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Hyperbranched methacrylates by self‐condensing group transfer polymerization
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| Zeitschriftentitel: | Macromolecular Rapid Communications |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Macromolecular Rapid Communications, 18, 1997, 9, S. 865-873 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Simon, Peter F. W. Radke, Wolfgang Müller, Axel H. E. Simon, Peter F. W. Radke, Wolfgang Müller, Axel H. E. |
|---|---|
| author |
Simon, Peter F. W. Radke, Wolfgang Müller, Axel H. E. |
| spellingShingle |
Simon, Peter F. W. Radke, Wolfgang Müller, Axel H. E. Macromolecular Rapid Communications Hyperbranched methacrylates by self‐condensing group transfer polymerization Materials Chemistry Polymers and Plastics Organic Chemistry |
| author_sort |
simon, peter f. w. |
| spelling |
Simon, Peter F. W. Radke, Wolfgang Müller, Axel H. E. 1022-1336 1521-3927 Wiley Materials Chemistry Polymers and Plastics Organic Chemistry http://dx.doi.org/10.1002/marc.1997.030180915 <jats:title>Abstract</jats:title><jats:p>The synthesis of hyperbranched methacrylates was achieved by self‐condensing group transfer polymerization of 2‐(2‐methyl‐1‐triethylsiloxy‐1‐propenyloxy)ethyl methacrylate (<jats:bold>1</jats:bold>). “Back‐biting” is shown to be the predominant side reaction. In spite of this, the compact nature of the hyperbranched molecules was demonstrated through SEC‐viscosity measurements and comparison with a linear analogue. The degree of branching can be controlled by copolymerization with conventional monomers, e.g. MMA, and the living polymers can be used as macroinitiators for star‐shaped polymers.</jats:p> Hyperbranched methacrylates by self‐condensing group transfer polymerization Macromolecular Rapid Communications |
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Wiley, 1997 |
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Wiley, 1997 |
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Macromolecular Rapid Communications |
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| title |
Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_unstemmed |
Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_full |
Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_fullStr |
Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_full_unstemmed |
Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_short |
Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_sort |
hyperbranched methacrylates by self‐condensing group transfer polymerization |
| topic |
Materials Chemistry Polymers and Plastics Organic Chemistry |
| url |
http://dx.doi.org/10.1002/marc.1997.030180915 |
| publishDate |
1997 |
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865-873 |
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<jats:title>Abstract</jats:title><jats:p>The synthesis of hyperbranched methacrylates was achieved by self‐condensing group transfer polymerization of 2‐(2‐methyl‐1‐triethylsiloxy‐1‐propenyloxy)ethyl methacrylate (<jats:bold>1</jats:bold>). “Back‐biting” is shown to be the predominant side reaction. In spite of this, the compact nature of the hyperbranched molecules was demonstrated through SEC‐viscosity measurements and comparison with a linear analogue. The degree of branching can be controlled by copolymerization with conventional monomers, e.g. MMA, and the living polymers can be used as macroinitiators for star‐shaped polymers.</jats:p> |
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| author | Simon, Peter F. W., Radke, Wolfgang, Müller, Axel H. E. |
| author_facet | Simon, Peter F. W., Radke, Wolfgang, Müller, Axel H. E., Simon, Peter F. W., Radke, Wolfgang, Müller, Axel H. E. |
| author_sort | simon, peter f. w. |
| container_issue | 9 |
| container_start_page | 865 |
| container_title | Macromolecular Rapid Communications |
| container_volume | 18 |
| description | <jats:title>Abstract</jats:title><jats:p>The synthesis of hyperbranched methacrylates was achieved by self‐condensing group transfer polymerization of 2‐(2‐methyl‐1‐triethylsiloxy‐1‐propenyloxy)ethyl methacrylate (<jats:bold>1</jats:bold>). “Back‐biting” is shown to be the predominant side reaction. In spite of this, the compact nature of the hyperbranched molecules was demonstrated through SEC‐viscosity measurements and comparison with a linear analogue. The degree of branching can be controlled by copolymerization with conventional monomers, e.g. MMA, and the living polymers can be used as macroinitiators for star‐shaped polymers.</jats:p> |
| doi_str_mv | 10.1002/marc.1997.030180915 |
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| imprint | Wiley, 1997 |
| imprint_str_mv | Wiley, 1997 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161 |
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| physical | 865-873 |
| publishDate | 1997 |
| publishDateSort | 1997 |
| publisher | Wiley |
| record_format | ai |
| recordtype | ai |
| series | Macromolecular Rapid Communications |
| source_id | 49 |
| spelling | Simon, Peter F. W. Radke, Wolfgang Müller, Axel H. E. 1022-1336 1521-3927 Wiley Materials Chemistry Polymers and Plastics Organic Chemistry http://dx.doi.org/10.1002/marc.1997.030180915 <jats:title>Abstract</jats:title><jats:p>The synthesis of hyperbranched methacrylates was achieved by self‐condensing group transfer polymerization of 2‐(2‐methyl‐1‐triethylsiloxy‐1‐propenyloxy)ethyl methacrylate (<jats:bold>1</jats:bold>). “Back‐biting” is shown to be the predominant side reaction. In spite of this, the compact nature of the hyperbranched molecules was demonstrated through SEC‐viscosity measurements and comparison with a linear analogue. The degree of branching can be controlled by copolymerization with conventional monomers, e.g. MMA, and the living polymers can be used as macroinitiators for star‐shaped polymers.</jats:p> Hyperbranched methacrylates by self‐condensing group transfer polymerization Macromolecular Rapid Communications |
| spellingShingle | Simon, Peter F. W., Radke, Wolfgang, Müller, Axel H. E., Macromolecular Rapid Communications, Hyperbranched methacrylates by self‐condensing group transfer polymerization, Materials Chemistry, Polymers and Plastics, Organic Chemistry |
| title | Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_full | Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_fullStr | Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_full_unstemmed | Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_short | Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_sort | hyperbranched methacrylates by self‐condensing group transfer polymerization |
| title_unstemmed | Hyperbranched methacrylates by self‐condensing group transfer polymerization |
| topic | Materials Chemistry, Polymers and Plastics, Organic Chemistry |
| url | http://dx.doi.org/10.1002/marc.1997.030180915 |