Eintrag weiter verarbeiten
Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents
Gespeichert in:
| Zeitschriftentitel: | Journal of Applied Polymer Science |
|---|---|
| Personen und Körperschaften: | , , , |
| In: | Journal of Applied Polymer Science, 137, 2020, 37 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
|
| Schlagwörter: |
| author_facet |
Nirwan, Viraj P. Pandey, Souvik Hey‐Hawkins, Evamarie Fahmi, Amir Nirwan, Viraj P. Pandey, Souvik Hey‐Hawkins, Evamarie Fahmi, Amir |
|---|---|
| author |
Nirwan, Viraj P. Pandey, Souvik Hey‐Hawkins, Evamarie Fahmi, Amir |
| spellingShingle |
Nirwan, Viraj P. Pandey, Souvik Hey‐Hawkins, Evamarie Fahmi, Amir Journal of Applied Polymer Science Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
| author_sort |
nirwan, viraj p. |
| spelling |
Nirwan, Viraj P. Pandey, Souvik Hey‐Hawkins, Evamarie Fahmi, Amir 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.49091 <jats:title>Abstract</jats:title><jats:p>Template smart inorganic polymers within an organic polymeric matrix to form hybrid nanostructured materials are a unique approach to induce novel multifunctionality. In particular, the fabrication of one‐dimensional materials via electrospinning is an advanced tool, which has gained success in fulfilling the purpose to fabricate two‐dimensional nanostructured materials. We have explored the formation of novel hybrid nanofibers by co‐spinning of poly(ferrocenylphosphinoboranes) <jats:bold>Fe A</jats:bold> [{Fe(C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)(C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>CH<jats:sub>2</jats:sub>PHBH<jats:sub>2</jats:sub>)}<jats:sub> <jats:italic>n</jats:italic></jats:sub>] and <jats:bold>Fe B</jats:bold> [{Fe(C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)(C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>PHBH<jats:sub>2</jats:sub>)}<jats:sub> <jats:italic>n</jats:italic></jats:sub>] with poly(ethylene oxide) (PEO) and polystyrene (PS). <jats:bold>Fe A</jats:bold> and <jats:bold>Fe B</jats:bold> contain main‐group elements and a ferrocene moiety as pendent group and have different properties compared to their only carbon‐containing counterparts. The use of PEO and polystyrene provided a matrix to spin those inorganic polymers as hybrid nanofibers which were collected in the form of a nonwoven mat. They were characterized by multinuclear NMR spectroscopy, scanning electron microscopy (SEM), and IR spectroscopy. Thermal properties of the polymers have been checked by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). <jats:sup>1</jats:sup>H, <jats:sup>31</jats:sup>P, and <jats:sup>11</jats:sup>B NMR and IR spectroscopy revealed the nature and types of interactions of the components after co‐spinning. The SEM micrographs identify the underlying unidirectional morphology of the generated hybrid nanofibers. Nonetheless, the DSC and TGA confirmed the significant boost toward the thermal stability of the resultant multifunctional fibers. It is believed that these unique types of multifunctional electrospun nanofibers will open new avenues toward the next generation of miniaturized devices.</jats:p> Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents Journal of Applied Polymer Science |
| doi_str_mv |
10.1002/app.49091 |
| facet_avail |
Online |
| finc_class_facet |
Chemie und Pharmazie Allgemeines Technik |
| format |
ElectronicArticle |
| fullrecord |
blob:ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9hcHAuNDkwOTE |
| id |
ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9hcHAuNDkwOTE |
| institution |
DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 DE-D275 DE-Bn3 DE-Brt1 |
| imprint |
Wiley, 2020 |
| imprint_str_mv |
Wiley, 2020 |
| issn |
0021-8995 1097-4628 |
| issn_str_mv |
0021-8995 1097-4628 |
| language |
English |
| mega_collection |
Wiley (CrossRef) |
| match_str |
nirwan2020hybrid2dnanofibersbasedonpolyethyleneoxidepolystyrenematrixandpolyferrocenylphosphinoboranesasfunctionalagents |
| publishDateSort |
2020 |
| publisher |
Wiley |
| recordtype |
ai |
| record_format |
ai |
| series |
Journal of Applied Polymer Science |
| source_id |
49 |
| title |
Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_unstemmed |
Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_full |
Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_fullStr |
Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_full_unstemmed |
Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_short |
Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_sort |
hybrid 2d nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| topic |
Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
| url |
http://dx.doi.org/10.1002/app.49091 |
| publishDate |
2020 |
| physical |
|
| description |
<jats:title>Abstract</jats:title><jats:p>Template smart inorganic polymers within an organic polymeric matrix to form hybrid nanostructured materials are a unique approach to induce novel multifunctionality. In particular, the fabrication of one‐dimensional materials via electrospinning is an advanced tool, which has gained success in fulfilling the purpose to fabricate two‐dimensional nanostructured materials. We have explored the formation of novel hybrid nanofibers by co‐spinning of poly(ferrocenylphosphinoboranes) <jats:bold>Fe A</jats:bold> [{Fe(C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)(C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>CH<jats:sub>2</jats:sub>PHBH<jats:sub>2</jats:sub>)}<jats:sub>
