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Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers
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| Zeitschriftentitel: | Journal of Applied Polymer Science |
|---|---|
| Personen und Körperschaften: | , |
| In: | Journal of Applied Polymer Science, 131, 2014, 11 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Wiley
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| Schlagwörter: |
| author_facet |
Kara, Meryem O. Pehlivaner Frey, Margaret W. Kara, Meryem O. Pehlivaner Frey, Margaret W. |
|---|---|
| author |
Kara, Meryem O. Pehlivaner Frey, Margaret W. |
| spellingShingle |
Kara, Meryem O. Pehlivaner Frey, Margaret W. Journal of Applied Polymer Science Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
| author_sort |
kara, meryem o. pehlivaner |
| spelling |
Kara, Meryem O. Pehlivaner Frey, Margaret W. 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.40305 <jats:title>ABSTRACT</jats:title><jats:p>In this study, the effect of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS) nanofibers is investigated. Conductive PEDOT:PSS nanofibers are electrospun by dissolving a fiber‐forming polymer, polyvinyl alcohol, in an aqueous dispersion of PEDOT:PSS. The conductivity of PEDOT:PSS nanofibers is enhanced 15‐fold by addition of DMSO and almost 30‐fold by addition of ethylene glycol to the spinning dopes. This improvement is attributed to the change in the conformation of the PEDOT chains from the coiled benzoid to the extended coil quinoid structure as confirmed by Raman spectroscopy, X‐ray diffraction, and differential scanning calorimetry. Scanning electron microscopy images show that less beady and more uniform fiber morphology could be obtained by incorporation of ethylene glycol in the spinning dopes. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. <jats:bold>2014</jats:bold>, <jats:italic>131</jats:italic>, 40305.</jats:p> Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers Journal of Applied Polymer Science |
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| title |
Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_unstemmed |
Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_full |
Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_fullStr |
Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_full_unstemmed |
Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_short |
Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_sort |
effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) nanofibers |
| topic |
Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry |
| url |
http://dx.doi.org/10.1002/app.40305 |
| publishDate |
2014 |
| physical |
|
| description |
<jats:title>ABSTRACT</jats:title><jats:p>In this study, the effect of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS) nanofibers is investigated. Conductive PEDOT:PSS nanofibers are electrospun by dissolving a fiber‐forming polymer, polyvinyl alcohol, in an aqueous dispersion of PEDOT:PSS. The conductivity of PEDOT:PSS nanofibers is enhanced 15‐fold by addition of DMSO and almost 30‐fold by addition of ethylene glycol to the spinning dopes. This improvement is attributed to the change in the conformation of the PEDOT chains from the coiled benzoid to the extended coil quinoid structure as confirmed by Raman spectroscopy, X‐ray diffraction, and differential scanning calorimetry. Scanning electron microscopy images show that less beady and more uniform fiber morphology could be obtained by incorporation of ethylene glycol in the spinning dopes. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. <jats:bold>2014</jats:bold>, <jats:italic>131</jats:italic>, 40305.</jats:p> |
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| author | Kara, Meryem O. Pehlivaner, Frey, Margaret W. |
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| description | <jats:title>ABSTRACT</jats:title><jats:p>In this study, the effect of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS) nanofibers is investigated. Conductive PEDOT:PSS nanofibers are electrospun by dissolving a fiber‐forming polymer, polyvinyl alcohol, in an aqueous dispersion of PEDOT:PSS. The conductivity of PEDOT:PSS nanofibers is enhanced 15‐fold by addition of DMSO and almost 30‐fold by addition of ethylene glycol to the spinning dopes. This improvement is attributed to the change in the conformation of the PEDOT chains from the coiled benzoid to the extended coil quinoid structure as confirmed by Raman spectroscopy, X‐ray diffraction, and differential scanning calorimetry. Scanning electron microscopy images show that less beady and more uniform fiber morphology could be obtained by incorporation of ethylene glycol in the spinning dopes. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. <jats:bold>2014</jats:bold>, <jats:italic>131</jats:italic>, 40305.</jats:p> |
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| spelling | Kara, Meryem O. Pehlivaner Frey, Margaret W. 0021-8995 1097-4628 Wiley Materials Chemistry Polymers and Plastics Surfaces, Coatings and Films General Chemistry http://dx.doi.org/10.1002/app.40305 <jats:title>ABSTRACT</jats:title><jats:p>In this study, the effect of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS) nanofibers is investigated. Conductive PEDOT:PSS nanofibers are electrospun by dissolving a fiber‐forming polymer, polyvinyl alcohol, in an aqueous dispersion of PEDOT:PSS. The conductivity of PEDOT:PSS nanofibers is enhanced 15‐fold by addition of DMSO and almost 30‐fold by addition of ethylene glycol to the spinning dopes. This improvement is attributed to the change in the conformation of the PEDOT chains from the coiled benzoid to the extended coil quinoid structure as confirmed by Raman spectroscopy, X‐ray diffraction, and differential scanning calorimetry. Scanning electron microscopy images show that less beady and more uniform fiber morphology could be obtained by incorporation of ethylene glycol in the spinning dopes. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. <jats:bold>2014</jats:bold>, <jats:italic>131</jats:italic>, 40305.</jats:p> Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers Journal of Applied Polymer Science |
| spellingShingle | Kara, Meryem O. Pehlivaner, Frey, Margaret W., Journal of Applied Polymer Science, Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers, Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
| title | Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_full | Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_fullStr | Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_full_unstemmed | Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_short | Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| title_sort | effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) nanofibers |
| title_unstemmed | Effects of solvents on the morphology and conductivity of poly(3,4‐ethylenedioxythiophene):Poly(styrenesulfonate) nanofibers |
| topic | Materials Chemistry, Polymers and Plastics, Surfaces, Coatings and Films, General Chemistry |
| url | http://dx.doi.org/10.1002/app.40305 |