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Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles
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Zeitschriftentitel: | European Journal of Organic Chemistry |
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Personen und Körperschaften: | , |
In: | European Journal of Organic Chemistry, 2003, 2003, 16, S. 3025-3042 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Wiley
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Schlagwörter: |
author_facet |
Lázár, László Fülöp, Ferenc Lázár, László Fülöp, Ferenc |
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author |
Lázár, László Fülöp, Ferenc |
spellingShingle |
Lázár, László Fülöp, Ferenc European Journal of Organic Chemistry Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles Organic Chemistry Physical and Theoretical Chemistry |
author_sort |
lázár, lászló |
spelling |
Lázár, László Fülöp, Ferenc 1434-193X 1099-0690 Wiley Organic Chemistry Physical and Theoretical Chemistry http://dx.doi.org/10.1002/ejoc.200300142 <jats:title>Abstract</jats:title><jats:p>Some important results from the past seven years on the ring‐chain tautomerism of 1,3‐heterocycles are reviewed, including substituent effects on the tautomeric equilibria and synthetic applications of this phenomenon. The structures and reactivities of numerous five‐ and six‐membered, saturated, <jats:italic>N</jats:italic>‐unsubstituted 1,3‐X,N‐heterocycles (X = O, S, NR) can be characterized by the ring‐chain tautomeric equilibria of the 1,3‐X,N‐heterocycles and the corresponding Schiff bases; this is often exploited advantageously in different areas of organic synthesis, and also in physical, medicinal and peptide chemistry. The selectivity of certain transformations can be explained on the basis of the ring‐chain tautomeric equilibration of the intermediates, followed by a shift in the equilibrium. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)</jats:p> Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles European Journal of Organic Chemistry |
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10.1002/ejoc.200300142 |
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2003 |
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Wiley |
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European Journal of Organic Chemistry |
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title |
Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_unstemmed |
Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_full |
Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_fullStr |
Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_full_unstemmed |
Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_short |
Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_sort |
recent developments in the ring‐chain tautomerism of 1,3‐heterocycles |
topic |
Organic Chemistry Physical and Theoretical Chemistry |
url |
http://dx.doi.org/10.1002/ejoc.200300142 |
publishDate |
2003 |
physical |
3025-3042 |
description |
<jats:title>Abstract</jats:title><jats:p>Some important results from the past seven years on the ring‐chain tautomerism of 1,3‐heterocycles are reviewed, including substituent effects on the tautomeric equilibria and synthetic applications of this phenomenon. The structures and reactivities of numerous five‐ and six‐membered, saturated, <jats:italic>N</jats:italic>‐unsubstituted 1,3‐X,N‐heterocycles (X = O, S, NR) can be characterized by the ring‐chain tautomeric equilibria of the 1,3‐X,N‐heterocycles and the corresponding Schiff bases; this is often exploited advantageously in different areas of organic synthesis, and also in physical, medicinal and peptide chemistry. The selectivity of certain transformations can be explained on the basis of the ring‐chain tautomeric equilibration of the intermediates, followed by a shift in the equilibrium. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)</jats:p> |
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author | Lázár, László, Fülöp, Ferenc |
author_facet | Lázár, László, Fülöp, Ferenc, Lázár, László, Fülöp, Ferenc |
author_sort | lázár, lászló |
container_issue | 16 |
container_start_page | 3025 |
container_title | European Journal of Organic Chemistry |
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description | <jats:title>Abstract</jats:title><jats:p>Some important results from the past seven years on the ring‐chain tautomerism of 1,3‐heterocycles are reviewed, including substituent effects on the tautomeric equilibria and synthetic applications of this phenomenon. The structures and reactivities of numerous five‐ and six‐membered, saturated, <jats:italic>N</jats:italic>‐unsubstituted 1,3‐X,N‐heterocycles (X = O, S, NR) can be characterized by the ring‐chain tautomeric equilibria of the 1,3‐X,N‐heterocycles and the corresponding Schiff bases; this is often exploited advantageously in different areas of organic synthesis, and also in physical, medicinal and peptide chemistry. The selectivity of certain transformations can be explained on the basis of the ring‐chain tautomeric equilibration of the intermediates, followed by a shift in the equilibrium. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)</jats:p> |
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source_id | 49 |
spelling | Lázár, László Fülöp, Ferenc 1434-193X 1099-0690 Wiley Organic Chemistry Physical and Theoretical Chemistry http://dx.doi.org/10.1002/ejoc.200300142 <jats:title>Abstract</jats:title><jats:p>Some important results from the past seven years on the ring‐chain tautomerism of 1,3‐heterocycles are reviewed, including substituent effects on the tautomeric equilibria and synthetic applications of this phenomenon. The structures and reactivities of numerous five‐ and six‐membered, saturated, <jats:italic>N</jats:italic>‐unsubstituted 1,3‐X,N‐heterocycles (X = O, S, NR) can be characterized by the ring‐chain tautomeric equilibria of the 1,3‐X,N‐heterocycles and the corresponding Schiff bases; this is often exploited advantageously in different areas of organic synthesis, and also in physical, medicinal and peptide chemistry. The selectivity of certain transformations can be explained on the basis of the ring‐chain tautomeric equilibration of the intermediates, followed by a shift in the equilibrium. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)</jats:p> Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles European Journal of Organic Chemistry |
spellingShingle | Lázár, László, Fülöp, Ferenc, European Journal of Organic Chemistry, Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles, Organic Chemistry, Physical and Theoretical Chemistry |
title | Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_full | Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_fullStr | Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_full_unstemmed | Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_short | Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
title_sort | recent developments in the ring‐chain tautomerism of 1,3‐heterocycles |
title_unstemmed | Recent Developments in the Ring‐Chain Tautomerism of 1,3‐Heterocycles |
topic | Organic Chemistry, Physical and Theoretical Chemistry |
url | http://dx.doi.org/10.1002/ejoc.200300142 |