<jats:italic>n</jats:italic></jats:sub>] and <jats:bold>Fe B</jats:bold> [{Fe(C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)(C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>PHBH<jats:sub>2</jats:sub>)}<jats:sub>
<jats:italic>n</jats:italic></jats:sub>] with poly(ethylene oxide) (PEO) and polystyrene (PS). <jats:bold>Fe A</jats:bold> and <jats:bold>Fe B</jats:bold> contain main‐group elements and a ferrocene moiety as pendent group and have different properties compared to their only carbon‐containing counterparts. The use of PEO and polystyrene provided a matrix to spin those inorganic polymers as hybrid nanofibers which were collected in the form of a nonwoven mat. They were characterized by multinuclear NMR spectroscopy, scanning electron microscopy (SEM), and IR spectroscopy. Thermal properties of the polymers have been checked by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). <jats:sup>1</jats:sup>H, <jats:sup>31</jats:sup>P, and <jats:sup>11</jats:sup>B NMR and IR spectroscopy revealed the nature and types of interactions of the components after co‐spinning. The SEM micrographs identify the underlying unidirectional morphology of the generated hybrid nanofibers. Nonetheless, the DSC and TGA confirmed the significant boost toward the thermal stability of the resultant multifunctional fibers. It is believed that these unique types of multifunctional electrospun nanofibers will open new avenues toward the next generation of miniaturized devices.</jats:p> |
| container_issue |
37 |
| container_start_page |
0 |
| container_title |
Journal of Applied Polymer Science |
| container_volume |
137 |
| format_de105 |
Article, E-Article |
| format_de14 |
Article, E-Article |
| format_de15 |
Article, E-Article |
| format_de520 |
Article, E-Article |
| format_de540 |
Article, E-Article |
| format_dech1 |
Article, E-Article |
| format_ded117 |
Article, E-Article |
| format_degla1 |
E-Article |
| format_del152 |
Buch |
| format_del189 |
Article, E-Article |
| format_dezi4 |
Article |
| format_dezwi2 |
Article, E-Article |
| format_finc |
Article, E-Article |
| format_nrw |
Article, E-Article |
| _version_ |
1792338725655543808 |
| geogr_code |
not assigned |
| last_indexed |
2024-03-01T15:36:48.49Z |
| geogr_code_person |
not assigned |
| openURL |
url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Hybrid+2D+nanofibers+based+on+poly%28ethylene+oxide%29%2Fpolystyrene+matrix+and+poly%28ferrocenylphosphinoboranes%29+as+functional+agents&rft.date=2020-10-05&genre=article&issn=1097-4628&volume=137&issue=37&jtitle=Journal+of+Applied+Polymer+Science&atitle=Hybrid+2D+nanofibers+based+on+poly%28ethylene+oxide%29%2Fpolystyrene+matrix+and+poly%28ferrocenylphosphinoboranes%29+as+functional+agents&aulast=Fahmi&aufirst=Amir&rft_id=info%3Adoi%2F10.1002%2Fapp.49091&rft.language%5B0%5D=eng |
| SOLR | |
| _version_ | 1792338725655543808 |
| author | Nirwan, Viraj P., Pandey, Souvik, Hey‐Hawkins, Evamarie, Fahmi, Amir |
| author_facet | Nirwan, Viraj P., Pandey, Souvik, Hey‐Hawkins, Evamarie, Fahmi, Amir, Nirwan, Viraj P., Pandey, Souvik, Hey‐Hawkins, Evamarie, Fahmi, Amir |
| author_sort | nirwan, viraj p. |
| container_issue | 37 |
| container_start_page | 0 |
| container_title | Journal of Applied Polymer Science |
| container_volume | 137 |
| description | <jats:title>Abstract</jats:title><jats:p>Template smart inorganic polymers within an organic polymeric matrix to form hybrid nanostructured materials are a unique approach to induce novel multifunctionality. In particular, the fabrication of one‐dimensional materials via electrospinning is an advanced tool, which has gained success in fulfilling the purpose to fabricate two‐dimensional nanostructured materials. We have explored the formation of novel hybrid nanofibers by co‐spinning of poly(ferrocenylphosphinoboranes) <jats:bold>Fe A</jats:bold> [{Fe(C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)(C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>CH<jats:sub>2</jats:sub>PHBH<jats:sub>2</jats:sub>)}<jats:sub> <jats:italic>n</jats:italic></jats:sub>] and <jats:bold>Fe B</jats:bold> [{Fe(C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)(C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>PHBH<jats:sub>2</jats:sub>)}<jats:sub> <jats:italic>n</jats:italic></jats:sub>] with poly(ethylene oxide) (PEO) and polystyrene (PS). <jats:bold>Fe A</jats:bold> and <jats:bold>Fe B</jats:bold> contain main‐group elements and a ferrocene moiety as pendent group and have different properties compared to their only carbon‐containing counterparts. The use of PEO and polystyrene provided a matrix to spin those inorganic polymers as hybrid nanofibers which were collected in the form of a nonwoven mat. They were characterized by multinuclear NMR spectroscopy, scanning electron microscopy (SEM), and IR spectroscopy. Thermal properties of the polymers have been checked by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). <jats:sup>1</jats:sup>H, <jats:sup>31</jats:sup>P, and <jats:sup>11</jats:sup>B NMR and IR spectroscopy revealed the nature and types of interactions of the components after co‐spinning. The SEM micrographs identify the underlying unidirectional morphology of the generated hybrid nanofibers. Nonetheless, the DSC and TGA confirmed the significant boost toward the thermal stability of the resultant multifunctional fibers. It is believed that these unique types of multifunctional electrospun nanofibers will open new avenues toward the next generation of miniaturized devices.</jats:p> |
