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Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung
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| Zeitschriftentitel: | Helvetica Chimica Acta |
|---|---|
| Personen und Körperschaften: | , , , , |
| In: | Helvetica Chimica Acta, 55, 1972, 5, S. 1696-1728 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Lichti, H. von Euw, J. Stöckel, K. Polonia, J. Reichstein, T. Lichti, H. von Euw, J. Stöckel, K. Polonia, J. Reichstein, T. |
|---|---|
| author |
Lichti, H. von Euw, J. Stöckel, K. Polonia, J. Reichstein, T. |
| spellingShingle |
Lichti, H. von Euw, J. Stöckel, K. Polonia, J. Reichstein, T. Helvetica Chimica Acta Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung Inorganic Chemistry Organic Chemistry Physical and Theoretical Chemistry Drug Discovery Biochemistry Catalysis |
| author_sort |
lichti, h. |
| spelling |
Lichti, H. von Euw, J. Stöckel, K. Polonia, J. Reichstein, T. 0018-019X 1522-2675 Wiley Inorganic Chemistry Organic Chemistry Physical and Theoretical Chemistry Drug Discovery Biochemistry Catalysis http://dx.doi.org/10.1002/hlca.19720550529 <jats:title>Abstract</jats:title><jats:p>Five crystalline compounds (anodendrosides) have been isolated from <jats:italic>Anodendron paniculatum</jats:italic> (<jats:italic>Roxb</jats:italic>.)<jats:italic>A. DC</jats:italic>. (Apocynaceae). They represent glycosides containing unusual sugars. Tentative structures for anodendroside‐A (<jats:bold>155</jats:bold>), −E<jats:sub>1</jats:sub> (<jats:bold>3</jats:bold>), −E<jats:sub>2</jats:sub> (<jats:bold>84</jats:bold>), −F (<jats:bold>144</jats:bold>) and −G (<jats:bold>115</jats:bold>) are now presented. These structures are based on UV., IR., but mostly on high resolution mass spectra. NMR.‐spectra could be performed with A, O‐acetyl‐E<jats:sub>2</jats:sub> and O‐acetyl‐G, which are in good agreement with the suggested structures. The unusual methylendioxy group postulated in the sugar moiety of A, E<jats:sub>1</jats:sub> and E<jats:sub>2</jats:sub> was also established by chemical methods, yielding approximately 1 Mol. equiv. of formaldehyde after acid hydrolysis of anodendroside‐E<jats:sub>2</jats:sub>.</jats:p> Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung Helvetica Chimica Acta |
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Wiley, 1972 |
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Wiley, 1972 |
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Helvetica Chimica Acta |
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49 |
| title |
Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_unstemmed |
Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_full |
Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_fullStr |
Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_full_unstemmed |
Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_short |
Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_sort |
die vermutliche struktur der anodendroside. glykoside und aglykone, 331. mitteilung |
| topic |
Inorganic Chemistry Organic Chemistry Physical and Theoretical Chemistry Drug Discovery Biochemistry Catalysis |
| url |
http://dx.doi.org/10.1002/hlca.19720550529 |
| publishDate |
1972 |
| physical |
1696-1728 |
| description |
<jats:title>Abstract</jats:title><jats:p>Five crystalline compounds (anodendrosides) have been isolated from <jats:italic>Anodendron paniculatum</jats:italic> (<jats:italic>Roxb</jats:italic>.)<jats:italic>A. DC</jats:italic>. (Apocynaceae). They represent glycosides containing unusual sugars. Tentative structures for anodendroside‐A (<jats:bold>155</jats:bold>), −E<jats:sub>1</jats:sub> (<jats:bold>3</jats:bold>), −E<jats:sub>2</jats:sub> (<jats:bold>84</jats:bold>), −F (<jats:bold>144</jats:bold>) and −G (<jats:bold>115</jats:bold>) are now presented. These structures are based on UV., IR., but mostly on high resolution mass spectra. NMR.‐spectra could be performed with A, O‐acetyl‐E<jats:sub>2</jats:sub> and O‐acetyl‐G, which are in good agreement with the suggested structures. The unusual methylendioxy group postulated in the sugar moiety of A, E<jats:sub>1</jats:sub> and E<jats:sub>2</jats:sub> was also established by chemical methods, yielding approximately 1 Mol. equiv. of formaldehyde after acid hydrolysis of anodendroside‐E<jats:sub>2</jats:sub>.</jats:p> |
