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Artificial Opals as Effect Pigments in Clear‐Coatings
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| Zeitschriftentitel: | Macromolecular Materials and Engineering |
|---|---|
| Personen und Körperschaften: | , , , , , , |
| In: | Macromolecular Materials and Engineering, 289, 2004, 2, S. 158-163 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Egen, Marc Braun, Lydia Zentel, Rudolf Tännert, Klaus Frese, Peter Reis, Oliver Wulf, Martin Egen, Marc Braun, Lydia Zentel, Rudolf Tännert, Klaus Frese, Peter Reis, Oliver Wulf, Martin |
|---|---|
| author |
Egen, Marc Braun, Lydia Zentel, Rudolf Tännert, Klaus Frese, Peter Reis, Oliver Wulf, Martin |
| spellingShingle |
Egen, Marc Braun, Lydia Zentel, Rudolf Tännert, Klaus Frese, Peter Reis, Oliver Wulf, Martin Macromolecular Materials and Engineering Artificial Opals as Effect Pigments in Clear‐Coatings Materials Chemistry Polymers and Plastics Organic Chemistry General Chemical Engineering |
| author_sort |
egen, marc |
| spelling |
Egen, Marc Braun, Lydia Zentel, Rudolf Tännert, Klaus Frese, Peter Reis, Oliver Wulf, Martin 1438-7492 1439-2054 Wiley Materials Chemistry Polymers and Plastics Organic Chemistry General Chemical Engineering http://dx.doi.org/10.1002/mame.200300152 <jats:title>Abstract</jats:title><jats:p><jats:bold>Summary:</jats:bold> In this paper, we describe the use of artificial opals from polymer beads as effect pigments in transparent industrial and automotive coatings. For this purpose, we synthesized monodisperse colloids from fluorinated methacrylates by surfactant‐free emulsion polymerization. The fluorinated monomers, in combination with crosslinking, lead to a refractive index contrast, thermal stability, and solvent resistivity necessary for use as effect pigments. After crystallization of the monodisperse polymer beads, crystal flakes with iridescent colors can be obtained. The crystal flakes can act as effect pigments in various transparent industrial and automotive coatings. Due to photonic crystal behavior of effect pigments, color flops up to 100 nm are observed.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:caption><jats:p>Crystal flakes of <jats:bold>CS</jats:bold>‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.</jats:p></jats:caption><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/jpeg" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mgra001.jpg"><jats:alt-text>magnified image</jats:alt-text><jats:caption><jats:p>Crystal flakes of <jats:bold>CS</jats:bold>‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.</jats:p></jats:caption></jats:graphic></jats:boxed-text> </jats:p> Artificial Opals as Effect Pigments in Clear‐Coatings Macromolecular Materials and Engineering |
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| title |
Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_unstemmed |
Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_full |
Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_fullStr |
Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_full_unstemmed |
Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_short |
Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_sort |
artificial opals as effect pigments in clear‐coatings |
| topic |
Materials Chemistry Polymers and Plastics Organic Chemistry General Chemical Engineering |
| url |
http://dx.doi.org/10.1002/mame.200300152 |
| publishDate |
2004 |
| physical |
158-163 |
| description |
<jats:title>Abstract</jats:title><jats:p><jats:bold>Summary:</jats:bold> In this paper, we describe the use of artificial opals from polymer beads as effect pigments in transparent industrial and automotive coatings. For this purpose, we synthesized monodisperse colloids from fluorinated methacrylates by surfactant‐free emulsion polymerization. The fluorinated monomers, in combination with crosslinking, lead to a refractive index contrast, thermal stability, and solvent resistivity necessary for use as effect pigments. After crystallization of the monodisperse polymer beads, crystal flakes with iridescent colors can be obtained. The crystal flakes can act as effect pigments in various transparent industrial and automotive coatings. Due to photonic crystal behavior of effect pigments, color flops up to 100 nm are observed.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:caption><jats:p>Crystal flakes of <jats:bold>CS</jats:bold>‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.</jats:p></jats:caption><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/jpeg" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mgra001.jpg"><jats:alt-text>magnified image</jats:alt-text><jats:caption><jats:p>Crystal flakes of <jats:bold>CS</jats:bold>‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.</jats:p></jats:caption></jats:graphic></jats:boxed-text>
