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Tris(oxalato)phosphorus Acid and Its Lithium Salt
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| Zeitschriftentitel: | Chemistry – A European Journal |
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| Personen und Körperschaften: | , , , , , |
| In: | Chemistry – A European Journal, 10, 2004, 10, S. 2451-2458 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Wietelmann, Ulrich Bonrath, Werner Netscher, Thomas Nöth, Heinrich Panitz, Jan‐Christoph Wohlfahrt‐Mehrens, Margret Wietelmann, Ulrich Bonrath, Werner Netscher, Thomas Nöth, Heinrich Panitz, Jan‐Christoph Wohlfahrt‐Mehrens, Margret |
|---|---|
| author |
Wietelmann, Ulrich Bonrath, Werner Netscher, Thomas Nöth, Heinrich Panitz, Jan‐Christoph Wohlfahrt‐Mehrens, Margret |
| spellingShingle |
Wietelmann, Ulrich Bonrath, Werner Netscher, Thomas Nöth, Heinrich Panitz, Jan‐Christoph Wohlfahrt‐Mehrens, Margret Chemistry – A European Journal Tris(oxalato)phosphorus Acid and Its Lithium Salt General Chemistry Catalysis Organic Chemistry |
| author_sort |
wietelmann, ulrich |
| spelling |
Wietelmann, Ulrich Bonrath, Werner Netscher, Thomas Nöth, Heinrich Panitz, Jan‐Christoph Wohlfahrt‐Mehrens, Margret 0947-6539 1521-3765 Wiley General Chemistry Catalysis Organic Chemistry http://dx.doi.org/10.1002/chem.200305208 <jats:title>Abstract</jats:title><jats:p>The conversion of three equivalents of anhydrous oxalic acid with phosphorus pentachloride yields tris(oxalato)phosphorus acid <jats:bold>1</jats:bold>, which crystallizes from diethyl ether solutions as protonated diethyl ether complex [(Et<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub>H]<jats:sup>+</jats:sup>[P(C<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>]<jats:sup>−</jats:sup>. The superacidic compound can be used as catalyst for Friedel–Crafts‐type reactions. Upon neutralization with lithium hydride, the lithium salt Li[P(C<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>] <jats:bold>2</jats:bold> is obtained, which is highly soluble in aprotic solvents and which exhibits a wide voltage window. Thus, the lithium compound is a promising candidate as electrolyte for high performance non‐aqueous batteries.</jats:p> Tris(oxalato)phosphorus Acid and Its Lithium Salt Chemistry – A European Journal |
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| title |
Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_unstemmed |
Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_full |
Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_fullStr |
Tris(oxalato)phosphorus Acid and Its Lithium Salt |
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Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_short |
Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_sort |
tris(oxalato)phosphorus acid and its lithium salt |
| topic |
General Chemistry Catalysis Organic Chemistry |
| url |
http://dx.doi.org/10.1002/chem.200305208 |
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2004 |
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2451-2458 |
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<jats:title>Abstract</jats:title><jats:p>The conversion of three equivalents of anhydrous oxalic acid with phosphorus pentachloride yields tris(oxalato)phosphorus acid <jats:bold>1</jats:bold>, which crystallizes from diethyl ether solutions as protonated diethyl ether complex [(Et<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub>H]<jats:sup>+</jats:sup>[P(C<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>]<jats:sup>−</jats:sup>. The superacidic compound can be used as catalyst for Friedel–Crafts‐type reactions. Upon neutralization with lithium hydride, the lithium salt Li[P(C<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>] <jats:bold>2</jats:bold> is obtained, which is highly soluble in aprotic solvents and which exhibits a wide voltage window. Thus, the lithium compound is a promising candidate as electrolyte for high performance non‐aqueous batteries.</jats:p> |
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| author | Wietelmann, Ulrich, Bonrath, Werner, Netscher, Thomas, Nöth, Heinrich, Panitz, Jan‐Christoph, Wohlfahrt‐Mehrens, Margret |
| author_facet | Wietelmann, Ulrich, Bonrath, Werner, Netscher, Thomas, Nöth, Heinrich, Panitz, Jan‐Christoph, Wohlfahrt‐Mehrens, Margret, Wietelmann, Ulrich, Bonrath, Werner, Netscher, Thomas, Nöth, Heinrich, Panitz, Jan‐Christoph, Wohlfahrt‐Mehrens, Margret |
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| description | <jats:title>Abstract</jats:title><jats:p>The conversion of three equivalents of anhydrous oxalic acid with phosphorus pentachloride yields tris(oxalato)phosphorus acid <jats:bold>1</jats:bold>, which crystallizes from diethyl ether solutions as protonated diethyl ether complex [(Et<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub>H]<jats:sup>+</jats:sup>[P(C<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>]<jats:sup>−</jats:sup>. The superacidic compound can be used as catalyst for Friedel–Crafts‐type reactions. Upon neutralization with lithium hydride, the lithium salt Li[P(C<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>] <jats:bold>2</jats:bold> is obtained, which is highly soluble in aprotic solvents and which exhibits a wide voltage window. Thus, the lithium compound is a promising candidate as electrolyte for high performance non‐aqueous batteries.</jats:p> |
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| imprint_str_mv | Wiley, 2004 |
| institution | DE-Bn3, DE-Brt1, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275 |
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| spelling | Wietelmann, Ulrich Bonrath, Werner Netscher, Thomas Nöth, Heinrich Panitz, Jan‐Christoph Wohlfahrt‐Mehrens, Margret 0947-6539 1521-3765 Wiley General Chemistry Catalysis Organic Chemistry http://dx.doi.org/10.1002/chem.200305208 <jats:title>Abstract</jats:title><jats:p>The conversion of three equivalents of anhydrous oxalic acid with phosphorus pentachloride yields tris(oxalato)phosphorus acid <jats:bold>1</jats:bold>, which crystallizes from diethyl ether solutions as protonated diethyl ether complex [(Et<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub>H]<jats:sup>+</jats:sup>[P(C<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>]<jats:sup>−</jats:sup>. The superacidic compound can be used as catalyst for Friedel–Crafts‐type reactions. Upon neutralization with lithium hydride, the lithium salt Li[P(C<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>] <jats:bold>2</jats:bold> is obtained, which is highly soluble in aprotic solvents and which exhibits a wide voltage window. Thus, the lithium compound is a promising candidate as electrolyte for high performance non‐aqueous batteries.</jats:p> Tris(oxalato)phosphorus Acid and Its Lithium Salt Chemistry – A European Journal |
| spellingShingle | Wietelmann, Ulrich, Bonrath, Werner, Netscher, Thomas, Nöth, Heinrich, Panitz, Jan‐Christoph, Wohlfahrt‐Mehrens, Margret, Chemistry – A European Journal, Tris(oxalato)phosphorus Acid and Its Lithium Salt, General Chemistry, Catalysis, Organic Chemistry |
| title | Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_full | Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_fullStr | Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_full_unstemmed | Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_short | Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| title_sort | tris(oxalato)phosphorus acid and its lithium salt |
| title_unstemmed | Tris(oxalato)phosphorus Acid and Its Lithium Salt |
| topic | General Chemistry, Catalysis, Organic Chemistry |
| url | http://dx.doi.org/10.1002/chem.200305208 |