author_facet Abbotto, Alessandro
Bellotto, Luca
De Angelis, Filippo
Manfredi, Norberto
Marinzi, Chiara
Abbotto, Alessandro
Bellotto, Luca
De Angelis, Filippo
Manfredi, Norberto
Marinzi, Chiara
author Abbotto, Alessandro
Bellotto, Luca
De Angelis, Filippo
Manfredi, Norberto
Marinzi, Chiara
spellingShingle Abbotto, Alessandro
Bellotto, Luca
De Angelis, Filippo
Manfredi, Norberto
Marinzi, Chiara
European Journal of Organic Chemistry
Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
Organic Chemistry
Physical and Theoretical Chemistry
author_sort abbotto, alessandro
spelling Abbotto, Alessandro Bellotto, Luca De Angelis, Filippo Manfredi, Norberto Marinzi, Chiara 1434-193X 1099-0690 Wiley Organic Chemistry Physical and Theoretical Chemistry http://dx.doi.org/10.1002/ejoc.200800692 <jats:title>Abstract</jats:title><jats:p>A series of heteroaromatic 4,4′‐π‐conjugated 2,2′‐bipyridines (bpy) bearing conjugated π‐excessive and π‐deficient heteroaromatic rings as donor (D) and acceptor (A) substituents, respectively, is presented. We have experimentally and computationally found that, upon variation of donor and acceptor properties of the heterocyclic subunits in combination with different structural symmetries (bpy‐π‐D or bpy‐π‐D‐π‐A), the absorption and emission maxima and molecular orbital energy levels can be easily tuned over a broad range. Properties of the new ligands can be efficiently exploited in metal complexes for dye‐sensitized solar cells and in other materials for optical applications. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p> Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines European Journal of Organic Chemistry
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series European Journal of Organic Chemistry
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title Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_unstemmed Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_full Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_fullStr Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_full_unstemmed Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_short Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_sort heteroaromatic donor–acceptor π‐conjugated 2,2′‐bipyridines
topic Organic Chemistry
Physical and Theoretical Chemistry
url http://dx.doi.org/10.1002/ejoc.200800692
publishDate 2008
physical 5047-5054
description <jats:title>Abstract</jats:title><jats:p>A series of heteroaromatic 4,4′‐π‐conjugated 2,2′‐bipyridines (bpy) bearing conjugated π‐excessive and π‐deficient heteroaromatic rings as donor (D) and acceptor (A) substituents, respectively, is presented. We have experimentally and computationally found that, upon variation of donor and acceptor properties of the heterocyclic subunits in combination with different structural symmetries (bpy‐π‐D or bpy‐π‐D‐π‐A), the absorption and emission maxima and molecular orbital energy levels can be easily tuned over a broad range. Properties of the new ligands can be efficiently exploited in metal complexes for dye‐sensitized solar cells and in other materials for optical applications. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p>
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author Abbotto, Alessandro, Bellotto, Luca, De Angelis, Filippo, Manfredi, Norberto, Marinzi, Chiara
author_facet Abbotto, Alessandro, Bellotto, Luca, De Angelis, Filippo, Manfredi, Norberto, Marinzi, Chiara, Abbotto, Alessandro, Bellotto, Luca, De Angelis, Filippo, Manfredi, Norberto, Marinzi, Chiara
author_sort abbotto, alessandro
container_issue 30
container_start_page 5047
container_title European Journal of Organic Chemistry
container_volume 2008
description <jats:title>Abstract</jats:title><jats:p>A series of heteroaromatic 4,4′‐π‐conjugated 2,2′‐bipyridines (bpy) bearing conjugated π‐excessive and π‐deficient heteroaromatic rings as donor (D) and acceptor (A) substituents, respectively, is presented. We have experimentally and computationally found that, upon variation of donor and acceptor properties of the heterocyclic subunits in combination with different structural symmetries (bpy‐π‐D or bpy‐π‐D‐π‐A), the absorption and emission maxima and molecular orbital energy levels can be easily tuned over a broad range. Properties of the new ligands can be efficiently exploited in metal complexes for dye‐sensitized solar cells and in other materials for optical applications. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p>
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imprint_str_mv Wiley, 2008
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spelling Abbotto, Alessandro Bellotto, Luca De Angelis, Filippo Manfredi, Norberto Marinzi, Chiara 1434-193X 1099-0690 Wiley Organic Chemistry Physical and Theoretical Chemistry http://dx.doi.org/10.1002/ejoc.200800692 <jats:title>Abstract</jats:title><jats:p>A series of heteroaromatic 4,4′‐π‐conjugated 2,2′‐bipyridines (bpy) bearing conjugated π‐excessive and π‐deficient heteroaromatic rings as donor (D) and acceptor (A) substituents, respectively, is presented. We have experimentally and computationally found that, upon variation of donor and acceptor properties of the heterocyclic subunits in combination with different structural symmetries (bpy‐π‐D or bpy‐π‐D‐π‐A), the absorption and emission maxima and molecular orbital energy levels can be easily tuned over a broad range. Properties of the new ligands can be efficiently exploited in metal complexes for dye‐sensitized solar cells and in other materials for optical applications. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p> Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines European Journal of Organic Chemistry
spellingShingle Abbotto, Alessandro, Bellotto, Luca, De Angelis, Filippo, Manfredi, Norberto, Marinzi, Chiara, European Journal of Organic Chemistry, Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines, Organic Chemistry, Physical and Theoretical Chemistry
title Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_full Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_fullStr Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_full_unstemmed Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_short Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
title_sort heteroaromatic donor–acceptor π‐conjugated 2,2′‐bipyridines
title_unstemmed Heteroaromatic Donor–Acceptor π‐Conjugated 2,2′‐Bipyridines
topic Organic Chemistry, Physical and Theoretical Chemistry
url http://dx.doi.org/10.1002/ejoc.200800692