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| author | Egen, Marc, Braun, Lydia, Zentel, Rudolf, Tännert, Klaus, Frese, Peter, Reis, Oliver, Wulf, Martin |
| author_facet | Egen, Marc, Braun, Lydia, Zentel, Rudolf, Tännert, Klaus, Frese, Peter, Reis, Oliver, Wulf, Martin, Egen, Marc, Braun, Lydia, Zentel, Rudolf, Tännert, Klaus, Frese, Peter, Reis, Oliver, Wulf, Martin |
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| description | <jats:title>Abstract</jats:title><jats:p><jats:bold>Summary:</jats:bold> In this paper, we describe the use of artificial opals from polymer beads as effect pigments in transparent industrial and automotive coatings. For this purpose, we synthesized monodisperse colloids from fluorinated methacrylates by surfactant‐free emulsion polymerization. The fluorinated monomers, in combination with crosslinking, lead to a refractive index contrast, thermal stability, and solvent resistivity necessary for use as effect pigments. After crystallization of the monodisperse polymer beads, crystal flakes with iridescent colors can be obtained. The crystal flakes can act as effect pigments in various transparent industrial and automotive coatings. Due to photonic crystal behavior of effect pigments, color flops up to 100 nm are observed.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:caption><jats:p>Crystal flakes of <jats:bold>CS</jats:bold>‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.</jats:p></jats:caption><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/jpeg" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mgra001.jpg"><jats:alt-text>magnified image</jats:alt-text><jats:caption><jats:p>Crystal flakes of <jats:bold>CS</jats:bold>‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.</jats:p></jats:caption></jats:graphic></jats:boxed-text> </jats:p> |
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| spelling | Egen, Marc Braun, Lydia Zentel, Rudolf Tännert, Klaus Frese, Peter Reis, Oliver Wulf, Martin 1438-7492 1439-2054 Wiley Materials Chemistry Polymers and Plastics Organic Chemistry General Chemical Engineering http://dx.doi.org/10.1002/mame.200300152 <jats:title>Abstract</jats:title><jats:p><jats:bold>Summary:</jats:bold> In this paper, we describe the use of artificial opals from polymer beads as effect pigments in transparent industrial and automotive coatings. For this purpose, we synthesized monodisperse colloids from fluorinated methacrylates by surfactant‐free emulsion polymerization. The fluorinated monomers, in combination with crosslinking, lead to a refractive index contrast, thermal stability, and solvent resistivity necessary for use as effect pigments. After crystallization of the monodisperse polymer beads, crystal flakes with iridescent colors can be obtained. The crystal flakes can act as effect pigments in various transparent industrial and automotive coatings. Due to photonic crystal behavior of effect pigments, color flops up to 100 nm are observed.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:caption><jats:p>Crystal flakes of <jats:bold>CS</jats:bold>‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.</jats:p></jats:caption><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/jpeg" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mgra001.jpg"><jats:alt-text>magnified image</jats:alt-text><jats:caption><jats:p>Crystal flakes of <jats:bold>CS</jats:bold>‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.</jats:p></jats:caption></jats:graphic></jats:boxed-text> </jats:p> Artificial Opals as Effect Pigments in Clear‐Coatings Macromolecular Materials and Engineering |
| spellingShingle | Egen, Marc, Braun, Lydia, Zentel, Rudolf, Tännert, Klaus, Frese, Peter, Reis, Oliver, Wulf, Martin, Macromolecular Materials and Engineering, Artificial Opals as Effect Pigments in Clear‐Coatings, Materials Chemistry, Polymers and Plastics, Organic Chemistry, General Chemical Engineering |
| title | Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_full | Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_fullStr | Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_full_unstemmed | Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_short | Artificial Opals as Effect Pigments in Clear‐Coatings |
| title_sort | artificial opals as effect pigments in clear‐coatings |
| title_unstemmed | Artificial Opals as Effect Pigments in Clear‐Coatings |
| topic | Materials Chemistry, Polymers and Plastics, Organic Chemistry, General Chemical Engineering |
| url | http://dx.doi.org/10.1002/mame.200300152 |