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Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
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Zeitschriftentitel: | European Journal of Organic Chemistry |
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Personen und Körperschaften: | , , , , |
In: | European Journal of Organic Chemistry, 2008, 2008, 30, S. 5047-5054 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Wiley
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Schlagwörter: |
author_facet |
Abbotto, Alessandro Bellotto, Luca De Angelis, Filippo Manfredi, Norberto Marinzi, Chiara Abbotto, Alessandro Bellotto, Luca De Angelis, Filippo Manfredi, Norberto Marinzi, Chiara |
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author |
Abbotto, Alessandro Bellotto, Luca De Angelis, Filippo Manfredi, Norberto Marinzi, Chiara |
spellingShingle |
Abbotto, Alessandro Bellotto, Luca De Angelis, Filippo Manfredi, Norberto Marinzi, Chiara European Journal of Organic Chemistry Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines Organic Chemistry Physical and Theoretical Chemistry |
author_sort |
abbotto, alessandro |
spelling |
Abbotto, Alessandro Bellotto, Luca De Angelis, Filippo Manfredi, Norberto Marinzi, Chiara 1434-193X 1099-0690 Wiley Organic Chemistry Physical and Theoretical Chemistry http://dx.doi.org/10.1002/ejoc.200800692 <jats:title>Abstract</jats:title><jats:p>A series of heteroaromatic 4,4′‐π‐conjugated 2,2′‐bipyridines (bpy) bearing conjugated π‐excessive and π‐deficient heteroaromatic rings as donor (D) and acceptor (A) substituents, respectively, is presented. We have experimentally and computationally found that, upon variation of donor and acceptor properties of the heterocyclic subunits in combination with different structural symmetries (bpy‐π‐D or bpy‐π‐D‐π‐A), the absorption and emission maxima and molecular orbital energy levels can be easily tuned over a broad range. Properties of the new ligands can be efficiently exploited in metal complexes for dye‐sensitized solar cells and in other materials for optical applications. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p> Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines European Journal of Organic Chemistry |
doi_str_mv |
10.1002/ejoc.200800692 |
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Chemie und Pharmazie Physik |
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Wiley, 2008 |
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2008 |
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European Journal of Organic Chemistry |
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title |
Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_unstemmed |
Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_full |
Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_fullStr |
Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_full_unstemmed |
Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_short |
Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_sort |
heteroaromatic donor–acceptor π‐conjugated 2,2′‐bipyridines |
topic |
Organic Chemistry Physical and Theoretical Chemistry |
url |
http://dx.doi.org/10.1002/ejoc.200800692 |
publishDate |
2008 |
physical |
5047-5054 |
description |
<jats:title>Abstract</jats:title><jats:p>A series of heteroaromatic 4,4′‐π‐conjugated 2,2′‐bipyridines (bpy) bearing conjugated π‐excessive and π‐deficient heteroaromatic rings as donor (D) and acceptor (A) substituents, respectively, is presented. We have experimentally and computationally found that, upon variation of donor and acceptor properties of the heterocyclic subunits in combination with different structural symmetries (bpy‐π‐D or bpy‐π‐D‐π‐A), the absorption and emission maxima and molecular orbital energy levels can be easily tuned over a broad range. Properties of the new ligands can be efficiently exploited in metal complexes for dye‐sensitized solar cells and in other materials for optical applications. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p> |
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author | Abbotto, Alessandro, Bellotto, Luca, De Angelis, Filippo, Manfredi, Norberto, Marinzi, Chiara |
author_facet | Abbotto, Alessandro, Bellotto, Luca, De Angelis, Filippo, Manfredi, Norberto, Marinzi, Chiara, Abbotto, Alessandro, Bellotto, Luca, De Angelis, Filippo, Manfredi, Norberto, Marinzi, Chiara |
author_sort | abbotto, alessandro |
container_issue | 30 |
container_start_page | 5047 |
container_title | European Journal of Organic Chemistry |
container_volume | 2008 |
description | <jats:title>Abstract</jats:title><jats:p>A series of heteroaromatic 4,4′‐π‐conjugated 2,2′‐bipyridines (bpy) bearing conjugated π‐excessive and π‐deficient heteroaromatic rings as donor (D) and acceptor (A) substituents, respectively, is presented. We have experimentally and computationally found that, upon variation of donor and acceptor properties of the heterocyclic subunits in combination with different structural symmetries (bpy‐π‐D or bpy‐π‐D‐π‐A), the absorption and emission maxima and molecular orbital energy levels can be easily tuned over a broad range. Properties of the new ligands can be efficiently exploited in metal complexes for dye‐sensitized solar cells and in other materials for optical applications. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p> |
doi_str_mv | 10.1002/ejoc.200800692 |
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imprint | Wiley, 2008 |
imprint_str_mv | Wiley, 2008 |
institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161 |
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physical | 5047-5054 |
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publisher | Wiley |
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recordtype | ai |
series | European Journal of Organic Chemistry |
source_id | 49 |
spelling | Abbotto, Alessandro Bellotto, Luca De Angelis, Filippo Manfredi, Norberto Marinzi, Chiara 1434-193X 1099-0690 Wiley Organic Chemistry Physical and Theoretical Chemistry http://dx.doi.org/10.1002/ejoc.200800692 <jats:title>Abstract</jats:title><jats:p>A series of heteroaromatic 4,4′‐π‐conjugated 2,2′‐bipyridines (bpy) bearing conjugated π‐excessive and π‐deficient heteroaromatic rings as donor (D) and acceptor (A) substituents, respectively, is presented. We have experimentally and computationally found that, upon variation of donor and acceptor properties of the heterocyclic subunits in combination with different structural symmetries (bpy‐π‐D or bpy‐π‐D‐π‐A), the absorption and emission maxima and molecular orbital energy levels can be easily tuned over a broad range. Properties of the new ligands can be efficiently exploited in metal complexes for dye‐sensitized solar cells and in other materials for optical applications. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p> Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines European Journal of Organic Chemistry |
spellingShingle | Abbotto, Alessandro, Bellotto, Luca, De Angelis, Filippo, Manfredi, Norberto, Marinzi, Chiara, European Journal of Organic Chemistry, Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines, Organic Chemistry, Physical and Theoretical Chemistry |
title | Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_full | Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_fullStr | Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_full_unstemmed | Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_short | Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
title_sort | heteroaromatic donor–acceptor π‐conjugated 2,2′‐bipyridines |
title_unstemmed | Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines |
topic | Organic Chemistry, Physical and Theoretical Chemistry |
url | http://dx.doi.org/10.1002/ejoc.200800692 |