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BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation
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| Zeitschriftentitel: | Macromolecular Chemistry and Physics |
|---|---|
| Personen und Körperschaften: | , , , , , |
| In: | Macromolecular Chemistry and Physics, 218, 2017, 15 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Wang, De‐Gao Li, Qian Zhu, Yunlong Tang, Hui Song, Min Kuang, Gui‐Chao Wang, De‐Gao Li, Qian Zhu, Yunlong Tang, Hui Song, Min Kuang, Gui‐Chao |
|---|---|
| author |
Wang, De‐Gao Li, Qian Zhu, Yunlong Tang, Hui Song, Min Kuang, Gui‐Chao |
| spellingShingle |
Wang, De‐Gao Li, Qian Zhu, Yunlong Tang, Hui Song, Min Kuang, Gui‐Chao Macromolecular Chemistry and Physics BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation Materials Chemistry Organic Chemistry Polymers and Plastics Physical and Theoretical Chemistry Condensed Matter Physics |
| author_sort |
wang, de‐gao |
| spelling |
Wang, De‐Gao Li, Qian Zhu, Yunlong Tang, Hui Song, Min Kuang, Gui‐Chao 1022-1352 1521-3935 Wiley Materials Chemistry Organic Chemistry Polymers and Plastics Physical and Theoretical Chemistry Condensed Matter Physics http://dx.doi.org/10.1002/macp.201700101 <jats:p>Facile Friedel–Crafts coupling reaction prepared porous organic polymers <jats:bold>BDP‐POP‐<jats:italic>n</jats:italic></jats:bold> (<jats:italic>n</jats:italic> = 1, 3, and 4) are reported. The influences of methyl substituents and single monomer isomerization on corresponding BDP‐POPs' porosity and singlet oxygen generation properties have been investigated. The obtained BDP‐POPs are thoroughly characterized by a combination of techniques such as Fourier transform infrared, solid <jats:sup>13</jats:sup>C NMR, scanning electron microscopy, and transmission electron microscopy. In addition, these porous polymers' singlet oxygen generation capacities under visible green light (480–510 nm) irradiation are compared. Results show that <jats:bold>BDP‐POP‐1</jats:bold>, whose pyrrolyl ring bears methyl substituents and the two 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐s‐indacene (BDP) units are at <jats:italic>para</jats:italic>‐position of the phenyl ring, possesses the largest Brunauer–Emmett–Teller surface area and the best singlet oxygen generation ability. Control experiment reveals that the <jats:bold>BDP‐POP‐1</jats:bold> shows superiority in generating singlet oxygen than that of model polymer <jats:bold>CMPBDP</jats:bold>. It is believed that this work may pave a road to design more effective porous materials for photocatalysis. <jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/png" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/macp201700101-abs-0001-m.png"><jats:alt-text>image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p> BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation Macromolecular Chemistry and Physics |
| doi_str_mv |
10.1002/macp.201700101 |
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Online |
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Chemie und Pharmazie Physik |
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Wiley, 2017 |
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1022-1352 1521-3935 |
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| title |
BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_unstemmed |
BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_full |
BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_fullStr |
BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_full_unstemmed |
BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_short |
BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_sort |
bodipy‐based porous organic polymers: how the monomeric methyl substituents and isomerization affect the porosity and singlet oxygen generation |
| topic |
Materials Chemistry Organic Chemistry Polymers and Plastics Physical and Theoretical Chemistry Condensed Matter Physics |
| url |
http://dx.doi.org/10.1002/macp.201700101 |
| publishDate |
2017 |
| physical |
|
| description |
<jats:p>Facile Friedel–Crafts coupling reaction prepared porous organic polymers <jats:bold>BDP‐POP‐<jats:italic>n</jats:italic></jats:bold> (<jats:italic>n</jats:italic> = 1, 3, and 4) are reported. The influences of methyl substituents and single monomer isomerization on corresponding BDP‐POPs' porosity and singlet oxygen generation properties have been investigated. The obtained BDP‐POPs are thoroughly characterized by a combination of techniques such as Fourier transform infrared, solid <jats:sup>13</jats:sup>C NMR, scanning electron microscopy, and transmission electron microscopy. In addition, these porous polymers' singlet oxygen generation capacities under visible green light (480–510 nm) irradiation are compared. Results show that <jats:bold>BDP‐POP‐1</jats:bold>, whose pyrrolyl ring bears methyl substituents and the two 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐s‐indacene (BDP) units are at <jats:italic>para</jats:italic>‐position of the phenyl ring, possesses the largest Brunauer–Emmett–Teller surface area and the best singlet oxygen generation ability. Control experiment reveals that the <jats:bold>BDP‐POP‐1</jats:bold> shows superiority in generating singlet oxygen than that of model polymer <jats:bold>CMPBDP</jats:bold>. It is believed that this work may pave a road to design more effective porous materials for photocatalysis.