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| author | Lichti, H., von Euw, J., Stöckel, K., Polonia, J., Reichstein, T. |
| author_facet | Lichti, H., von Euw, J., Stöckel, K., Polonia, J., Reichstein, T., Lichti, H., von Euw, J., Stöckel, K., Polonia, J., Reichstein, T. |
| author_sort | lichti, h. |
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| description | <jats:title>Abstract</jats:title><jats:p>Five crystalline compounds (anodendrosides) have been isolated from <jats:italic>Anodendron paniculatum</jats:italic> (<jats:italic>Roxb</jats:italic>.)<jats:italic>A. DC</jats:italic>. (Apocynaceae). They represent glycosides containing unusual sugars. Tentative structures for anodendroside‐A (<jats:bold>155</jats:bold>), −E<jats:sub>1</jats:sub> (<jats:bold>3</jats:bold>), −E<jats:sub>2</jats:sub> (<jats:bold>84</jats:bold>), −F (<jats:bold>144</jats:bold>) and −G (<jats:bold>115</jats:bold>) are now presented. These structures are based on UV., IR., but mostly on high resolution mass spectra. NMR.‐spectra could be performed with A, O‐acetyl‐E<jats:sub>2</jats:sub> and O‐acetyl‐G, which are in good agreement with the suggested structures. The unusual methylendioxy group postulated in the sugar moiety of A, E<jats:sub>1</jats:sub> and E<jats:sub>2</jats:sub> was also established by chemical methods, yielding approximately 1 Mol. equiv. of formaldehyde after acid hydrolysis of anodendroside‐E<jats:sub>2</jats:sub>.</jats:p> |
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| imprint | Wiley, 1972 |
| imprint_str_mv | Wiley, 1972 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
| issn | 0018-019X, 1522-2675 |
| issn_str_mv | 0018-019X, 1522-2675 |
| language | English |
| last_indexed | 2024-03-01T15:19:59.03Z |
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| physical | 1696-1728 |
| publishDate | 1972 |
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| publisher | Wiley |
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| series | Helvetica Chimica Acta |
| source_id | 49 |
| spelling | Lichti, H. von Euw, J. Stöckel, K. Polonia, J. Reichstein, T. 0018-019X 1522-2675 Wiley Inorganic Chemistry Organic Chemistry Physical and Theoretical Chemistry Drug Discovery Biochemistry Catalysis http://dx.doi.org/10.1002/hlca.19720550529 <jats:title>Abstract</jats:title><jats:p>Five crystalline compounds (anodendrosides) have been isolated from <jats:italic>Anodendron paniculatum</jats:italic> (<jats:italic>Roxb</jats:italic>.)<jats:italic>A. DC</jats:italic>. (Apocynaceae). They represent glycosides containing unusual sugars. Tentative structures for anodendroside‐A (<jats:bold>155</jats:bold>), −E<jats:sub>1</jats:sub> (<jats:bold>3</jats:bold>), −E<jats:sub>2</jats:sub> (<jats:bold>84</jats:bold>), −F (<jats:bold>144</jats:bold>) and −G (<jats:bold>115</jats:bold>) are now presented. These structures are based on UV., IR., but mostly on high resolution mass spectra. NMR.‐spectra could be performed with A, O‐acetyl‐E<jats:sub>2</jats:sub> and O‐acetyl‐G, which are in good agreement with the suggested structures. The unusual methylendioxy group postulated in the sugar moiety of A, E<jats:sub>1</jats:sub> and E<jats:sub>2</jats:sub> was also established by chemical methods, yielding approximately 1 Mol. equiv. of formaldehyde after acid hydrolysis of anodendroside‐E<jats:sub>2</jats:sub>.</jats:p> Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung Helvetica Chimica Acta |
| spellingShingle | Lichti, H., von Euw, J., Stöckel, K., Polonia, J., Reichstein, T., Helvetica Chimica Acta, Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung, Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Drug Discovery, Biochemistry, Catalysis |
| title | Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_full | Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_fullStr | Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_full_unstemmed | Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_short | Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| title_sort | die vermutliche struktur der anodendroside. glykoside und aglykone, 331. mitteilung |
| title_unstemmed | Die vermutliche Struktur der Anodendroside. Glykoside und Aglykone, 331. Mitteilung |
| topic | Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Drug Discovery, Biochemistry, Catalysis |
| url | http://dx.doi.org/10.1002/hlca.19720550529 |