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Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets
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| Zeitschriftentitel: | Macromolecular Rapid Communications |
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| Personen und Körperschaften: | , , , , , , |
| In: | Macromolecular Rapid Communications, 40, 2019, 15 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Zhou, Liang‐Liang Chen, Jia‐Yi Li, Xing‐Yu Li, Hang Wang, Huan Wang, De‐Gao Kuang, Gui‐Chao Zhou, Liang‐Liang Chen, Jia‐Yi Li, Xing‐Yu Li, Hang Wang, Huan Wang, De‐Gao Kuang, Gui‐Chao |
|---|---|
| author |
Zhou, Liang‐Liang Chen, Jia‐Yi Li, Xing‐Yu Li, Hang Wang, Huan Wang, De‐Gao Kuang, Gui‐Chao |
| spellingShingle |
Zhou, Liang‐Liang Chen, Jia‐Yi Li, Xing‐Yu Li, Hang Wang, Huan Wang, De‐Gao Kuang, Gui‐Chao Macromolecular Rapid Communications Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets Materials Chemistry Polymers and Plastics Organic Chemistry |
| author_sort |
zhou, liang‐liang |
| spelling |
Zhou, Liang‐Liang Chen, Jia‐Yi Li, Xing‐Yu Li, Hang Wang, Huan Wang, De‐Gao Kuang, Gui‐Chao 1022-1336 1521-3927 Wiley Materials Chemistry Polymers and Plastics Organic Chemistry http://dx.doi.org/10.1002/marc.201900182 <jats:title>Abstract</jats:title><jats:p>The aggregate morphologies of 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐<jats:italic>s</jats:italic>‐indacene (BODIPY) main chain supramolecular polymer amphiphiles (SPA) are tunable by a fine balance of different non‐covalent interactions. When the BODIPY segments and sodium cholate are mixed in aqueous solution, they form SPA by electrostatic attraction and hydrogen‐bonds. This SPA displays helical nanowires' morphology. After the third component dimeric β‐cyclodextrin (β‐CD‐C) is added, the hydrogen bonds between the cholate are substituted by the host–guest interaction between cholate and β‐CD‐C. Therefore, these SPA transform their aggregate morphologies into nanosheets' architecture. Therefore, a simple and effective way to regulate self‐assembly by non‐covalent forces is developed. This supramolecular method may provide an effective way to prepare various nanostructures in aqueous solution and show promising application in the future.</jats:p> Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets Macromolecular Rapid Communications |
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10.1002/marc.201900182 |
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Wiley, 2019 |
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| title |
Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_unstemmed |
Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_full |
Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_fullStr |
Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_full_unstemmed |
Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_short |
Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_sort |
morphologies transformation of bodipy‐based main chain supramolecular polymers amphiphiles: from helical nanowires to nanosheets |
| topic |
Materials Chemistry Polymers and Plastics Organic Chemistry |
| url |
http://dx.doi.org/10.1002/marc.201900182 |
| publishDate |
2019 |
| physical |
|
| description |
<jats:title>Abstract</jats:title><jats:p>The aggregate morphologies of 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐<jats:italic>s</jats:italic>‐indacene (BODIPY) main chain supramolecular polymer amphiphiles (SPA) are tunable by a fine balance of different non‐covalent interactions. When the BODIPY segments and sodium cholate are mixed in aqueous solution, they form SPA by electrostatic attraction and hydrogen‐bonds. This SPA displays helical nanowires' morphology. After the third component dimeric β‐cyclodextrin (β‐CD‐C) is added, the hydrogen bonds between the cholate are substituted by the host–guest interaction between cholate and β‐CD‐C. Therefore, these SPA transform their aggregate morphologies into nanosheets' architecture. Therefore, a simple and effective way to regulate self‐assembly by non‐covalent forces is developed. This supramolecular method may provide an effective way to prepare various nanostructures in aqueous solution and show promising application in the future.</jats:p> |
