 10.1002/mrc.4086 |
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| format_dezwi2 | Article, E-Article |
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| imprint_str_mv | Wiley, 2014 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
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| physical | 448-452 |
| publishDate | 2014 |
| publishDateSort | 2014 |
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| series | Magnetic Resonance in Chemistry |
| source_id | 49 |
| spelling | Shainyan, Bagrat A. Moskalik, Mikhail Yu. Heydenreich, Matthias Kleinpeter, Erich 0749-1581 1097-458X Wiley General Materials Science General Chemistry http://dx.doi.org/10.1002/mrc.4086 <jats:p>Restricted rotation about the N–S partial double bonds in a <jats:italic>bis‐N</jats:italic>‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane derivative 1 has been frozen at low temperature (<jats:italic>Δ</jats:italic>G<jats:sup>≠</jats:sup> = 11.6 kcal mol<jats:sup>−1</jats:sup>), and the existence of all four rotamers about the two N–S bonds, <jats:italic>3‐in,8‐in</jats:italic>, <jats:italic>3‐in,8‐out</jats:italic>, <jats:italic>3‐out,8‐in</jats:italic>, and 3‐<jats:italic>out,8‐out</jats:italic>, respectively, proved experimentally by NMR spectroscopy and theoretically by DFT and MP2 calculations. Copyright © 2014 John Wiley & Sons, Ltd.</jats:p> Conformational equilibrium and dynamic behavior of <i>bis‐N</i>‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane Magnetic Resonance in Chemistry |
| spellingShingle | Shainyan, Bagrat A., Moskalik, Mikhail Yu., Heydenreich, Matthias, Kleinpeter, Erich, Magnetic Resonance in Chemistry, Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane, General Materials Science, General Chemistry |
| title | Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_full | Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_fullStr | Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_full_unstemmed | Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_short | Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_sort | conformational equilibrium and dynamic behavior of <i>bis‐n</i>‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| title_unstemmed | Conformational equilibrium and dynamic behavior of bis‐N‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane |
| topic | General Materials Science, General Chemistry |
| url | http://dx.doi.org/10.1002/mrc.4086 |