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| author | Wang, De‐Gao, Li, Qian, Zhu, Yunlong, Tang, Hui, Song, Min, Kuang, Gui‐Chao |
| author_facet | Wang, De‐Gao, Li, Qian, Zhu, Yunlong, Tang, Hui, Song, Min, Kuang, Gui‐Chao, Wang, De‐Gao, Li, Qian, Zhu, Yunlong, Tang, Hui, Song, Min, Kuang, Gui‐Chao |
| author_sort | wang, de‐gao |
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| description | <jats:p>Facile Friedel–Crafts coupling reaction prepared porous organic polymers <jats:bold>BDP‐POP‐<jats:italic>n</jats:italic></jats:bold> (<jats:italic>n</jats:italic> = 1, 3, and 4) are reported. The influences of methyl substituents and single monomer isomerization on corresponding BDP‐POPs' porosity and singlet oxygen generation properties have been investigated. The obtained BDP‐POPs are thoroughly characterized by a combination of techniques such as Fourier transform infrared, solid <jats:sup>13</jats:sup>C NMR, scanning electron microscopy, and transmission electron microscopy. In addition, these porous polymers' singlet oxygen generation capacities under visible green light (480–510 nm) irradiation are compared. Results show that <jats:bold>BDP‐POP‐1</jats:bold>, whose pyrrolyl ring bears methyl substituents and the two 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐s‐indacene (BDP) units are at <jats:italic>para</jats:italic>‐position of the phenyl ring, possesses the largest Brunauer–Emmett–Teller surface area and the best singlet oxygen generation ability. Control experiment reveals that the <jats:bold>BDP‐POP‐1</jats:bold> shows superiority in generating singlet oxygen than that of model polymer <jats:bold>CMPBDP</jats:bold>. It is believed that this work may pave a road to design more effective porous materials for photocatalysis. <jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/png" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/macp201700101-abs-0001-m.png"><jats:alt-text>image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p> |
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| imprint | Wiley, 2017 |
| imprint_str_mv | Wiley, 2017 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161 |
| issn | 1022-1352, 1521-3935 |
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| mega_collection | Wiley (CrossRef) |
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| publishDateSort | 2017 |
| publisher | Wiley |
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| series | Macromolecular Chemistry and Physics |
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| spelling | Wang, De‐Gao Li, Qian Zhu, Yunlong Tang, Hui Song, Min Kuang, Gui‐Chao 1022-1352 1521-3935 Wiley Materials Chemistry Organic Chemistry Polymers and Plastics Physical and Theoretical Chemistry Condensed Matter Physics http://dx.doi.org/10.1002/macp.201700101 <jats:p>Facile Friedel–Crafts coupling reaction prepared porous organic polymers <jats:bold>BDP‐POP‐<jats:italic>n</jats:italic></jats:bold> (<jats:italic>n</jats:italic> = 1, 3, and 4) are reported. The influences of methyl substituents and single monomer isomerization on corresponding BDP‐POPs' porosity and singlet oxygen generation properties have been investigated. The obtained BDP‐POPs are thoroughly characterized by a combination of techniques such as Fourier transform infrared, solid <jats:sup>13</jats:sup>C NMR, scanning electron microscopy, and transmission electron microscopy. In addition, these porous polymers' singlet oxygen generation capacities under visible green light (480–510 nm) irradiation are compared. Results show that <jats:bold>BDP‐POP‐1</jats:bold>, whose pyrrolyl ring bears methyl substituents and the two 4,4‐difluoro‐4‐bora‐3a,4a‐diaza‐s‐indacene (BDP) units are at <jats:italic>para</jats:italic>‐position of the phenyl ring, possesses the largest Brunauer–Emmett–Teller surface area and the best singlet oxygen generation ability. Control experiment reveals that the <jats:bold>BDP‐POP‐1</jats:bold> shows superiority in generating singlet oxygen than that of model polymer <jats:bold>CMPBDP</jats:bold>. It is believed that this work may pave a road to design more effective porous materials for photocatalysis. <jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/png" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/macp201700101-abs-0001-m.png"><jats:alt-text>image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p> BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation Macromolecular Chemistry and Physics |
| spellingShingle | Wang, De‐Gao, Li, Qian, Zhu, Yunlong, Tang, Hui, Song, Min, Kuang, Gui‐Chao, Macromolecular Chemistry and Physics, BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation, Materials Chemistry, Organic Chemistry, Polymers and Plastics, Physical and Theoretical Chemistry, Condensed Matter Physics |
| title | BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_full | BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_fullStr | BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_full_unstemmed | BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_short | BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| title_sort | bodipy‐based porous organic polymers: how the monomeric methyl substituents and isomerization affect the porosity and singlet oxygen generation |
| title_unstemmed | BODIPY‐Based Porous Organic Polymers: How the Monomeric Methyl Substituents and Isomerization Affect the Porosity and Singlet Oxygen Generation |
| topic | Materials Chemistry, Organic Chemistry, Polymers and Plastics, Physical and Theoretical Chemistry, Condensed Matter Physics |
| url | http://dx.doi.org/10.1002/macp.201700101 |