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| author | Zhou, Liang‐Liang, Chen, Jia‐Yi, Li, Xing‐Yu, Li, Hang, Wang, Huan, Wang, De‐Gao, Kuang, Gui‐Chao |
| author_facet | Zhou, Liang‐Liang, Chen, Jia‐Yi, Li, Xing‐Yu, Li, Hang, Wang, Huan, Wang, De‐Gao, Kuang, Gui‐Chao, Zhou, Liang‐Liang, Chen, Jia‐Yi, Li, Xing‐Yu, Li, Hang, Wang, Huan, Wang, De‐Gao, Kuang, Gui‐Chao |
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| description | <jats:title>Abstract</jats:title><jats:p>The aggregate morphologies of 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐<jats:italic>s</jats:italic>‐indacene (BODIPY) main chain supramolecular polymer amphiphiles (SPA) are tunable by a fine balance of different non‐covalent interactions. When the BODIPY segments and sodium cholate are mixed in aqueous solution, they form SPA by electrostatic attraction and hydrogen‐bonds. This SPA displays helical nanowires' morphology. After the third component dimeric β‐cyclodextrin (β‐CD‐C) is added, the hydrogen bonds between the cholate are substituted by the host–guest interaction between cholate and β‐CD‐C. Therefore, these SPA transform their aggregate morphologies into nanosheets' architecture. Therefore, a simple and effective way to regulate self‐assembly by non‐covalent forces is developed. This supramolecular method may provide an effective way to prepare various nanostructures in aqueous solution and show promising application in the future.</jats:p> |
| doi_str_mv | 10.1002/marc.201900182 |
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| imprint | Wiley, 2019 |
| imprint_str_mv | Wiley, 2019 |
| institution | DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1 |
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| publishDate | 2019 |
| publishDateSort | 2019 |
| publisher | Wiley |
| record_format | ai |
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| series | Macromolecular Rapid Communications |
| source_id | 49 |
| spelling | Zhou, Liang‐Liang Chen, Jia‐Yi Li, Xing‐Yu Li, Hang Wang, Huan Wang, De‐Gao Kuang, Gui‐Chao 1022-1336 1521-3927 Wiley Materials Chemistry Polymers and Plastics Organic Chemistry http://dx.doi.org/10.1002/marc.201900182 <jats:title>Abstract</jats:title><jats:p>The aggregate morphologies of 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐<jats:italic>s</jats:italic>‐indacene (BODIPY) main chain supramolecular polymer amphiphiles (SPA) are tunable by a fine balance of different non‐covalent interactions. When the BODIPY segments and sodium cholate are mixed in aqueous solution, they form SPA by electrostatic attraction and hydrogen‐bonds. This SPA displays helical nanowires' morphology. After the third component dimeric β‐cyclodextrin (β‐CD‐C) is added, the hydrogen bonds between the cholate are substituted by the host–guest interaction between cholate and β‐CD‐C. Therefore, these SPA transform their aggregate morphologies into nanosheets' architecture. Therefore, a simple and effective way to regulate self‐assembly by non‐covalent forces is developed. This supramolecular method may provide an effective way to prepare various nanostructures in aqueous solution and show promising application in the future.</jats:p> Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets Macromolecular Rapid Communications |
| spellingShingle | Zhou, Liang‐Liang, Chen, Jia‐Yi, Li, Xing‐Yu, Li, Hang, Wang, Huan, Wang, De‐Gao, Kuang, Gui‐Chao, Macromolecular Rapid Communications, Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets, Materials Chemistry, Polymers and Plastics, Organic Chemistry |
| title | Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_full | Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_fullStr | Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_full_unstemmed | Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_short | Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| title_sort | morphologies transformation of bodipy‐based main chain supramolecular polymers amphiphiles: from helical nanowires to nanosheets |
| title_unstemmed | Morphologies Transformation of BODIPY‐Based Main Chain Supramolecular Polymers Amphiphiles: From Helical Nanowires to Nanosheets |
| topic | Materials Chemistry, Polymers and Plastics, Organic Chemistry |
| url | http://dx.doi.org/10.1002/marc.201900182 |