| doi_str_mv | 10.1002/app.49091 |
| facet_avail | Online |
| finc_class_facet | Chemie und Pharmazie, Allgemeines, Technik |
| format | ElectronicArticle |
| format_de105 | Article, E-Article |
| format_de14 | Article, E-Article |
| format_de15 | Article, E-Article |
| format_de520 | Article, E-Article |
| format_de540 | Article, E-Article |
| format_dech1 | Article, E-Article |
| format_ded117 | Article, E-Article |
| format_degla1 | E-Article |
| format_del152 | Buch |
| format_del189 | Article, E-Article |
| format_dezi4 | Article |
| format_dezwi2 | Article, E-Article |
| format_finc | Article, E-Article |
| format_nrw | Article, E-Article |
| geogr_code | not assigned |
| geogr_code_person | not assigned |
| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTAwMi9hcHAuNDkwOTE |
| imprint | Wiley, 2020 |
| imprint_str_mv | Wiley, 2020 |
| institution | DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1 |
| issn | 0021-8995, 1097-4628 |
| issn_str_mv | 0021-8995, 1097-4628 |
| language | English |
| last_indexed | 2024-03-01T15:36:48.49Z |
| match_str | nirwan2020hybrid2dnanofibersbasedonpolyethyleneoxidepolystyrenematrixandpolyferrocenylphosphinoboranesasfunctionalagents |
| mega_collection | Wiley (CrossRef) |
| physical | |
| publishDate | 2020 |
| publishDateSort | 2020 |
| publisher | Wiley |
| record_format | ai |
| recordtype | ai |
| series | Journal of Applied Polymer Science |
| source_id | 49 |
| spelling | Nirwan, Viraj P. Pandey, Souvik Hey‐Hawkins, Evamarie Fahmi, Amir 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.49091 <jats:title>Abstract</jats:title><jats:p>Template smart inorganic polymers within an organic polymeric matrix to form hybrid nanostructured materials are a unique approach to induce novel multifunctionality. In particular, the fabrication of one‐dimensional materials via electrospinning is an advanced tool, which has gained success in fulfilling the purpose to fabricate two‐dimensional nanostructured materials. We have explored the formation of novel hybrid nanofibers by co‐spinning of poly(ferrocenylphosphinoboranes) <jats:bold>Fe A</jats:bold> [{Fe(C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)(C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>CH<jats:sub>2</jats:sub>PHBH<jats:sub>2</jats:sub>)}<jats:sub> <jats:italic>n</jats:italic></jats:sub>] and <jats:bold>Fe B</jats:bold> [{Fe(C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)(C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>PHBH<jats:sub>2</jats:sub>)}<jats:sub> <jats:italic>n</jats:italic></jats:sub>] with poly(ethylene oxide) (PEO) and polystyrene (PS). <jats:bold>Fe A</jats:bold> and <jats:bold>Fe B</jats:bold> contain main‐group elements and a ferrocene moiety as pendent group and have different properties compared to their only carbon‐containing counterparts. The use of PEO and polystyrene provided a matrix to spin those inorganic polymers as hybrid nanofibers which were collected in the form of a nonwoven mat. They were characterized by multinuclear NMR spectroscopy, scanning electron microscopy (SEM), and IR spectroscopy. Thermal properties of the polymers have been checked by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). <jats:sup>1</jats:sup>H, <jats:sup>31</jats:sup>P, and <jats:sup>11</jats:sup>B NMR and IR spectroscopy revealed the nature and types of interactions of the components after co‐spinning. The SEM micrographs identify the underlying unidirectional morphology of the generated hybrid nanofibers. Nonetheless, the DSC and TGA confirmed the significant boost toward the thermal stability of the resultant multifunctional fibers. It is believed that these unique types of multifunctional electrospun nanofibers will open new avenues toward the next generation of miniaturized devices.</jats:p> Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents Journal of Applied Polymer Science |
| spellingShingle | Nirwan, Viraj P., Pandey, Souvik, Hey‐Hawkins, Evamarie, Fahmi, Amir, Journal of Applied Polymer Science, Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents, Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
| title | Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_full | Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_fullStr | Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_full_unstemmed | Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_short | Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_sort | hybrid 2d nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| title_unstemmed | Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
| topic | Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
| url | http://dx.doi.org/10.1002/app.49091 |